中国塑料 ›› 2017, Vol. 31 ›› Issue (6): 46-53 .DOI: 10.19491/j.issn.1001-9278.2017.06.008

• 材料与性能 • 上一篇    下一篇

高模量高抗冲聚丙烯复合材料的制备及性能研究

郑智焕1,杨丽庭1,付梓阳1,李彦涛2,张惠2,唐梓健1   

  1. 1. 华南师范大学化学与环境学院2. 华南师范大学
  • 收稿日期:2017-01-10 修回日期:2017-03-06 出版日期:2017-06-26 发布日期:2017-09-26

Preparation and Properties of High Modulus and High Impact Polypropylene Composites

  • Received:2017-01-10 Revised:2017-03-06 Online:2017-06-26 Published:2017-09-26

摘要: 通过熔融共混法研究了乙烯辛烯共聚物(POE)、滑石粉和高密度聚乙烯(PEHD)的含量对高模量、高抗冲聚丙烯(PP)复合材料力学性能、结晶行为、热分解行为以及相态的影响。结果表明,PP与POE的黏度比越小,PP/POE复合材料的韧性越好;当PP/POE/滑石粉/PEHD复合材料的质量比为13/4/12/3时,综合力学性能最佳;相比纯PP,复合材料的弯曲模量提高了60.1 %,缺口冲击强度提高了435.9 %,拉伸强度和弯曲强度分别降低了27.4 %和17.4 %;PEHD能够增强PP与POE的界面相互作用,提高复合材料的韧性;加入滑石粉和PEHD均可提高复合材料的起始分解温度以及最大热失重速率温度,提高了复合材料的热稳定性。

关键词: 聚丙烯, 乙烯-辛烯共聚物, 高密度聚乙烯, 高模量, 冲击强度

Abstract: This paper reported a study of effects of ethylene-octene copolymer (POE), talc, and high-density polyethylene (PEHD) contents on mechanical properties, crystallization behavior, thermal decomposition behavior, and morphology of polypropylene (PP) composites. Impact toughness of the composites tended to increase with a decrease in the PP/POE viscosity ratio. The optimum mechanical properties were gained for the composites with PP/POE/talc/PE-HD weight ratio of 13/4/12/3. Compared with pure PP, the composites achieved an increase in flexural modulus by 60.1 % and in impact strength by 435.9 %, whereas their tensile strength and flexural strength were reduced by 27.4 % and 17.4 %, respectively. The interface interaction between PP and POE phases was enhanced due to the presence of PE-HD, thus improving the impact toughness of the composites. The introduction of talc or PE-HD into the composites also resulted in an improvement in initial decomposition temperature and the temperature at the maximum weightloss rate and, therefore, enhanced the thermal stability of the composites.

Key words: polypropylene, ethylene-octene copolymer, high-density polyethylene, high modulus, impact strength