中国塑料 ›› 2017, Vol. 31 ›› Issue (8): 62-67 .DOI: 10.19491/j.issn.1001-9278.2017.08.011

• 材料与性能 • 上一篇    下一篇

聚丙烯/硅藻土复合材料断口形貌的二维分形特征研究

龚友根1,吴成宝2,刘传生1,陈峥华3,龚煜4,李璐瑶4,梁基照5   

  1. 1. 广州民航学院2. 清华大学;华南理工大学3. 广州白云国际机场地勤服务有限公司机务工程部4. 广州民航职业技术学院飞机维修工程学院5. 华南理工大学机械与汽车工程学院
  • 收稿日期:2017-03-27 修回日期:2017-05-04 出版日期:2017-08-26 发布日期:2017-09-26

Two-dimensional Fractal Characteristic of Fractography of Polypropylene/Diatomite Composites

  • Received:2017-03-27 Revised:2017-05-04 Online:2017-08-26 Published:2017-09-26

摘要: 采用熔融共混法制备了2种硅藻土填充聚丙烯(PP/硅藻土)复合材料PP/281和PP/700,采用扫描电子显微镜观察了冲击断口形貌,运用图像处理软件IPP提取了复合材料断口形貌的二维轮廓曲线;应用结构函数法测算了断口形貌二维轮廓曲线的分形维数(DL),定量表征了复合材料的断口形貌特征;探讨了DL与复合材料冲击强度(σⅣ)的关系。结果表明,PP及其PP/硅藻土复合材料的断口形貌具有显著的分形特征,其中纯PP的DL值为1.6375,PP/硅藻土复合材料的DL值介于1.6474~1.7361之间;在所考察的硅藻土体积填充分数(φf)范围内,PP/281复合材料的DL值在φf为10 %时有最大值1.7361,PP/700复合材料在φf为5 %时具有最大值1.7143;σⅣ值与DL值正相关,且呈近似指数函数关系。

关键词: 硅藻土, 聚丙烯, 复合材料, 断口形貌, 分形维数

Abstract: Two types of polypropylene (PP)/diatomate composites, PP/281 and PP/700, were prepared via melt blending, their impact strength (σⅣ) was evaluated by impact tests, and their fractography obtained from impact testing was observed by scanning electron microscopy. The profile curve of the fractography was extracted by an Image Pro-Plus image processing software, and their fractal dimension (DL) was calculated by a structure function method. The relationship between DL and σⅣ was investigated intensively. The results indicated that the fracture of PP and its composites with diatomate exhibit an evident fractal feature, and DL was in the range of 1.6474~1.7361, which could be used to characterize the fractography of PP/Diatomate composites quantitatively. PP/281 composites had a maximum DL of 1.7361 at a filling fraction (φf) of 10 vol %, whereas PP/700 composites showed a maximum DL of 1.7143 at the φf of 5 vol %. The relationship between DL and σⅣ had a positive correlation and was exponential.

Key words: diatomate, polypropylene, composite, fractography, fractal dimension