中国塑料 ›› 2007, Vol. 21 ›› Issue (3): 10-15.

• 材料与性能 • 上一篇    下一篇

聚丙烯/线形双峰聚乙烯共混体系的流变行为、结晶形态与力学性能研究

秦江雷,李志庭,高俊刚,闰明涛   

  1. 河北大学化学与环境科学学院,河北保定071002
  • 出版日期:2007-03-26 发布日期:2021-04-02

Rheological Behavior,Crystal Morphology and Mechanical Properties of PP/PE-LB Blend#br#

QIN Jiang-lei,LI Zhi-ting,GAO Jun-gang,RUN Ming-tao   

  1. College of Chemistry and Environment Science,Hebei University,Baoding 071002, China
  • Online:2007-03-26 Published:2021-04-02

摘要: 用毛细管流变仪研究了聚丙烯(PP)与线形双峰聚乙烯( PE-LB)共混体系熔体的流变行为。讨论了共混体系的组成、剪切应力和剪切速率对熔体流变行为、熔体勃度的影响。测定了PE-LB不同含量的共混物熔体的非牛顿指数,并计算了共混熔体的勃流活化能。结果表明:共混体系熔体属假塑性流体,其赫度随PE-LB加入量的增加逐渐增大,但是在PE-LB含量较低时豁度的增幅并不明显;共棍体系的非牛顿指数显示出双波谷形,在两者含量比较接近的时候出现峰值。DSC实验证明PE-LB的加人使PP的熔融温度降低,结晶温度提高,说明PE-LB与PP有一定相容性,并对PP有稀释作用;SEM照片显示共混体系没有出现相分离的界面,证明两者有一定的相容性。PE-LB对PP有明显的增韧改性作用,当PE-LB质量含量为20%时,冲击强度比纯PP提高了67%;当含量为40%时,冲击强度提高了3.2倍,拉伸强度分别下降为纯PP的93%和65%。

关键词: 聚丙烯, 线形双峰聚乙烯, 共混, 流变行为, 力学性能

Abstract: Melt rheological behaviors of the polypropylene/linear bimodal polyethylene( PP/PE-LB) blend were studied with capillary rheometer.Influences of composition, shear stress, and shearing rate on the melt rheological behavior were discussed. Non-Newtonian index( n) and melt flow activation en ergy of the melt were measured and the results showed that PP/PE-LB blends were pseudoplastic fluids.Melt viscosity of the blends increased with increasing PE-LB content. DSC and SEM showed that addi tion of PE-LB helped PP crystallize at higher temperatures. The addition of LBPE obviously increased the mechanical properties of PP. While the additions were 20 wt % and 40 wt %, the notched impact strength increased about 67% and 320%, respectively,  however, at the cost of the tensile strength lowered by 7 % and 35 %, respectively.

Key words: polypropylene;linear bimodal polyethylene, blending;rheological behavior, mechanical property

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