中国塑料 ›› 2009, Vol. 23 ›› Issue (01): 55-58 .DOI: 10.19491/j.issn.1001-9278.2009.01.012

• 加工与应用 • 上一篇    下一篇

相容剂对聚丙烯/纳米黏土复合材料抗熔垂性能影响的研究

陈斌艺,刘本刚,陈士宏,王向东,张玉霞   

  1. 北京工商大学材料利学与工程系, 北京100048
  • 收稿日期:2008-11-05 修回日期:1900-01-01 出版日期:2009-01-26 发布日期:2009-01-26

Study on the Sag Resistance of PP-g-MAH Modified PP/Nano-clay Composites

CHEN Bin-yi,LIU Ben-gang,CHEN Shi一hong,WANG Xiang-dong,ZHANG Yu-xia   

  1. Department of Materials Scicnec and Engineering, Beijing Technology and Business University, Beijing 100048,China
  • Received:2008-11-05 Revised:1900-01-01 Online:2009-01-26 Published:2009-01-26
  • Contact: WANG Xiang-dong

摘要: 在双螺杆挤出机上制备了相容剂马来酸酐接枝聚丙烯(PP-g-MAH)改性的聚丙烯(PP)纳米黏土复合材料。通过XRD测试和杭熔垂性能测试研究了PP-g-MAH对复合材料杭熔垂性能的影响。研究表明:PP-g-MAH的性能和用量对复合材料的插层结构有一定影响,进而影响到复合材料的杭熔垂性能.其中,采用熔体流动辣率小、接枝率低的PP-g-MAH所得到的纳米黏土复合材料的杭熔垂性能相对较奸,但PP-g-MAH的含量不宜过高。插层结构的黏土片层的层间距与复合材料杭熔垂性能存在一定关联,PP纳米黏土复合材料中存在最利于材料杭熔垂性能捍高的插层结构,层间距为2. 90-3. 10 nm的插层结构对应的复合材料的杭熔垂能力较好

关键词: 聚丙烯, 纳米黏土, 相容剂, 马来酸酐接枝聚丙烯, 插层结构, 杭熔垂性能

Abstract: PP-g-MAH modified PP/nano-clay composite was prepared on a twin-screw extruder.Effect of the compatibilizcr, PP-g-MnH,on the sag resistance of the composite was studied by XRD analysis and sag resistance testing. Experimental results show that the compatilizcr properties and dosages have certain influences on the intercalation structure and the sag resistance of the
composite. When the compatilizcr with lower melt flow rate and lower grafting rate was used,the composite exhibited excellent sag resistance. The layer spacing of the different intercalated structure of the composite was related to the sag resistance,there was optimal layer spacing. While
the layer space of the clay is 2. 90一3. 00 nm, the sag resistance of the PP/nano-clay composite
reached its highest value.

Key words: polypropylene, nano-clay, compatibilizcr, polypropylene-graft-malcic anhydride, intercalation structure, sag resistance