中国塑料 ›› 2009, Vol. 23 ›› Issue (05): 91-94 .DOI: 10.19491/j.issn.1001-9278.2009.05.017

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硼元素在膨胀型阻燃聚丙烯中的协同作用

马志领 胡英超 杨磊 王磊 路正宇   

  1. 河北大学 河北大学
  • 收稿日期:2009-01-14 修回日期:1900-01-01 出版日期:2009-05-26 发布日期:2009-05-26

The Synergy of Boron Element in the Intumescent Flame Retardant PP

  

  • Received:2009-01-14 Revised:1900-01-01 Online:2009-05-26 Published:2009-05-26

摘要: 摘要:通过燃烧性能测定、热分析和锥形量热等方法研究了硼元素在膨胀型阻燃聚丙烯(PP)中的作用。热分析表明,膨胀型阻燃剂(KDIFR)的加入明显的促进了PP成炭,使剩炭率提高,放热量减小,硼元素的引入剩炭率略有降低,放热量增大。锥形量热图表明KDIFR显著减少了PP燃烧过程的热释放速率,释热总量,及CO2和CO释放量,这种效果在硼引入后,受热燃烧初期得以促进,但随着时间的延长减弱。实验证明KDIFR使PP由聚烯烃类燃烧转变为纤维类燃烧,而硼元素的引入促进了这一转变,显著减缓了火焰传播速率,阻燃效果更加突出。

关键词: 关键词:聚丙烯, 硼, 膨胀型阻燃剂, 热分析, 锥形量热仪

Abstract: Abstract:The effect of boron in the intumescent flame retardant PP was studied by horizontal combustion test, thermal analysis and cone calorimeter. The thermal analysis showed that KDIFR made the PP’s char residual increase and heat release reduce, but the introduction of boron made the char residual decrease and heat release increase slightly. Cone calorimeter graphs indicated the KDIFR significantly reduced the heat release rate, total heat release, and CO2, CO emissions in the combustion process of PP, which was promoted by boron, but was weakened as the combustion process continued. In a word, experiments results showed that KDIFR changed the PP’s typical polyolefin type combustion to fiber type combustion, which was promoted by boron, and slowed down the flame propagation, and had more prominent flame retardance.

Key words: Key words: polypropylene, boron, intumescent flame retardant, thermal analysis, cone calorimeter

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