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中国塑料 ›› 2018, Vol. 32 ›› Issue (02): 10-18.DOI: 10.19491/j.issn.1001-9278.2018.02.002
王悦,祝展聪,周鑫,于守武
收稿日期:
2017-07-31
修回日期:
2017-10-24
出版日期:
2018-02-26
发布日期:
2018-02-26
基金资助:
Received:
2017-07-31
Revised:
2017-10-24
Online:
2018-02-26
Published:
2018-02-26
摘要: 三嗪系成炭剂依据分子构型可分为小分子、线形大分子和超支化大分子,分别介绍了其合成原料、合成工艺和阻燃效果,重点对采用三聚氯氰、三聚氰胺、异氰尿酸及其衍生物等原料制备的成炭剂进行了评述,分析了不同品种成炭剂的优缺点,并对三嗪系阻燃剂的发展方向进行了展望。
中图分类号:
王悦 祝展聪 周鑫 于守武. 三嗪系成炭剂的研究进展[J]. 中国塑料, 2018, 32(02): 10-18.
[1]鲁建,刘柯,王玉忠.三嗪衍生物的合成及其用于的阻燃研究[J].四川大学学报自然科学版, 2002, 39(3):513-517[2]LU Jian, LIU Ke, WANGYu-zhong.Synthesis of Triazine Derivatives and Their Application in Flame-Retardation of ABS[J].Journal of Sichuan University(Natural Science Edition), 2002, 39(3):513-517[3]Xin Wang,Yuan Hu,Lei Song,et al.Effect of a triazine ring-containing charring agent on fire retardancy and thermal degradation of intumescent flame retardant epoxy resins[J].Polymers for Advanced Technologies, 2011, 22(12):2480-2487[4]Lijun Qian,Yong Qiu,Jing Liu,et al.The flame retardant group-synergistic-effect of a phosphaphenanthrene and triazine double-group compound in epoxy resin[J].Journal of Applied Polymer Science, 2014, 131(3):1082-1090[5]彭治汉,邵偲淳,谭逸伦,等.一种含三嗪环的笼状磷酸酯阻燃剂及其制备方法[6]PENG ZHIHAN, SHAO SICHUN, TAN YILUN, et al.Triazine ring containing caged organic phosphate flame retardant and preparation method thereof[7]Yongzhen Wang,Jianqing Zhao,Yanchao Yuan,et al.Synthesis of maleimido-substituted aromatic s-triazine and its application in flame-retarded epoxy resins[J].Polymer Degradation & Stability, 2014, 99(1):27-34[8]王怀芳,朱平,张建波,等.棉织物用三嗪类磷系阻燃剂的制备及应用[J].印染助剂, 2005, 122(09):15-17[9]WANG Huai-fang, ZHU Ping, ZHANG Jian-bo, et al.Preparation and application of triazinyl phosphorus flame retardant for cotton fabrics[J].Textile Auxiliaries, 2005, 122(09):15-17[10]刘胜男,赵培华,李欣航,等.新型三嗪类氮-硅成炭剂的合成及其热稳定性[J].合成化学, 2015, 23(1):27-30[11]LIU Sheng-nan, ZHAO Pei-hua, LI Xin-hang, et al.Synthesis and Thermal Stability of a Novel Triazine-based N-Si Charring Agent[J].Chinese Journal of Synthetic Chemistry, 2015, 23(1):27-30[12]李果,胡新利,俞春雷,等.阻燃剂三嗪三苯基次膦酸乙酯的合成及应用[J].塑料科技, 2015, 43(2):90-94[13]Li Guo, Hu Xinli, Yu Chunlei, et al.Synthesis and Application of Flame Retardant Triazine Triphenyl Phosphinic Ethyl Ester[J].Plastics Science and Technology, 2015, 43(2):90-94[14]王文涛,熊宽宽,赵斌,等.新型无卤硅-氮成炭剂的合成及其热稳定性[J].合成化学, 2016, 24(1):26-29[15]WANG Wen-tao, XIONG Kuan-kuan, ZHAO Bin, et al.Synthesis and Thermal Stability of A Novel Halogen-free Si-N Charring Agent[J].Chinese Journal of Synthetic Chemistry, 2016, 24(1):26-29[16]Wenyan Chen,Shanshan Yuan,Yong Sheng,et al.Effect of charring agent THEIC on flame retardant properties of polypropylene[J]. Journal of Applied Polymer Science, 2015, 132(1)[J].Journal of Applied Polymer Science, 2015, 132(1):1-8[17]王彦林,杨海,李豫丹.三嗪氯代三硅酸酯化合物及其制备方法[J].中国专利, 2012, :-[18]韩虹,王彦林,吴娟,等.三嗪三硅酸氯丙酯阻燃剂的合成研究[J].化学世界, 2015, 56(10):618-621[19]HAN Hong, WANG Yanlin, WU Juan, et al.Study on Synthesis of Triazinenyl Trichloro-propyl Silicate Retardant [J]. Chemical world, 2015, (10): 618-621.[J].Chemical world, 2015, 56(10):618-621[20]Guixun Li,Wanjie Wang,Shaokui Cao,et al.Reactive,intumescent,halogen‐free flame retardant for polypropylene[J].Journal of Applied Polymer Science, 2014, 131(7):2540-2540[21]Jincheng Wang,Guang Li,Shenglin Yang,et al.New intumescent flame‐retardant agent: Application to polyurethane coatings[J].Journal of Applied Polymer Science, 2004, 91(2):1193-1206[22]Ghada Makhlouf,Mohamed Hassan,Mohamed Nour,et al.A Novel Intumescent Flame Retardant: Synthesis and Its Application for Linear Low-Density Polyethylene[J].Arabian Journal for Science & Engineering, 2017, :1-11[23]王雪峰,吴荣梁,孙春梅,等.膨胀型类磷酸酯蜜胺盐阻燃剂的合成及应用研究[J].功能高分子学报, 2005, 17(4):630-634[24]WANG Xue-feng, WU Rong-liang, SUN Chun-mei, et al.Study on the Preparation and Application of Intumescent Flame Retardants Containing Various Phosphates Melamine Salt[J].Journal of Functional Polymers, 2005, 17(4):630-634[25]毋登辉,赵培华,刘亚青.新型磷-氮膨胀型阻燃剂的合成及其热稳定性[J].合成化学, 2013, 21(6):663-666[26]WU Deng-hui, ZHAO Pei-hua, LIU Ya-qing.Synthesis and Thermal Performance of a Novel P-N Intumescent Flame Retardant [J]. Chinese Journal of Synthetic Chemistry, 2013, (06): 663-666.[J].Chinese Journal of Synthetic Chemistry, 2013, 21(6):663-666[27]Bin Li,Miaojun Xu.Effect of a novel charring–foaming agent on flame retardancy and thermal degradation of intumescent flame retardant polypropylene[J].Polymer Degradation and Stability, 2006, 91(6):1380-1386[28]刘克升,李斌.苯氧基三嗪聚合物的合成及膨胀阻燃ABS的研究[J]. 化学与粘合, 2008, (05): 42-46.[J].化学与粘合, 2008, 30(5):42-46[29]LIU Ke-sheng, LI Bin.Synthesis of Phenoxy Triazine Oligomers and Study on Intumescent Hame Retardant ABS[J].CHEMISTRY AND ADHESION, 2008, 30(5):42-46[30]Kun Yang,Miao Jun Xu,Bin Li.Synthesis of N-ethyl triazine–piperazine copolymer and flame retardancy andwater resistance of intumescent flame retardant polypropylene[J].Polymer Degradation & Stability, 2013, 98(7):1397-1406[31]Xiao Ping Hu,Ya Lan Li,Yu Zhong Wang.Synergistic Effect of the Charring Agent on the Thermal and Flame Retardant Properties of Polyethylene[J].Macromolecular Materials & Engineering, 2004, 289(2):208-212[32]Caimin Feng,Yi Zhang,Siwei Liu,et al.Synthesis of novel triazine charring agent and its effect in intumescent flame‐retardant polypropylene[J].Journal of Applied Polymer Science, 2011, 123(6):3208-3216[33]Caimin Feng,Minyi Liang,Jiali Jiang,et al.Synergistic effect of a novel triazine charring agent and ammonium polyphosphate on the flame retardant properties of halogen-free flame retardant polypropylene composites[J].Thermochimica Acta, 2016, (627-629):83-90[34]Caimin Feng,Zongwen Li,Minyi Liang,et al.Preparation and characterization of a novel oligomeric charring agent and its application in halogen-free flame retardant polypropylene[J].Journal of Analytical & Applied Pyrolysis, 2015, (111):238-246[35]刘刚,刘述梅,生启,等.含磷三嗪环聚合物的合成与表征[J].石油化工, 2007, 36(2):173-177[36]Liu Gang, Liu Shumei, Sheng Qi, et al.Synthesis and Characterization of Phosphorus-Containing Triazine Polymer[J]. PETROCHEMICAL TECHNOLOGY, 2007, (02): 173-177.[J].PETROCHEMICAL TECHNOLOGY, 2007, 36(2):173-177[37]D.Enescu,AFrache,M. Lavaselli,et al. Novel phosphorous–nitrogen intumescent flame retardant system. Its effects on flame retardancy and thermal properties of polypropylene[J].Polymer Degradation and Stability, 2013, 98(1):297-305[38]Zhao Zan Xu,Jian Qian Huang,Ming Jun Chen,et al.Flame retardant mechanism of an efficient flame-retardant polymeric synergist with ammonium polyphosphate for polypropylene[J].Polymer Degradation & Stability, 2013, 98(10):2011-2020[39]Xinqing Su,Yuwen Yi,Jie Tao,et al.Synergistic effect between a novel triazine charring agent and ammonium polyphosphate on flame retardancy and thermal behavior of polypropylene[J].Polymer Degradation and Stability, 2014, 105(0):12-20[40]郝冬梅,李旭,林倬仕,等.三嗪类阻燃剂的热性能及成炭机理探索[J].工程塑料应用, 2010, 38(12):8-11[41]Hao Dongmei, Li Xu, Lin Zhuoshi, et al.REACHER ON THERMAL BEHAVIOUR AND CHARRING MECHANISM OFTRIAZINE FLAME RETARANT [J]. Engineering Plastics Application, 2010, (12): 8-11.[J].Engineering Plastics Application, 2010, 38(12):8-11[42]张涛,杜中杰,邹威,等.三嗪类成炭剂的制备及其阻燃聚丙烯的研究[J].中国塑料, 2013, 27(4):80-84[43]ZHANG Tao, DU Zhong-jie, ZOU Wei, et al.Preparation of Novel Triazine-based Charring Agent and Its Flame Retardation on Polypropylene[J].China Plastics, 2013, 27(4):80-84[44]张 涛,杜中杰,邹 威,等.聚磷酸铵/三嗪成炭剂/碳纳米管复配体系对聚丙烯阻燃性的影响[J].塑料, 2013, 42(3):1-4[45]ZHANG Tao, DU Zhong-jie, ZOU Wei, et al.Effect of Ammonium Polyphosphate /Triazine Charring Agent /Carbon Nanotube on Flame Retardancy of Polypropylene[J].Plastics, 2013, 42(3):1-4[46]胡亚鹏,王香梅,李娟.多羟基结构三嗪成炭剂在膨胀阻燃PP中的应用[J].工程塑料应用, 2016, 44(6):99-103[47]Hu Yapeng, Wang Xiangmei, Li Juan.Application of Triazine-Based Charring Agent with Multi-Hydroxyl Group in Intumescent Flame Retardant Polypropylene[J].ENGINEERING PLASTICS APPLICATION, 2016, 44(6):99-103[48]周婷,周红,瞿隽申,等.三嗪阻燃剂的合成、改性及阻燃性能测试[J].塑料科技, 2016, 44(3):98-102[49]Zhou Ting, Zhou Hong, Qu Junshen, et al.Synthesis, Modification and Determination of Flame Retardant Properties of Triazine Flame-retardant[J].Plastics Science and Technology, 2016, 44(3):98-102[50]唐霜,尹昌宇,赖学军,等.三嗪类大分子成炭剂的合成及其在聚丙烯中应用[J].现代塑料加工应用, 2012, 24(4):46-49[51]Tang Shuang, Yin Changyu, Lai Xuejun, et al.Synthesis of Triazine-based macromolecule Charring Agent and Its Application to Polypropylene[J].MODERN PLASTICS PROCESSING AND APPLICATIONS, 2012, 24(4):46-49[52]罗国菁,杨永兵,张伟,等.含硅成炭剂的合成及其在阻燃PP中的应用研究[J].中国塑料, 2011, 25(12):76-80[53]LUO Guojing, YANG Yongbing, ZHANG Wei, et al.Research on Synthesis of Charring Agent Containing Silicon and Its Application in Flame Retarded PP[J].China Plastics, 2011, 25(12):76-80[54]Xuejun Lai,Shuang Tang,Hongqiang Li,et al.Flame-retardant mechanism of a novel polymeric intumescent flame retardant containing caged bicyclic phosphate for polypropylene[J].Polymer Degradation & Stability, 2015, (113):22-31[55]王远月,刘够生.马来酸异氰尿酸酯成炭剂的合成及其对聚丙烯阻燃性能的研究[J].材料导报, 2016, 30(11):83-86[56]WANG Yuanyue, LIU Gousheng.Synthesis of Maleic Isocyanurate Agent and Its Flame Retardancy Properties on Polypropylene[J].Materials Review, 2016, 30(11):83-86[57]Jin,J. Sun,J. S. Zhang,et al..The preparation of a novel intumescent flame retardant based on supramolecular interactions and its application in polyamide 11[J].Acs Applied Materials & Interfaces, 2017, :-[58]Jiandong Zuo,Yikun Su,Shumei Liu,et al.Preparation and properties of FR-PP with phosphorus-containing intumescent flame retardant[J].Journal of Polymer Research, 2011, 18(5):1125-1129[59]Sibdas Singha Mahapatra,Niranjan Karak.s-Triazine containing flame retardant hyperbranched polyamines: Synthesis,characterization and properties evaluation[J].Polymer Degradation & Stability, 2007, 92(6):947-955[60]Chen Hao Ke,Juan Li,Ke Yi Fang,et al.Synergistic effect between a novel hyperbranched charring agent and ammonium polyphosphate on the flame retardant and anti-dripping properties of polylactide[J].Polymer Degradation & Stability, 2010, 95(5):763-770[61]Chenhao Ke,Juan Li,Keyi Fang,et al.Enhancement of a hyperbranched charring and foaming agent on flame retardancy of polyamide 6[J].Polymers for Advanced Technologies, 2011, 22(12):2237-2243[62]Panyue Wen,Xiaofeng Wang,Bibo Wang,et al.One-pot synthesis of a novel s-triazine-based hyperbranched charring foaming agent and its enhancement on flame retardancy and water resistance of polypropylene[J].Polymer Degradation and Stability, 2014, 110(0):165-174[63]Panyue Wen,Xiaofeng Wang,Weiyi Xing,et al.Synthesis of a Novel Triazine-Based Hyperbranched Char Foaming Agent and the Study of Its Enhancement on Flame Retardancy and Thermal Stability of Polypropylene[J].Industrial & Engineering Chemistry Research, 2013, 52(48):17015-17022[64]靳玉娟,高鹏翔,钱立军,等.超支化乙二胺三嗪成炭剂的合成及其阻燃性能研究[J].化工新型材料, 2013, 41(3):94-96[65]Jin Yujuan, Gao Pengxiang, Qian Lijun, et al.Study on the synthesis of hyperbranched ethylene-diamine triazine charring agent and its flame retardation performance[J].NEW CHEMICAL MATERIALS, 2013, 41(3):94-96[66]靳玉娟,高鹏翔,钱立军,等.超支化芳胺三嗪聚合物的合成及其对聚丙烯阻燃性能影响的研究[J].中国塑料, 2013, 27(5):77-81[67]JIN Yujuan, GAOPengxiang, QIAN Lijun, et al.Synthesis of Hyperbranched Aromatic Amine Triazine Polymer and Its Flame Retardation Performance on Polypropylene[J].China Plastics, 2013, 27(5):77-81[68]王宇旋,姜宏伟.交联三嗪类聚合物的制备及其成炭性研究[J].高分子学报, 2009, (04):325-330[69]WANG Yuxuan, JIANG Hongwei.PREPARATION OF TRIAZINE BASED CROSSLINKED POLYMERS AND THEIR CHARRING PROPERTIES[J].ACTA POLYMERICA SINICA, 2009, (4):325-330 |
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