中国塑料 ›› 2012, Vol. 26 ›› Issue (08): 40-44 .DOI: 10.19491/j.issn.1001-9278.2012.08.007

• 材料与性能 • 上一篇    下一篇

NDI型聚氨酯弹性体宏观性能的研究

余成科 付会娟 罗建勋 毛立新 张立群   

  1. 北京化工大学 北京化工大学 北京化工大学材料学院 北京化工大学党委组织部 北京化工大学材料科学与工程学院
  • 收稿日期:2012-04-16 修回日期:1900-01-01 出版日期:2012-08-26 发布日期:2012-08-26

Study on Macroproperties of Polyurethane Elastomer Based on NDI

Chengke YU Huijuan FU Jianxun LUO Lixin MAO Liqun ZHANG   

  • Received:2012-04-16 Revised:1900-01-01 Online:2012-08-26 Published:2012-08-26
  • Contact: Lixin MAO

摘要: 采用预聚物法合成了以聚四氢呋喃醚二醇(PTMG)、1, 5萘二异氰酸酯(NDI)、1,4丁二醇(BDO)、三羟甲基丙烷(TMP)等为主要原料的双组分浇注型聚氨酯弹性体。通过差示扫描量热分析、动态力学性能分析和常规力学性能分析,对NDI型聚氨酯弹性体的性能进行了研究。结果表明,NDI型聚氨酯弹性体有良好的低温柔顺性,动态生热低、储能模量高、力学性能优异;随着预聚物中NCO基含量的增加,软段玻璃化转变温度依次降低,平台区储能模量依次上升,损耗因子逐渐降低,拉伸强度先增大后减小,硬度逐渐升高。

关键词: 1, 5-萘二异氰酸酯, 聚氨酯弹性体, 热性能, 力学性能

Abstract: Casting twocomponent polyurethane elastomers were synthesized with polytetramethylene ether glycols (PTMG), 1,5naphthalene diisocyanate (NDI), 1,4butanediol (BDO), and trimethylolpropane (TMP) as the main precusors. The obtained polyurethane elastomers had superior mechanical properties, good flexibility at low temperature, low dynamic heat, and high storage modulus. With increasing NCO content, the platform modulus and hardness increased, the glass transition temperature of soft segments and the loss factor reduced, while tensile strength first increased and then decreased.

Key words: 1, 5naphthalene diisocyanate, polyurethane elastomer, thermal property, mechanical property

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