中国塑料 ›› 2017, Vol. 31 ›› Issue (2): 34-37 .DOI: 10.19491/j.issn.1001-9278.2017.02.006

• 材料与性能 • 上一篇    下一篇

庚二酸钙改性聚丙烯的力学性能

王亚飞,靳书丛,张思源,赵爽,刘倩,闰明涛   

  1. 河北大学化学与环境科学学院
  • 收稿日期:2016-10-14 修回日期:2016-11-15 出版日期:2017-02-26 发布日期:2017-02-26

Mechanical Properties of Polypropylene Modified by Calcium Pimelate

  • Received:2016-10-14 Revised:2016-11-15 Online:2017-02-26 Published:2017-02-26

摘要: 通过融熔共混的方法制备了β成核剂——庚二酸钙(CaHA)改性的聚丙烯(PP),并测试了其改性效果和力学性能。结果表明, CaHA是一种高效的β成核剂,对促进PP的α晶型向β晶型转变具有显著效果;当加入的CaHA含量为1 %时,PP的改性效果最好,其中冲击强度可达到32.8 kJ/m2,拉伸强度达到38.8 MPa,弯曲强度达到31.6 MPa。

关键词: 聚丙烯, 庚二酸钙, β成核剂, 力学性质

Abstract: A series of polypropylene compounds modified by calcium pimelate (CaHA) were prepared by a meltblending method, and their mechanical performance, thermal properties and fracture surface were investigated extensively. The results indicated that CaHA could well act as a βform nucleating agent to promote a crystalline transformation from αform crystals to the β one in PP. The compounds achieved optimum mechanical performance when 1.0 wt % of CaHA was incorporated into PP, and their impact strength,tensile strength and flexural strength reached 32.79 kJ/m2, 38.8 MPa and 31.6 MPa, respectively.

Key words: polypropylene, calcium pimelate, β nucleating agent, mechanical property