中国塑料 ›› 2014, Vol. 28 ›› Issue (05): 59-63 .DOI: 10.19491/j.issn.1001-9278.2014.05.012

• 材料与性能 • 上一篇    下一篇

碱处理竹纤维对聚酰胺6结构和性能的影响

王春华,周松,朱毅科,邵登全,吴俊杰,肖祥松   

  1. 西南石油大学材料科学与工程学院
  • 收稿日期:2014-01-15 修回日期:2014-02-17 出版日期:2014-05-26 发布日期:2014-05-26

Effect of Alkali Treated Bamboo Fiber on the Structure and Properties of Polyamide 6

  • Received:2014-01-15 Revised:2014-02-17 Online:2014-05-26 Published:2014-05-26

摘要: 采用10 %的(质量分数,下同)NaOH碱溶液对竹纤维进行了处理,通过双螺杆挤出和注射成型制备了聚酰胺6(PA6)/竹纤维复合材料。用扫描电子显微镜﹑差示扫描量热仪、X射线衍射仪和热失重分析仪等表征了材料的形貌、结构和热性能,测试了熔体流动速率和力学性能。研究表明,碱处理可清除竹纤维中的胶质物,增大其比表面积,有利于改善PA6和竹纤维间的界面结合。PA6与竹纤维之间具有较好界面结合,相界面间无明显间隙。竹纤维使复合材料中PA6晶相的完整程度降低,使复合材料刚性增加,冲击强度、熔体流动性和热稳定性下降。在挤出和注射过程中,PA6/竹纤维复合材料较好的熔体流动性和一定的热稳定性使其具有熔体加工性能。

关键词: 聚酰胺6, 竹纤维, 复合材料, 结构, 性能

Abstract: Bamboo fibers(BFs)were treated with 10 % NaOH solution, and polyamide 6/bamboo fiber(PA6/BFs)composites were prepared by a twin screw extruder and an injection molding, and analyzed by SEM, DSC, XRD, TG, and mechanical testing. It demonstrated that BFs provided a larger surface area for leaching out the cementing materials during alkali treatment, which improved the mechanically interlocking between bamboo fibers and the PA6 matrix. BFs had good interfacial adhesion with PA6 matrix without obvious gaps. The presence of BFs resulted in more crystal imperfection of the PA6 component, and the increased stiffness of PA6/BFs composite accompanied by a decrease of impact strength, melt flow index, and thermal stability. The combination of reasonably good melt flow index and thermal stability of PA6/BFs composites ensured the processability of the composites during extrusion and injection molding.

Key words: polyamide 6, bamboo fiber, composite, structure, property