中国塑料 ›› 2008, Vol. 22 ›› Issue (11): 28-32 .DOI: 10.19491/j.issn.1001-9278.2008.11.006

• 材料与性能 • 上一篇    下一篇

PP/PET/MFIAA/HET原位成纤复合材料的力学性能与熔体流动性

刘俊,谷琳,赵典,王经武   

  1. 郑州大学材料科学与工程学院,河南 郑州 450052
  • 收稿日期:2008-01-01 修回日期:1900-01-01 出版日期:2008-11-26 发布日期:2008-11-26

Mechanical properties and Melt-flowability of PP/PET/MFIAA/HET in Situ Fiberized Composites

LIU Jun, GU Lin, ZHAO Dian, WANG Jing-wu   

  1. College of Material Science and Engineering, Zhengzhou University, Henan Zhengzhou 450052, China
  • Received:2008-01-01 Revised:1900-01-01 Online:2008-11-26 Published:2008-11-26
  • Contact: WANG Jing-wu

摘要: 研究了聚对苯二甲酸乙二醇酯(PET)含量、基体性质、成型加工温度对橡纤混杂型PP/PET/多功能界面活化剂(MFIAA)/高效增韧剂(HET)原位成纤复合材料力学性能和熔体流动性的影响。结果表明,MFC、HET用量不变,PET含量增大,微纤的数量增加,长径比增大,复合材料的刚性提高,韧性有所降低;基体PP的熔体流动速率增大,有利于PET微纤在制品中的保持,基体熔体流动速率为16.2 g/10min时,复合材料的缺口冲击强度、拉伸强度和弯曲模量分别达到原料PP的3.49倍、99 %和1.73倍,韧性显著提高的同时刚性保持率也很高;受熔体流动性和分散相形态的双重控制,PP/PET/MFIAA/HET较为适宜的成型加工温度为(200±10) ℃。PET微纤是造成PP/PET/MFIAA/HET流动阻抗增加的主要原因,随着PET含量的增大,复合材料的熔体流动性急剧降低。

关键词: 原位成纤, 聚丙烯, 聚对苯二甲酸乙二醇酯, 力学性能, 熔体流动速率

Abstract: Influence of the content of PET, properties of matrix, and prosessing temperature on the mechanical and rheological behavior of PP/PET/MFIAA/HET composites was studied. With PET content increased, the number and fine degree of PET micro-fibril increased, which resulted in higher rigidity of the composite but lower toughness. Using PP having a high melt flow rate as the matrix was very beneficial to maintain the microfibril morphology of in situ fiberized composite sample. When using a PP matrix with melt flow rate of 16.2 g/10min, the notched Izod impact strength, tensile yield strength, and flexural modulus of PP/PET/MFIAA/HET with the matrix were 3.49, 0.99, and 1.73 times, respectively, those of neat PP. Effected by both melt-flowability and morphology of the disperse phase, the optimum prosessing temperature for PP/PET/MFIAA/HET should be (200±10)℃. PET microfibril constituted the main reason of the composite melt flow resistance, increasing the content of PET microfibril, the melt-flowability of PP/PET/MFIAA/HET falls rapidly.

Key words: in situ fiberized, polypropylene, poly(ethylene terephthalate), mechanical property, melt flow rate