中国塑料 ›› 2011, Vol. 25 ›› Issue (04): 98-101 .DOI: 10.19491/j.issn.1001-9278.2011.04.023

• 标准与测试 • 上一篇    下一篇

一种新型聚合物熔体动态密度测量方法的研究

韩科 李增和 许红 吴大鸣   

  1. 北京化工大学 北京化工大学 北京化工大学
  • 收稿日期:2010-11-23 修回日期:1900-01-01 出版日期:2011-04-26 发布日期:2011-04-26

Study on Measurement Method for Dynamic Density of Polymer Melts

HAN Ke LI Zenghe XU Hong WU Daming   

  • Received:2010-11-23 Revised:1900-01-01 Online:2011-04-26 Published:2011-04-26
  • Contact: XU Hong

摘要: 介绍一种聚合物熔体在不同温度及压力状态下熔体密度的测量方法,该方法基于聚合物熔体PVT相互关系原理,将测量微距离的读数百分表安装在改进结构的熔体流动速率试验机上,可以测量出任意熔融温度及压力下的聚合物熔体密度。通过对测量结果进行理论分析发现,聚合物熔体密度测量值符合聚合物自由体积理论,即聚合物熔体密度随温度升高而减小,随压力增大而增大。

关键词: 聚合物, 熔体密度, 熔体流动速率, 活塞行程梯度, 熔体温度, 测量方法, 压力

Abstract: A new measurement method for polymer melt density under different pressure and temperature was established. Based on the PVT theory of polymer melt, a melt flow rates tester was modified with a dial indicator for the measurement of the micro distance. With the modified instrument, polymer melt density can be measured under any pressure and melting temperature. By further analyzing the result, the data of the melt density was agreed with the free volume theory, i.e., the polymer melt density decreased with increasing temperature and increased with increasing pressure.

Key words: polymer, melt density, melt flow rate, piston travel distance gradient, melt temperature, measurement method, pressure