中国塑料 ›› 2008, Vol. 22 ›› Issue (08): 85-89 .DOI: 10.19491/j.issn.1001-9278.2008.08.018

• 助剂 • 上一篇    下一篇

不同硅烷偶联剂在聚丙烯/KD膨胀型阻燃剂复合体系中的作用研究

马志领,李洪恩,韩捷   

  1. 河北大学化学与环境科学学院,河北保定071002
  • 收稿日期:2008-01-09 修回日期:1900-01-01 出版日期:2008-08-26 发布日期:2008-08-26

Effect of Different Silane Coupling Agents in Polypropylene/KDIFR Composites

MA Zhi-ling,L I Hong-en,HAN Jie   

  1. College of Chemistry and Environmental Science of Hebei University, Banding 071002, China
  • Received:2008-01-09 Revised:1900-01-01 Online:2008-08-26 Published:2008-08-26
  • Contact: MA Zhi-ling

摘要: 考察了硅烷偶联剂(KH-SSO,KH-560)在聚丙烯( PP) /KD膨胀型阻燃剂(KDIFR)复合体系中的偶联作用。X射线衍射研究表明,KDIFR可促进PP形成R晶,KH-550增强KDIFR粒子的R成核作用,而KH-560则降低这种作用。扫描电镜分析表明硅烷偶联剂的加人使粒子与基体间的薪结作用增强。偏光显微镜分析表明,随着硅烷偶联剂的增加,球晶的大小趋于一致,KDIFR的分散趋于均匀。KH-550和KH-560的加人均可提高复合体系的力学性能,PP/KDIFR/KH-560 = 70 /30 /5(质量份数,下同)复合体系综合性能最佳,冲击强度和拉伸强度比PP/KDIFR分别提高了24.2%和9.6%。阻燃性能的测试结果表明硅烷偶联剂的加人可提高材料的阻燃性。

关键词: 聚丙烯, 膨胀型阻燃剂, 硅烷偶联剂, R成核, 球晶

Abstract: The influence of silane coupling agent KH-550 and KH-560 on the structure and properties ofpolypropylene(PP)/intumcsccnt flame-rctardant(KDIFR) composites was studied. X-ray diffraction(XRD)indicated that KDIFR promoted the formation of俘一form PP,which was strengthened by KH-550,but weakened by KH-560.SEM showed that the adhesion between KDIFR and PP was enhanced by the silanes. POM showed that the size of the spherulites of PP and the dispersion of KDIFR particles became more uniform with the increasing silane content. The mechanical properties of the composites were also improved.八recipe of PP/KDIFR/KH-560二70}30}5 was found to be optimal,the impact and tensile strengths were increased by 24. 2%and 9. 6%,rc}spectivcly, compared with neat PP/KDIFR eompcasites. The flame retardancy of the eompcasites was also improvcxl when silane was added.

Key words: polypropylene, intumescent flame-retardant, silane coupling agent, (3-nucleation, sphcrulitc