China Plastics ›› 2010, Vol. 24 ›› Issue (07): 28-33 .DOI: 10.19491/j.issn.1001-9278.2010.07.006

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Preparation of Polyaniline/ Schiff Base Nanorods Composites and Their Conductive Properties

DUAN Guochen QI Shuhua WU Xinming QI Haiyuan ZHANG Yi   

  • Received:2010-01-05 Revised:1900-01-01 Online:2010-07-26 Published:2010-07-26

Abstract: Polyaniline/schiff base composites were prepared via seeding polymerization. The influence of Schiff base dosage, concentration of acid and the organic medium on the properties of composites was investigated. Structure and morphology of the composites were characterized using FTIRUV-Vis and SEM. It was demonstrated that the conductivity of polyaniline/schiff base composite could reach 1.201S/ cm. In comparison with polyaniline (9.21×10-6 S/cm), its conductivity increased by the order of magnitude of six at room temperature, under the condition of 15 % schiff base, 2 mol/L HCl concentration and in Ethylene glycol. In addition, the dispersion and heat resistance properties of polyaniline/schiff base were better than that of polyaniline obviously.

Key words: polyaniline, schiff base, conductivity, nanorod, composite