Effect of Suberic Acid/Calcium Stearate Bi-component Nucleating Agent on β Crystal in Isotactic Polypropylene

doi:10.19491/j.issn.1001-9278.2010.07.017

China Plastics ›› 2010, Vol. 24 ›› Issue (07): 78-82 .DOI: 10.19491/j.issn.1001-9278.2010.07.017

Previous Articles Next Articles

Effect of Suberic Acid/Calcium Stearate Bi-component Nucleating Agent on β Crystal in Isotactic Polypropylene

XUE Jianfeng DOU Qiang

Received:2010-03-25 Revised:1900-01-01 Online:2010-07-26 Published:2010-07-26

Abstract

Abstract: Isotactic polypropylene (iPP) containing a binary nucleating agent of suberic acid/calcium stearate (SA/CaSt) was isothermally crystallized at 120 ℃ for 30 min in order to study the influence of the latters on the content of β crystals. It was found that when SA contents was 0.15 % and that of CaSt was more than 0.525 %, β crystals were observed in iPP. When CaSt contents were 0.675 %, β crystals contents showed a maximum. Analysis of FTIR indicated that an in situ chemical reaction occured between SA and CaSt during the melting blending, and a high effective β nucleating agent (calcium suberate) was produced.

Key words: β crystal, suberic acid, calcium stearate, nucleating agent, polypropylene

XUE Jianfeng DOU Qiang. Effect of Suberic Acid/Calcium Stearate Bi-component Nucleating Agent on β Crystal in Isotactic Polypropylene[J]. China Plastics, 2010, 24(07): 78-82 .

[1]	ZHANG Lin, XIA Zhangchuan, HE Yadong, XIN Chunling, WANG Ruixue, REN Feng. Influence of gas flow of plasma jet carrier on modification effect for glass fiber [J]. China Plastics, 2022, 36(9): 7-15.
[2]	ZHANG Bing. Study on test of oxidation induction time for random copolymer polypropylene pipe [J]. China Plastics, 2022, 36(8): 107-109.
[3]	ZHAO Hongjing, ZHU Jiang. Study on numerical simulation of two⁃phase extrusion for micro/nano⁃laminated natural rubber/polypropylene [J]. China Plastics, 2022, 36(8): 110-114.
[4]	LIU Yi, WANG Ye, SUN Wei, QU Guoxing, XU Xia, YANG Shaolin, YUAN Ning. Determination of content of transparent nucleating agent in polypropylene using infrared spectroscopy [J]. China Plastics, 2022, 36(8): 115-118.
[5]	ZHANG Taozhong, CHEN Xiaolong, HAO Xiaoyu, YU Fujia. Comparison of mechanical properties and interfacial interactions of polypropylene composites filled with talc， calcium carbonate， and barium sulfate [J]. China Plastics, 2022, 36(8): 36-41.
[6]	WU Wei, HU Huanbo, SHEN Hui, ZHAO Tianyu. Dual⁃synergistic effect of 4A zeolite and Ca⁃Mg⁃Al hydrotalcite on intumescent flame retardant PP and its mechanism [J]. China Plastics, 2022, 36(7): 1-7.
[7]	YU Changyong, XIN Zhong. Effect of α/β complex nucleating agent based on hexahydrophthalate on properties of polypropylene [J]. China Plastics, 2022, 36(7): 121-128.
[8]	LIU Yi, SUN Wei, QU Guoxing, WANG Ye, YUAN Ning, YANG Shaolin, XU Xia, CHANG Xiaoyi, ZHANG Yufei. Structure and performance analysis of transparent polypropylene special material for thin⁃wall injection molding [J]. China Plastics, 2022, 36(7): 37-43.
[9]	SUN Wei, LIU Yi, LIAO Yunlong, CHEN Junjia. Study on influence factors for determination of ethylene content in polypropylene powder [J]. China Plastics, 2022, 36(6): 54-59.
[10]	WANG Qingsong. Development of glass⁃fiber⁃reinforced polypropylene with high strength and low VOC [J]. China Plastics, 2022, 36(4): 30-34.
[11]	WANG Fuyu, GUO Jinqiang, ZHANG Yuxia. In⁃situ fibrillation methods of polymer blends and their application in PP⁃based blends [J]. China Plastics, 2022, 36(3): 146-156.
[12]	LI Rui, JIANG Yanfeng, WU Shuang, AN Yanjie, JIANG Zeyu, ZHANG Mingqiang. Microstructure and thermal characterization of polypropylene special material for cast films through temperature rising elution fractionation [J]. China Plastics, 2022, 36(3): 53-57.
[13]	CAO Zhifeng, ZHAO Lipin, HE Ting, MA Baijun. Preparation and properties of five⁃layer co⁃extrusion barrier films [J]. China Plastics, 2022, 36(3): 64-68.
[14]	ZHAI Yujiao, XIN Chunling, HE Yadong, YAN Baorui, QIAO Linjun. Study on process parameters for filling process of polypropylene microcellular injection molding under supercritical N₂ [J]. China Plastics, 2022, 36(3): 69-74.
[15]	SONG Renda, WU Gaojian, CHEN Junxiang, ZHANG Youchen, YANG Weimin, XIE Pengcheng. Preparation and its electromagnetic shielding performance of PP/PET/CNTs foaming composites [J]. China Plastics, 2022, 36(2): 1-7.

Effect of Suberic Acid/Calcium Stearate Bi-component Nucleating Agent on β Crystal in Isotactic Polypropylene

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments