China Plastics ›› 2010, Vol. 24 ›› Issue (12): 36-41 .DOI: 10.19491/j.issn.1001-9278.2010.12.007

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Study on Properties and Morphology of PA6/POE Blends Compatibized by POE Grafted Itaconic Acid

Xijun LIU Baoqing HOU   

  • Received:2010-07-21 Revised:2010-10-11 Online:2010-12-26 Published:2010-12-26

Abstract: In this paper, a series of ethylene-octene copolymer graft (POE-g-ITA) was prepared via melt grafting technique using a twin screw extruder. The grafted product was characterized uisng FT-IR,and the effect of the loading of itaconic acid initiator on the graft ratio and melt flow rate of POE-g-ITA were studied. The graft ratio of POE-g-ITA reached 1.36% when POE/ITA/DCP is 94/6/0.36. The obtained POE-g-ITA was introduced into PA6/POE blends through twin screw extruder. The mechanical properties and morphological structure of the blends were investigated. The impact strength of the PA6/POE blend containing 5 phr POE-g-ITA was 12.78 times higher than neat PA 6. The interface between PA 6 and POE phases became indistinct and the dispersion phase size significantly reduced, the interface interaction was markedly enhanced and the compatibility was significantly increased.

Key words: morphological structure, polyamide 6, ethylene-octene copolymer, itaconic acid, mechanical properties