Study on Non-isothermal Crystallization Kinetics of POM/TPU Blends

doi:10.19491/j.issn.1001-9278.2008.07.008

China Plastics ›› 2008, Vol. 22 ›› Issue (07): 42-46 .DOI: 10.19491/j.issn.1001-9278.2008.07.008

Previous Articles Next Articles

Study on Non-isothermal Crystallization Kinetics of POM/TPU Blends

LIU Chun-lin，ZHOU Ru-dong，DING Yong-hong，WU Dun

1 .School of Materials Science and Engineering, Jiangsu Polytechnic University, C;hangzhou 213164，China;2. Polyrmer Materials Key Lab of C;hangzhou, C;hangzhou 213164，China

Received:2008-03-07 Revised:1900-01-01 Online:2008-07-26 Published:2008-07-26

Abstract

Abstract: The non-isothermal crystallization behavior of POM and POM/TPU blends were investigated by differential scanning calorimetry (DSC).The Jeziorny, Ozawa, and Mo methods were employed to analyze the DSC data. The results showed that the width of the crystallization peak was broadened，the
crystallization temperature(Tc) decreased with increasing cooling rate.At the same cooling rate, Tc of the blends was higher than that of neat POM. Jeziorny method could well he used to treat the nonisothermal crystallization. It showed that TPU increased the crystallization rate, decreased the half crys-tallization time(t1/2)，and changed the nucleating mechanism during crystallization of POM. However,Ozawa method did not fit the polymer blends, because it ignored the influence of secondary crystalliza-tlon.

Key words: polyoxymethylene, thermoplastic polyurethane clastomer, non-isothermal crystallization

LIU Chun-lin, ZHOU Ru-dong, DING Yong-hong, WU Dun. Study on Non-isothermal Crystallization Kinetics of POM/TPU Blends[J]. China Plastics, 2008, 22(07): 42-46 .

[1]	FENG Kai, LI Yongqing, MA Xiuqing, HAN Ying. Research progress and application in toughening modification of polyoxymethylene [J]. China Plastics, 2022, 36(7): 157-164.
[2]	. Study on Preparation and Crystallization of Polyoxymethylene/Poly(ethylene glycol)-Grafted Multiwalled Carbon Nanotubes Composites [J]. China Plastics, 2019, 33(1): 17-23.
[3]	. Study on Non-isothermal Crystallization Kinetics of Polypropylene Matrix Composites with Maleic Anhydride-grafted Polypropylene and Waste Printed Circuit Boards Nonmetallic Powders [J]. China Plastics, 2018, 32(07): 72-77.
[4]	. Preparation and Properties of Reinforced POM/TPU Composites with Potassium Hexatitanate Whiskers [J]. China Plastics, 2017, 31(06): 41-45 .
[5]	. Study on Non-isothermal Crystallization Kinetics of Polyoxymethylene/Polypropylene Blends Used for Catalytic Skim Binder of Metal Powder Injection Molding [J]. China Plastics, 2017, 31(04): 45-50 .
[6]	. Effect of Lacquer-seed-shell-fiber Content on Mechanical and Tribological Properties of Polyoxymethylene/Basalt Fiber Composites [J]. China Plastics, 2017, 31(04): 40-44 .
[7]	. Mechanical Properties, Thermal Characteristics and Crystallization Behaviors of Polyoxymethylene/Surface-modified Silica Nanocomposites Compounds [J]. China Plastics, 2017, 31(03): 46-52 .
[8]	. Study on Mechanical Properties of Recycled Polyoxymethylene/Modified Bamboo Fiber Composites [J]. China Plastics, 2016, 30(12): 91-96 .
[9]	. Properties of Flame-retarded POM Based on Caged-phosphate and Microcapsulated Red Phosphorus [J]. China Plastics, 2016, 30(07): 82-87 .
[10]	. Research Progress in Reinforced Modification of Polyoxymethylene [J]. China Plastics, 2015, 29(09): 6-11 .
[11]	. Preparation and Properties of POM/Elastomer/Nano-CaCO3 Composites [J]. China Plastics, 2015, 29(04): 58-63 .
[12]	. Effect of Fe2O3-coated Mica on Non-isothermal Crystallization Kinetics of PET [J]. China Plastics, 2014, 28(05): 37-41 .
[13]	Zheng Zhen-Chao . Study on Non-Isothermal Crystallization Kinetics of PTFE/POB Composites [J]. China Plastics, 2014, 28(03): 33-39 .
[14]	. Study on the Behavior of Melting and Non-Isothermal Crystallization of PE-LLD/GB Composites [J]. China Plastics, 2014, 28(03): 46-53 .
[15]	. Nonisothermal Crystallization Kinetics of PPR with Amide βnucleating Agents [J]. China Plastics, 2014, 28(02): 59-63 .

Study on Non-isothermal Crystallization Kinetics of POM/TPU Blends

Knowledge

Abstract

Cite this article

share this article

References

Related Articles 15

Recommended Articles

Metrics

Comments