China Plastics ›› 2012, Vol. 26 ›› Issue (10): 31-35 .DOI: 10.19491/j.issn.1001-9278.2012.10.004

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Effect of Chain Extender and Crosslinking Agent on the Properties of Polyurethane Elastomer Based on NDI

Huijian FU Chengke YU Jianxun LUO Lixin MAO Liqun ZHANG   

  • Received:2012-05-02 Revised:2012-06-05 Online:2012-10-26 Published:2012-10-26

Abstract: A series polyurethane elastomers was obtained through curing a prepolymer prepared from 1,5naphthalene diisocyanate (NDI) and polytetramethyleneetherglycol(PTMG), with trihydroxy polyether polyols(330N) as a crosslinking agent and a 1,4butanediol(BDO) as a chain extender. The effect of the crosslinking agent and chain extender on the properties of polyurethane elastomer based on NDI(NDIPUE) was discussed. With increasing contents of 330N, the glass transition temperature for soft segment of NDIPUE increased, the storage modulus decreased between 0 ℃ and 150 ℃, tensile strength and elongation at break of the NDIPUE increased firstly and then decreased; and its hardness went down also.

Key words: polyurethane elastomer, 1, 5naphthalene diisocyanate, trihydroxy polyether polyols, thermal property, mechanical property