Current research status in natural polymer biodegradable mulching films

Abstract

Abstract: This paper reviewed the research status in biodegradable solid agricultural mulches， such as starch， plant fiber and lignin as raw material， according to the mechanical properties of the mulches which can meet the requirement of mechanical laying strength. The difficulties in the development of biodegradable mulching films were proposed， and the future development direction of biodegradable mulching films was prospected. The paper can provide a technical basis for the development and performance improvement of biodegradable plastic film materials.

Key words: natural polymer, biodegradability, agricultural mulch

References

[1] Kasirajan, S.,Ngouajio, M.. Polyethylene and biodegradable mulches for agricultural applications: a review [J]. Agronomy for Sustainable Development,2012,32(2): 501-529.
[2] Wang Yong Peng, Li Xiao Gang, Zhu Jing, et al. Multi-site assessment of the effects of plastic-film mulch on dryland maize productivity in semiarid areas in China[J]. agricultural and forest methorology, 2016,220:160-169.
[3] 王频.残膜污染治理的对策和措施[J].农业工程学报,1998,14(3):185-188.
[4] 国家技术监督局.GB13735-1992 聚乙烯吹塑农用地面覆盖薄膜[S].北京：中国标准出版社,1993.
[5]叶永成,白福臣,于恺.我国农膜技术的发展方向[J].塑料工业,2002,30(6):1-3.
[6] 张建军,郭天文,樊廷录,等.农用地膜残留对玉米生长发育及土壤水分运移的影响[J]. 灌溉排水学报,2014,33(1):100-102.
[7] Zacharias Steinmetz, Claudia Wollmann, Miriam Schaefer,et.al.. Plastic mulching in agriculture. Trading short-term agronomic benefits for long-term soil degradation[J]. Science of the Total Environment, 2016,550:690-705.
[8] 陈诗江,王清文. 生物降解高分子材料研究及应用[J]. 化学工程与装备, 2011(7): 142-144.
[9] 何乐,陈复生,刘伯业. 天然高分子可降解材料的研究与发展[J]. 化工新型材料,2011，39(5):4-6,14.
[10] 黎先发. 可降解地膜材料研究现状与进展[J].塑料,2004,33(1):76-81.
[11] 徐明双,李青山,刘冬. 可降解塑料的研究进展[J]. 塑料制造, 2009,(5): 81-85.
[12] 汪秀丽,张玉荣,王玉忠.淀粉基高分子材料的研究进展[J].高分子学报，2011(1):24-37.
[13] Shah, A. A., Hasan, F., Hameed, ,et al. Biological degradation of plastics: a comprehensive review. Biotechnol. Adv.,2008(26), 246-265.
[14] Felix H. Otey, Richard P. Westhoff. Degradable starch-based agricultural mulch film[P].US:3949145，1976-04-06.
[15] Felix H. Otey, Richard P. Westhoff. Biodegradable film compositions prepared from starch and copolymers of ethylene and acrylic acid [P].US:4133784，1979-09-1.
[16] Felix H. Otey, Richard P. Westhoff. Biodegradable starch-based blown films[P].US:4337181，1982-06-29.
[17] Maruyama, Hitoshi. Agricultural mulching film[P]. JP:JPH03262421,1991-11-22.
[18] 叶永成.可控光和生物双降解除草农用地膜[P].CN:95108803.3,1995-08-28.
[19] Pete Halley, Rulande Rutgers, Steve Coombs,et al. Developing biodegradable mulch films from starch-based polymers. Starch-Starke,2001(53), 362-367,
[20] Tsukushi, Kenmon. Agricultural film [P]. JP:2002119152,2002-04-23.
[21] 黎先发,周建.淀粉基可降解农膜的性能研究[J]. 广西轻工业,2007(4):22-23.
[22] Yachuan Zhang, J. H. Han,G. N. Kim. Biodegradable Mulch
Film Made of Starch-Coated Paper and Its Effectiveness on Temperature and Moisture
Content of Soil[J. Communications in Soil Science and Plant Analysis, 2008,39(7-8):1026-1040.
[23] 宁夏绿环生物降解制品开发有限公司. 环保型可控降解农用地膜及其制备方法[P]. CN:102408587B，2012-11-28.
[24] 蒋瑞萍,谢畅,孔杰,等.淀粉/EAA/PE可控降解保水地膜的研制[J].塑料,2013,42(3):62-64,112.
[25] 佛山市衡龙科技有限公司. 一种复合全降解农用地膜材料及其制备工艺[P]. CN :102329435 B，2014-04-16.
[26] Dafu Wei, Hao Wang, Huining Xiao,et al.. Morphology and mechanical properties of poly(butylene adipate-co-terephthalate)/potato starch blends in the presence of synthesized reactive compatibilizer or modified poly(butylene adipate-co-terephthalate). Carbohydr. Polym.,2015(123), 275-282.
[27] 常州龙骏天纯环保科技有限公司. 一种可完全生物降解农用地膜及其制备方法[P]. CN:104861402A，2015-05-13.
[28] 青岛农业大学. 一种二氧化碳基聚合物/ 改性淀粉可降解农用地膜及其制备方法[P]. CN:104910603 A，2015-09-06.
[29] 太仓市天合新材料科技有限公司. 一种生物降解农用地膜新材料[P]. CN：105218870 A，2015-10-30.
[30] 桐城市华猫软膜有限公司. 一种可降解环保农用地膜及其制备方法[P]. CN：106009062 A，2016-06-23.
[31] 江苏省农业科学院. 一种淀粉基可降解农用地膜及其制备方法[P]. CN 103980548 B，2016-06-15.
[32] Jaisankar S N, Lakshinarayana Y, Radhakrishnan G. Compatibility of Poly(Vinyl Chloride-Vinyl Acetate)/Polyester-Based Polyurethane Blends[J]. Polymer International，1997，43(4) ：368-372.
[33] Kang T K，Kim Y，Cho W J，et al. Effects of Amorphous Nylon on the Properties of Poly(Butylene Terephthalate) and 70/30 Poly(Butylene Terephthalate)/Nylon 6 Blends[J].Polymer Engineering & Science，1996，36(20)：2525-2533
[34] Worner C，Muller P，Mulhaupt R. Toughened Poly(Butylene Terephthalate)s and Blends Prepared by Simultaneous Chain Extension, Interfacial Coupling, and Dynamic Vulcanization Using Oxazoline Intermediates[J].Journal of Applied Polymer Science，1997，66(4) ：633-642.
[35] Jacob J，Ramaswamy M，Mrinal B. Evaluation of Compatibly and Properties of Biodegradable Polyester Blends[J]. Journal of Polymer Science：Part A：Polymer Chemistry，2002，40(12) ：2003-2014.
[36] 赖小娟,李小瑞,李刚辉.甲基纤维素/聚酰胺可生物降解膜的制备及其性能[J].中国塑料,2005(12):60- 63.
[37] 沈一丁,赖小娟,王磊.聚乳酸/乙基纤维素复合膜的制备及其性能[J].复合材料学报,2007(3):40- 44.
[38] 陈国华,高复生.甲壳素钠/羧甲基纤维素钠共混复合纳滤膜的制备及性能研究[J].中国海洋大学学报(自然科学版),2007(3):507- 511.
[39]周景辉,朱宏伟. 环保型纸基麻地膜的试制[J].中国造纸学报,2003,18(2):101-105.
[40]朱宏伟. 红麻全秆农用麻地膜的研制[D].大连轻工业学院,2006.
[41]王朝云,吕江南,欧阳清,等. 环保型麻地膜的试制[J].纺织学报,2008,29(3):42-46.
[42]韩永俊,陈海涛,刘丽雪,等. 水稻秸秆纤维地膜制造工艺参数优化[J]. 农业工程学报,2011,27(3):242-247.
[43] 袁巧时,陈海涛,韩永俊,等.玉米秸秆纤维制造可降解地膜工艺参数优化[J].黑龙江造纸，2011(2):1-5.
[44] 李丽霞，纪文义，陈海涛，等. 大豆秸秆纤维制造可降解地膜工艺参数优化[J]. 农业工程学报,2013,29(14) :220-226.
[45] 陈海涛，明向兰，刘爽，等. 废旧棉与水稻秸秆纤维混合地膜制造工艺参数优化[J]. 农业工程学报,2015,31(13):292-300.
[46] 盛伟,罗军,葛明桥.纸基棉短绒地膜的研制与表征[J].产业用纺织品，2009(3):9-12.
[47] 张燕杰，罗军，葛明桥. PVA浸渍纸基棉质地膜的制备与表征[J].纺织学报,2012,33(9):31-34.
[48 张燕杰，罗军，葛明桥. 完全降解纸基棉质地膜的制备及性能研究[J]. 产业用纺织品，2011(11):5-9.
[49] 方丽娜，黄晨，杜兆芳,等.丝棉非织造布用于农用地膜的研究[J].产业用纺织品，2006(7):27-31.
[50] 黄晨，韩晓建，方丽娜,等.浸渍粘合法制备棉丝非织造地膜及其性能表征[J].纺织学报,2007,28(12):54-57.
[51] 穆环珍,刘晨,郑涛,等.木质素的化学改性方法及其应用[J].农业环境科学学报,2006,25(1):26.
[52] 邱学青，蔡振和，杨东杰. 木质素磺酸钠Langmuir-Blodgett膜的制备与表征[J].高等学校化学工程学报, 2014,28(5): 1112-1118.
[53] 邓永红，郭运清，邱学青，等. 木质素改性产物的吸附与分散性能[J].华南理工大学学报(自然科学版), 2014,42(10): 63-69.
[54] 徐冠豪,任世学,方桂珍. 聚乙烯醇聚合度对碱木质素/聚乙烯醇共混膜力学性能的影响[J].生物质化学工程, 2013,47(5):1-6.
[55] 郭建国,张玉苍,孙岩峰. 木质素磺酸盐/LLDPE复合材料性能研究[J].塑料工业, 2011,39(2): 97-99，109.
[56] 陈夫山,王帅.木质素基环保地膜的研究[J].造纸科学与术,2014,33(2):88-91.
[57]　中野准三.木质素的化学-基础与应用[M].北京:轻工业出版社,1988.
[58] ASTM D 5988-2003, Standard Test Method for Determining Aerobic Biodegradation in Soil of Plastic Materials or Residual Plastic Materials After Composting, Edition:2003
[59] ISO 17556:2003, Plastics—Determination of the ultimate aerobic biodegradability in soil by measuring the oxygen demand in a respirometer or the amount of carbon dioxide evolved, International Organization for Standardization, Edition:2003.
[60] NF U52-001: Biodegradable materials for use in agriculture and horticulture-mulching products-Requirements and test methods, Edition:2005.