Preparation and adsorption properties of chitosan/polyaniline⁃GO nicotine molecule⁃imprinted composites

doi:10.19491/j.issn.1001-9278.2024.07.006

Abstract

Abstract:

Chitosan （CS）/polyaniline （PANI）⁃graphene oxide （GO） nicotine⁃imprinted composites with anti⁃swelling properties were prepared through cross⁃linking CS and PANI with GO. The swelling rate of the CS/PANI⁃GO nicotine⁃imprinted composite was 2.7 % after soaking in water for 10 h. Nicotine as an adsorbent exhibited an adsorption capacity of 198 mg/g. Meanwhile， the selective adsorption capacity of the adsorbent was studied， and nornicotinine and cotinine were found to obtain adsorption selectivities of 2.97 and 2.4， respectively， indicating good nicotine specific adsorption performance.

Key words: molecularly imprinted composite, nicotine, adsorption, chitosan, graphene oxide

CLC Number:

TQ 325

WEI Jia, LIU Kai, PENG Lijuan, TIAN Yangyang, ZHAO Lin, LI Yanhong, YANG Peipei, LI Songwei, LU Bo. Preparation and adsorption properties of chitosan/polyaniline⁃GO nicotine molecule⁃imprinted composites[J]. China Plastics, 2024, 38(7): 32-36.

Figures/Tables 6

Fig.1. FTIR of GO， CS and CS2/PANI⁃GO

Fig.2. Swelling ratio of molecularly imprinted PANI⁃GO and CS x /PANI⁃GO

Fig.3. Effects of pH and adsorption time on nicotine adsorption by GO， PANI⁃GO and CS2/PANI⁃GO， quasi⁃primary and quasi⁃secondary kinetic models

Fig.4. CS2/PANI⁃GO adsorption thermodynamic curve and Langmuir model

Fig.5. Adsorption properties of nicotine and cotinine on imprinted and non⁃imprinted polymers

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