中国塑料 ›› 2008, Vol. 22 ›› Issue (02): 47-51 .DOI: 10.19491/j.issn.1001-9278.2008.02.010

• 加工与应用 • 上一篇    下一篇

稀土复合偶联剂对氢氧化铝的改性及其在聚丙烯中的应用研究

周卫平,朱庆英,林文彪,张己兰   

  1. 惠州学院化学工程系,广东惠州516015
  • 收稿日期:2007-08-21 修回日期:1900-01-01 出版日期:2008-02-26 发布日期:2008-02-26

Surface Modification of Aluminum Hydroxide by Rare Earth Complex Coupling Agent and its Application in Polypropylene

ZHOU Wei-ping,ZHU Qing-Ying,LIN Wen-biao,ZHANG Ji-lan   

  1. Chemical Engineering Department,Huizhou University, Huizhou 516015, China
  • Received:2007-08-21 Revised:1900-01-01 Online:2008-02-26 Published:2008-02-26
  • Contact: ZHOU Wei-ping

摘要: 选用稀土复合偶联剂和有机硅烷、钛酸酯等常用偶联剂分别对氢氧化铝进行改性并比较其改性效果,结果表明,用稀土复合偶联剂改性氢氧化铝的效果最好,其活化指数由0上升至99%以上,吸油值从0. 4214g电降至0.247 0 g电,说明氢氧化铝改性后表面已从亲水的强极性转为疏水的非极性,与聚合物的相容性明显改善。利用差热分析技术测定热初始分解温度发现,氢氧化铝改性后热初始分解温度显著提高,达到249℃,从而拓宽了其在聚合物阻燃中的应用范围。与用其他偶联剂改性相比,应用于聚丙烯时,稀土复合偶联剂能显著改善材料的断裂伸长率和冲击性能:在填充大量氢氧化铝时,其断裂伸长率比未改性的聚丙烯/氢氧化铝复合体系提高了5.24倍,比纯聚丙烯体系提高了59.6;冲击韧性比未改性的聚丙烯/氢氧化铝复合体系提高了17. 7,比纯聚丙烯体系提高了14. 8%。聚丙烯体系中加人氢氧化铝后阻燃性能提高,经偶联剂改性后效果更佳。

关键词: 稀土复合偶联剂, 氢氧化铝, 表面改性, 聚丙烯

Abstract: Aluminum hydroxide was modified with rare earth complex coupling agent and the performance of the product was compared with those modified with other coupling agents including silane and titanate. Modified with rare earth complex, the activation index increased from zero to 99%,while the oil absorption value falls from 0.4214g to 0.2747g,which indicated that the surface of aluminuet hydroxide was transformed to hydrophobic. Measured by differential thermal analysis, the initial thermal decomposition temperature of aluminum hydroxide was increased to 249 C .the elongation at break of polypropylene (PP) containing rare earth complex modified Al (OH):was 5 .24 times higher than that containing unmodified Al(OH)3,and was 59 .5%higher than that of neat PP. the impact toughness of polypropylene (PP) containing rare earth complex modified Al (OH):was 17. 7% times higher than that containing unmodified Al(OH):,and was 14 .8%higher than that of neat PP. the rare earth complex modification also improved the fire retardant properties of PP.

Key words: rare earth complex coupling agent, aluminum hydroxide, surface modification, polypropylene