中国塑料

中国塑料 ›› 2008, Vol. 22 ›› Issue (02): 72-75 .DOI: 10.19491/j.issn.1001-9278.2008.02.015

• 加工与应用 • 上一篇    下一篇

新型阻燃剂间苯三酚三(二苯基磷酸醋)的合成及其阻燃环氧树脂研究

于宝刚，卢林刚，何诩，唐凯   

  1. 中国人民武装警察部队学院科研部，河北廊坊065000
  • 收稿日期:2007-10-31 修回日期:1900-01-01 出版日期:2008-02-26 发布日期:2008-02-26

Synthesis of a New Phloroglucin Tri(diphenyl phosphate) Flame Retardant and its Application in Epoxy Resins

YU Bao-gang，LU Liu-gang，HE Yi，TANG Kai   

  1. office of Scientific Research, the Chinese People's Armed Police Force Academy, LanG fang 06s000, China
  • Received:2007-10-31 Revised:1900-01-01 Online:2008-02-26 Published:2008-02-26
  • Contact: YU Bao-gang

摘要： 以间苯三酚、三氯氧磷和苯酚为原料，合成了间苯三酚三(二苯基磷酸酯)(PDP)阻燃剂，并通过红外光谱分析和元素分析表征了其结构。结果表明，反应的最佳工艺条件为:无水三氯化铝作为催化剂，间苯三酚与三氯氧磷的物质的量之比为1:5;第一步反应温度为70℃，反应时间为7h;第二步反应温度为130℃，反应时间为8h。产品收率达87.2%。PDP阻燃环氧树脂的应用实验表明，其与三聚氰胺质量比为3:1的复配体系添加量为15%(质量分数，下同)时，环氧树脂的氧指数为32. 2%，达到UL94 V-0级。

关键词: 磷系阻燃剂, 间苯三酚, 间苯三酚三(二苯基磷酸醋), 环氧树脂

Abstract: Phloroglucin tri(diphenyl phosphate) was synthesized based on phloroglucin, phosphorus oxychloride, and phenol. the optimal reaction conditions were as following:using aluminum chloride as a catalyst, molar ratio of phloroglucin to phosphorus oxychloride was 1:5，reacted for 7 h at 70℃，followed by 8 h at 130℃.A gross yield of 87.2%was obtained. A mixture of the product andmelamine ( mass ratio 3:1)was introduced into epoxy resin (mass ratio of epoxy/mixture=85/15)，the limiting oxygen index and UL94 of the latter became 32. 2%and V-0，respectively.

Key words: phosphorous flame retardant, phloroglucin, phloroglucin tri(diphenyl phosphate), epoxy resin

京公网安备11010802034965号　 京ICP备13020181号-2
《中国塑料》编辑部 ©2008-2023 版权所有
地址:北京市海淀区阜成路11号　邮编：100048
编辑部：010-68985541　联系信箱：cp@plaschina.com.cn
广告部/发行部：010-68985253　本系统由北京玛格泰克科技发展有限公司设计开发