中国塑料 ›› 2008, Vol. 22 ›› Issue (07): 78-82 .DOI: 10.19491/j.issn.1001-9278.2008.07.016

• 助剂 • 上一篇    下一篇

成核剂二(3,4一二甲基二节叉)山梨醇对聚丙烯结晶性能的影响

倪卓,牛柯   

  1. 深圳大学化学与化工学院,广东深圳518060
  • 收稿日期:2008-01-28 修回日期:1900-01-01 出版日期:2008-07-26 发布日期:2008-07-26

Effect of DMDBS on Crystallization Behavior of Polypropylene

NI Zhuo,NIU Ke   

  1. School of Chemistry and Chemical Engineering, Shenzhen University, Shenzhen 518060, China
  • Received:2008-01-28 Revised:1900-01-01 Online:2008-07-26 Published:2008-07-26
  • Contact: NI Zhuo

摘要: 以二(3,4一二甲基二节叉)山梨醇(DMDBS)为成核剂,使用溶液沉淀法制备DMDBS质量分数分别为0.1%,0.3%,0.5%,0.7%,0.9%的粉末聚丙烯(PP)样品,采用红外光谱仪、差示扫描量热仪,X衍射仪和偏光显微镜等技术进行结晶性能的研究。结果表明,透明成核剂DMDBS是PP的有效a诱导剂,DMDBS的加人能诱导大量球晶生成,使结晶峰尖锐,结晶温度区间变窄,提高PP的结晶速率和结晶度,其中熔融吸收峰温度提高1.7-3.l℃,结晶度提高16%左右。在PP中添加0.3 % DMDBS时,PP的改性效果最好,结晶度达到最大值。

关键词: 二(3, 4一二甲基二节叉)山梨醇, 聚丙烯, 成核剂, 结晶形态

Abstract: This work presents the effect of di(3,4-dimethyl) dihenzaldchyde sorhitol (DMDBS) on the crystallization behavior of polypropylene (PP).The contents of DMDBS in PP were 0.1%,0.3%,0 .5%,0.7%,and 0.J%.Various techniques including FT-IR, DSC, WAXD, polarized light microscopy, etc. were employed to investigate crystal structures and thermal properties for the samples.
Extensive experiments demonstrated that DMDBS acted as an effective a form nucleating agent for PP,resulting in smaller spherulite size, higher crystallization and melting temperatures, and higher trans-parency of the samples.

Key words: di(3, 4-dimethyl) dihenzaldchyde sorhitol, polypropylene, nucleating agent, crystal morphology