中国塑料 ›› 2010, Vol. 24 ›› Issue (08): 1-8 .DOI: 10.19491/j.issn.1001-9278.2010.08.001

• 综述 •    下一篇

反应器共混多相耐冲击聚丙烯结构和性能研究进展

吕立新   

  • 收稿日期:2010-04-27 修回日期:1900-01-01 出版日期:2010-08-26 发布日期:2010-08-26

Progress in the Study of Structure and Properties of Heterophasic

  • Received:2010-04-27 Revised:1900-01-01 Online:2010-08-26 Published:2010-08-26

摘要: 回顾了近几年国内外在反应器共混多相耐冲击聚丙烯结构和性能方面所取得的主要成就,首先讨论了反应器共混多相耐冲击聚丙烯原始粉料颗粒和造粒后粒料及流延薄膜的形态结构,着重强调了分散相颗粒的多层芯-壳结构;还讨论了产品复杂性的起因、相分离及结晶的相互作用以及预剪切等对材料性能的影响;并讨论了分散相的组成和黏度对材料断裂行为的影响。

关键词: 聚丙烯, 反应器共混, 耐冲击, 合金, 结构, 性能

Abstract: The significant research progress in relationships between structure and properties of reactor-blended hetero-phase impact-resistant during the last decade were summarized. The morphology of reactor-blended hetero-phase impact-resistant pristine particles as well as pellets and casting films were discussed first. Particular attention was focused on the multilayered core-shell structure of the dispersed phase. Origin of product's heterogeneity, coupling effects of phase separation and crystallization, and the pre-shearing effect on the phase morphology and material properties were presented. The fracture characteristics as a function of the dispersed phase composition and viscosity were also discussed.

Key words: polypropylene, blending in reactor, impact-resistant, alloy, structure, property