中国塑料 ›› 2010, Vol. 24 ›› Issue (08): 60-63 .DOI: 10.19491/j.issn.1001-9278.2010.08.015

• 加工与应用 • 上一篇    下一篇

成核母粒及螺杆组合对玻纤增强PET复合材料性能的影响

傅明连 郑炳云 陈彰旭   

  1. 莆田学院环境与生命科学系 莆田学院
  • 收稿日期:2010-05-10 修回日期:1900-01-01 出版日期:2010-08-26 发布日期:2010-08-26

Effect of Nucleating Masterbatch and Screw Combination on the Properties of Glass Fiber Reinforced PET Composites

  

  • Received:2010-05-10 Revised:1900-01-01 Online:2010-08-26 Published:2010-08-26

摘要: 采用熔融插层法制备了一种高效成核母粒,研究了该成核母粒对玻璃纤维(GF)增强聚对苯二甲酸乙二醇酯(PET)复合材料性能的影响。结果表明,加入6 %(质量分数,下同)的成核母粒时,GF增强PET复合材料的起始结晶温度比纯PET高24.8 ℃,结晶温度范围比纯PET扩大了66.3 ℃,冷结晶峰基本消失,可在70 ℃的模温下进行注塑;同时探讨了螺杆组合对GF增强PET复合材料性能的影响,结果表明,螺杆前段的剪切太强会降低复合材料的冲击强度,通过优化螺杆组合,制备出综合性能优异的GF增强PET复合材料,其热变形温度为228 ℃,拉伸强度159 MPa,弯曲强度235 MPa,冲击强度101 J/m。

关键词: 增强, 玻璃纤维, 聚对苯二甲酸乙二醇酯, 成核母粒, 复合材料, 螺杆组合

Abstract: High effective nucleating masterbatch was prepared by melt intercalation approach, and its effect on the properties of glass fiber reinforced PET composites was investigated. When the content of nucleating masterbatch was 6 wt %, the initiative crystallization temperature and crystallization range of the composite increased 24.8 ℃ and 66.3 ℃ compared to the neat PET, respectively. The addition of masterbatch essentially diminished the cooling crystallization and made it possible for the molding was carried out at a mold temperature of 70 ℃. The effect of screw combination on the properties of fiber reinforced PET composites was also studied. It was found that if the shearing stress was too high the impact strength of composites would decline. Base on the optimized screw combination, the fiber reinforced PET composites with excellent comprehensive properties was prepared, the heat distortion temperature reached 228 ℃, the tensile, flexural, and impact strengths obtained were 159 MPa, 235 MPa, and 101 J/m, respectively.

Key words: reinforcement, glass fiber, poly(ethylene terephthalate), nucleating masterbatch, composite, screw combination

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