中国塑料 ›› 2010, Vol. 24 ›› Issue (11): 11-14 .DOI: 10.19491/j.issn.1001-9278.2010.11.003

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聚丙烯/纳米二氧化硅复合材料研究进展

赵祎程 姚军燕   

  1. 西北工业大学理学院
  • 收稿日期:2010-05-04 修回日期:1900-01-01 出版日期:2010-11-26 发布日期:2010-11-26

Research Progress in Polypropylene/Nano Silicon Dioxide Composites

  

  • Received:2010-05-04 Revised:1900-01-01 Online:2010-11-26 Published:2010-11-26

摘要: 从制备方法、相容性和增强增韧机理3个方面综述了聚丙烯(PP)/纳米二氧化硅(SiO2)复合材料的研究进展。其中,制备方法包括原位聚合法、溶胶凝胶法和超声波法;增强增韧机理包括裂缝与银纹相互转化机理、物理化学作用机理、微裂纹化机理和临界基体层厚度机理。指出了可以通过对纳米粒子进行表面改性,以降低其表面势能、调节疏水性、增加与基体之间的润湿性和结合力来改善材料的性能。

关键词: 聚丙烯, 纳米二氧化硅, 复合材料, 相容性, 增强, 制备, 增韧, 机理

Abstract: This review was about polypropylene/nano-silicon dioxide composites with their preparation, compatibility, and toughening/reinforcing mechanism introduced. The preparation methods included in-situ polymerization, sol-gel, and ultrasonic procedure. The mechanism involved in toughening of polypropylene matrix by the nanoparticles included cracks/craze mutual transformation, physical chemistry process, and critical ligand thickness. The mechanical properties of the composites could be further increased through surface modification of the nano-particles to reduce the interface energy, increase the wetting and binding, and regulate its hydrophobicity.

Key words: polypropylene, nano silicon dioxide, composite, compatibility, reinforcement, preparation, toughening, mechanism