中国塑料 ›› 2011, Vol. 25 ›› Issue (04): 38-41 .DOI: 10.19491/j.issn.1001-9278.2011.04.009

• 材料与性能 • 上一篇    下一篇

SEBS-g-MAH增韧聚乳酸的性能研究

刘密密 魏发云 张瑜   

  1. 东华大学 东华大学
  • 收稿日期:2010-10-25 修回日期:2010-12-17 出版日期:2011-04-26 发布日期:2011-04-26

Study on Preparation of Poly(lactic acid) Toughened by SEBS-g-MAH

LIU Mimi WEI Fayun ZHANG Yu   

  • Received:2010-10-25 Revised:2010-12-17 Online:2011-04-26 Published:2011-04-26
  • Contact: ZHANG Yu

摘要: 采用哈克密炼机制备了聚乳酸(PLA)与马来酸酐接枝苯乙烯-乙烯-丁二烯-苯乙烯嵌段共聚弹性体(SEBS-g-MAH)的共混物,并对共混物的力学性能、流变性能和微观结构进行了分析。结果表明,共混物的拉伸强度随着SEBS-g-MAH含量的增加而下降,断裂伸长率随着SEBS-g-MAH含量的增加而增大。当SEBS-g-MAH的含量为30 %时,共混物的冲击强度提高了2.5倍,共混物的韧性得到提高。随着SEBS-g-MAH含量的增加,PLA熔体黏度的变化趋势与SEBS-g-MAH越来越相似,即熔体黏度随着频率的增大而下降。扫描电镜分析表明,MAH基团改善了两相间的界面作用,增韧作用明显。

关键词: 聚乳酸, 马来酸酐接枝苯乙烯-乙烯-丁二烯-苯乙烯共聚物, 增韧, 力学性能, 流变性能

Abstract: Poly(lactic acid) (PLA) and SEBS-g-MAH were mixed using a HAAKE rheometer. The mechanical properties, rheological properties and the microstructure of the obtained blends were investigated. It was shown that the tensile strength of the blends decreased, and the elongation at break increased with increasing SEBS-g-MAH content. When the loading of SEBS-g-MAH was 30 %, the impact strength of the blend was 2.5 times that of neat PLA. The melt viscosity of the blends decreased with increasing SEBS-g-MAH content. SEM showed that the MAH groups on the interface compatibilized the two components.

Key words: poly(lactide acid), maleic anhydride grafed styrene-ethylene-butadiene-styrene copolymer, toughening, mechanical property, rheological behavior