中国塑料 ›› 2012, Vol. 26 ›› Issue (03): 67-70 .DOI: 10.19491/j.issn.1001-9278.2012.03.012

• 加工与应用 • 上一篇    下一篇

拉伸工艺对聚苯硫醚薄膜结构与性能的影响

张守玉 牛鹏飞 黄宝奎 王孝军 杨杰   

  1. 四川大学高分子科学与工程学院 四川大学材料科学与技术研究所
  • 收稿日期:2011-09-23 修回日期:1900-01-01 出版日期:2012-03-26 发布日期:2012-03-26

Effect of Drawing Process on Structure and Properties of Polyphenylene Sulfide Films

ZHANG Shouyu NIU Pengfei HUANG Baokui WANG Xiaojun YANG Jie   

  • Received:2011-09-23 Revised:1900-01-01 Online:2012-03-26 Published:2012-03-26
  • Contact: YANG Jie

摘要: 采用哈克挤出机制备了聚苯硫醚片材,并通过自制拉膜机单轴拉伸制备聚苯硫醚薄膜。通过对拉伸工艺进行探讨,确定了聚苯硫醚薄膜最佳拉伸温度在85~100 ℃。借助万能材料试验机、差示扫描量热仪、X射线衍射仪等手段研究了拉伸速率对薄膜结构与性能的影响。结果表明,随着拉伸速率的增加,薄膜在相应方向上的取向度增加,结晶度、拉伸强度和断裂伸长率均呈先增加后降低的趋势。

关键词: 聚苯硫醚薄膜, 拉伸速率, 取向度, 结晶度, 力学性能

Abstract: Polyphenylene sulfide (PPS) sheets were prepared using a HAAKE extruder and then were uniaxially-stretched into PPS film. The processing technology of uniaxially-stretched PPS films was discussed and the optimum stretching temperature was determined between 85℃~100℃. According to the analysis results of universal material testing machine, differential scanning calorimetry and X-ray diffraction tests, the impact of extrusion processing and tensile rate on the structures and mechanical properties of the uniaxially-stretched film was studied. With increasing tensile rate the orientation degree of the film increased, but the crystallinity, tensile strength and elongation at break of the film increased firstly and then decreased.

Key words: polyphenylene sulfide film, stretching velocity, orientation degree, crystallinity, mechanical property