中国塑料 ›› 2012, Vol. 26 ›› Issue (08): 60-63 .DOI: 10.19491/j.issn.1001-9278.2012.08.011

• 材料与性能 • 上一篇    下一篇

有机蒙脱土对EVA/IFR复合材料阻燃性能的影响

徐晓光   

  1. 中国国际工程咨询公司
  • 收稿日期:2012-03-05 修回日期:1900-01-01 出版日期:2012-08-26 发布日期:2012-08-26

Effect of Organmontmorillonite on Flame Retardancy of EVA/IFR Composites

Xiaoguang XU   

  • Received:2012-03-05 Revised:1900-01-01 Online:2012-08-26 Published:2012-08-26
  • Contact: Xiaoguang XU

摘要: 以聚磷酸铵(APP)和季戊四醇(PER)为膨胀型阻燃剂(IFR)制备了含有蒙脱土的无卤阻燃乙烯醋酸乙烯共聚物(EVA)复合材料。通过极限氧指数、热失重分析、锥形量热分析等手段研究了有机蒙脱土(OMMT)的存在对EVA阻燃性能和热降解性能的影响,并通过扫描电子显微镜对复合材料残炭表面形貌进行了观察和分析。结果表明,加入有机蒙脱土可以促进复合材料成炭、改善炭层质量,从而起到了良好的隔热、抑烟作用;OMMT的最佳添加量为3份(质量份数,下同),复合材料的极限氧指数可达到29.4 %,垂直燃烧可达V0级。

关键词: 膨胀型阻燃剂, 乙烯-醋酸乙烯共聚物, 有机蒙脱土, 复合材料

Abstract: A flame retarded EVA was prepared by using ammonium polyphosphate (APP) and pentaerythritol (PER) as the main flame retardants. Organmontmorillonite was used to further improve the flame retardancy of EVA. Limiting oxygen index, thermal gravimetric analysis and cone calorimetry were used to characterize the flammability and thermal behavior of the EVA composites. The morphology of the composite was observed and analyzed using SEM. Montmorillonite could enhance the char formation and improve the char layer quality, and hence reduced the HRR and smoke release amount. The limited oxygen index reached 29.4 % and UL 94 reached V0 level when 3 phr montmorillonite was added.

Key words: intumescent flame retardants, ethylenevinyl acetate copolymer, organmontmorillonite, composite

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