中国塑料 ›› 2014, Vol. 28 ›› Issue (04): 34-38 .DOI: 10.19491/j.issn.1001-9278.2014.04.006

• 材料与性能 • 上一篇    

ABS/木质素复合材料动态流变行为的研究

倪庆婷,刘惠,叶青,张柳,龚方红   

  1. 常州大学
  • 收稿日期:2013-11-13 修回日期:2013-12-30 出版日期:2014-04-15 发布日期:2014-04-15

Study of Dynamic Rheological Behavior of ABS/Lignin Composites

  • Received:2013-11-13 Revised:2013-12-30 Online:2014-04-15 Published:2014-04-15

摘要: 通过酸析法从木质素磺酸钙中提纯木质素,利用熔融共混法制备了丙烯腈丁二烯苯乙烯共聚物(ABS)/木质素复合材料,采用旋转流变研究了复合体系的动态流变行为。结果表明,经过提纯后,木质素磺酸钙在波长622 cm-1处的SO伸缩振动吸收峰消失;在线性黏弹区内,复合体系的储能模量(G′)保持恒定,当应变(γ)超过临界值γc时,复合体系进入非线性黏弹区,出现了“Payne效应”,G′随着γ增大而骤然减小,而且随着木质素含量的增加γc下降;随着剪切速率的增加,复合材料的复数黏度(η*)呈下降趋势,表现出剪切变稀的特征;随着木质素含量增加,复合体系的η*增大,储能模量(G′)和损耗模量(G″)交叉点黏弹转变频率(ωc)呈先增大后减小的趋势。

关键词: 丙烯腈丁二烯苯乙烯共聚物, 木质素, 复合材料, 动态流变行为

Abstract: Lignin was purified from calcium lignosulfonate by using recovery treatment.FTIR showed that the peak at 622 cm-1 owing to SO disappeared after being purified.Composites of ABS/lignin were prepared via meltblending method.The dynamic rheological behavior of composites was investigated by rotational rheometer.It showed that the storage modulus G′ of the composites kept invariant in linear viscoelastic region.When strain was over critical value γc, “Payne effect” occurred and G′ decreased rapidly with increasing strain.The critical value γc decreased with increasing content of lignin.The composites presented a shear thinning behavior and the complex viscosity decreased with increasing shear rate.With increasing content of lignin,the complex viscosity increased and the intersection of G′ and G″ increased firstly and then dropped.