中国塑料 ›› 2015, Vol. 29 ›› Issue (04): 102-106 .DOI: 10.19491/j.issn.1001-9278.2015.04.019

• 塑料与环境 • 上一篇    下一篇

废弃聚苯乙烯颗粒接枝改性制备防水涂料的研究

刘运学1,唐元亮2,李兰葛大利牛晚扬   

  1. 1. 沈阳建筑大学2. 沈阳市浑南新区浑南东路9号
  • 收稿日期:2014-11-24 修回日期:2015-01-17 出版日期:2015-04-26 发布日期:2015-04-26

Study on Preparation of Waterproof Coatings Graftmodified with Waste Polystyrene Particles

  • Received:2014-11-24 Revised:2015-01-17 Online:2015-04-26 Published:2015-04-26

摘要: 以丙烯酸(AA)和丙烯酸丁酯(BA)为共聚单体,采用溶液接枝法对废聚苯乙烯(PS)进行接枝改性制得PS接枝共聚物,然后以PS接枝共聚物的乳液为基料制备改性PS防水涂料。研究了引发剂用量、单体用量、反应温度和反应时间对PS接枝共聚物接枝率的影响,以及填料和增塑剂的用量对改性PS防水涂料性能影响。结果表明,PS接枝共聚物的最佳合成工艺为:PS用量为30 g,溶剂用量为60 mL,引发剂用量为2.2 g,单体用量为20 g,反应温度为85 ℃,反应时间为25 h;向改性PS乳液中填加10 %的填料和4 %的增塑剂制得的防水涂料性能最佳:耐水时间为25 h,耐盐时间为27 h,表干时间为18 min,冲击强度达50 kg·cm。

关键词: 聚苯乙烯, 泡沫塑料, 接枝改性, 防水涂料

Abstract: An emulsion type waterproof coating was prepared with acrylic acid and butyl acrylate grafted waste PS foam as the main raw material. The effects of initiator loading, monomer ratio, reaction temperature, and reaction time on the grafting rate of PS were studied. It was found the optimal recipe was: PS 30 g, solvent 60 mL, initiator 2.2 g, monomer 20 g, filler 10 wt %, plasticizer 4 wt %, both based on the weight of grafted PS, the reaction temperature 85 ℃, the reaction time 2.5 h. The waterproof time was 25 h; the time of torlerance of salinity was 27 h, the dry time was 18 min, and the impact strength was 50 kg·cm.

Key words: polystyrene, foam, graft modification, waterproof coating