中国塑料 ›› 2016, Vol. 30 ›› Issue (04): 114-118 .DOI: 10.19491/j.issn.1001-9278.2016.04.020

• 助剂 • 上一篇    下一篇

扩链改性对聚乳酸注塑发泡成型的影响

李金伟1,何继敏2,程丽1,兰霞1,邵翠映1   

  1. 1. 北京化工大学塑料机械及塑料工程研究所2. 北京化工大学
  • 收稿日期:2015-12-04 修回日期:2015-12-24 出版日期:2016-04-26 发布日期:2016-04-26

Influence of Chain Extenders on Foam Injection Molding of Poly(lactic acid)

  • Received:2015-12-04 Revised:2015-12-24 Online:2016-04-26 Published:2016-04-26

摘要: 通过添加不同含量的扩链剂(CE)对2种牌号聚乳酸(PLA)进行改性,对改性PLA进行注塑发泡,研究了扩链剂用量对PLA熔体流变性能、试样的泡孔形态和力学性能等的影响,并比较了不同PLA泡沫的泡孔结构和力学性能的差异。结果表明,PLA的熔体流动速率随着扩链剂的加入明显降低,同时熔体强度得到提高;随着扩链剂含量的增多,注塑级和挤出级PLA的发泡效果和力学性能都逐渐提高,扩链剂含量达到0.8 %(质量分数,下同)时,取得最好的泡孔结构和最优的力学性能;改性注塑级发泡试样较改性挤出级发泡试样有更高的力学性能。

关键词: 聚乳酸, 扩链, 注塑, 发泡, 泡孔形态, 熔体强度, 力学性能

Abstract: PLA was modified with chain extenders, and was foamed molded through injection molding. Melt flowability, cell morphology,and mechanical properties of the foam were investigated. It was found that, there was a significant reduction in the melt flow rate and an improvement in the melt strength by the chain extender. With increasing contents of the chain extender, the foaming performance and mechanical properties of both injection and extrusion grade PLA were improved gradually. When the content of the chain extender reached 0.8 wt%, the optimal cell morphology and mechanical properties were obtained. Foamed samples of the modified injection molding grade had better mechanical properties.

Key words: poly(latic acid), chain extension, injection molding, foaming, cell morphology, melt strength, mechanical property