中国塑料 ›› 2016, Vol. 30 ›› Issue (05): 46-49 .DOI: 10.19491/j.issn.1001-9278.2016.05.009

• 材料与性能 • 上一篇    下一篇

PP-g-GMA的制备及其增容PP/PA6共混物的性能

汪杰,刘海,文胜,龚春丽,郑根稳   

  1. 湖北工程学院
  • 收稿日期:2016-01-19 修回日期:2016-02-09 出版日期:2016-05-26 发布日期:2016-05-26

Preparation of PP-g-GMA and Properties of PP/PA6 Blends Compatibilized with PP-g-GMA

  • Received:2016-01-19 Revised:2016-02-09 Online:2016-05-26 Published:2016-05-26

摘要: 通过熔融接枝反应制备了甲基丙烯酸缩水甘油酯接枝聚丙烯(PP-g-GMA),并将其作为聚丙烯/聚酰胺6(PP/PA6)共混物的相容剂,研究了PP-g-GMA对PP/PA6共混物的力学性能及形态结构的影响。结果表明,采用滴定法测得PP-g-GMA接枝率为3.35 %;当PP-g-GMA的添加量为4 %(质量分数,下同)和8 %时,PP/PA6/PP-g-GMA共混物的拉伸强度和缺口冲击强度分别较PP/PA6共混物提高了32.4 %和60.4 %;PP-g-GMA显著改善了PP/PA6 共混物的界面相容性,是PP/PA6共混物的有效增容剂。

关键词: 甲基丙烯酸缩水甘油酯接枝聚丙烯, 聚丙烯, 聚酰胺6, 共混物, 相容剂, 力学性能

Abstract: Glycidyl methacrylate grafted polypropylene (PP-g-GMA) was prepared in an internal mixer, which was used as a compatibilizer for PP/PA6 blends.The mechanical properties and morphology of compatibilized PP/PA6 blends were investigated. The graft rate of PP-g-GMA measured with titration method was 3.35 %. The tensile strength and notched impact strength of PP/PA6/PP-g-GMA blends increased by 32.4 % and 60.4 % than neat PP/PA6 blends when the addition of PP-g-GMA was 4 wt% and 8 wt%, respectively. The interface compatibility of PP/PA6 blends was significantly enhanced while adding PP-g-GMA. It meant that PP-g-GMA was an efficient compatibilizer for PP/PA6 blends.

Key words: polypropylene grafted glycidyl methacrylate, polypropylene, polyamide 6, blend, compatilizer, mechanical property