中国塑料 ›› 2017, Vol. 31 ›› Issue (1): 29-35 .DOI: 10.19491/j.issn.1001-9278.2017.01.006

• 材料与性能 • 上一篇    下一篇

PLA/PHBV共混改性研究

段雨婷1,许国志2   

  1. 1. 北京工商大学2. 北京工商大学材料与机械工程学院
  • 收稿日期:2016-09-29 修回日期:2016-10-27 出版日期:2017-01-26 发布日期:2017-01-26

Study on Blending Modification of PLA/PHBV

  • Received:2016-09-29 Revised:2016-10-27 Online:2017-01-26 Published:2017-01-26

摘要: 采用熔融共混法制备了聚乳酸/聚(3-羟基丁酸-co-3羟基戊酸酯)(PLA/PHBV)共混物,研究了PLA/PHBV质量比以及滑石粉(Talc)含量对PLA/PHBV共混物性能的影响。结果表明,随着PHBV含量的增加,PLA/PHBV的结晶度先降低后升高,断裂伸长率提高了21.81%,冲击强度提高了35.9 %,拉伸强度下降;随着Talc含量的增加,PLA/PHBV/Talc的结晶度增大,冲击强度提高了12.4 %,但是断裂伸长率和拉伸强度有所下降;在不显著降低拉伸强度和弯曲强度的前提下,PHBV的含量为20 %(质量分数,下同)且Talc含量为1.5 %时,复合材料的力学性能最优。

关键词: 聚乳酸, 聚(3-羟基丁酸-共聚-3-羟基戊酸酯), 滑石粉, 结晶性能, 力学性能

Abstract: Poly(L-lacticacid) (PLA)/poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) blends were prepared by a meltblending method. The effects of PLA/PHBV weight ratio and talc content on the properties of PLA/PHBV blends were investigated. With a continuous increase of PHBV content, the crystallinity degree of the blends showed a decrease at first and then began to increase. The blends achieved an increase by 35.9 % in impact strength and by 21.81 % in elongation at break, whereas the tensile strength was reduced. On the other hand, the crystallinity degree of the blends also increased with increasing talc content and their impact strength increased by 12.4 %, followed by a decrease in tensile strength and elongation at break. The mechanical properties of the blends achieved optimum values with addition of 20 wt % PHBV and 1.5 wt %talc.

Key words: poly(L-lacticacid), poly(3-hydroxybutyrate-co-3-hydroxyvalerate), talc, crystallization behavior, mechanical property