京公网安备11010802034965号
京ICP备13020181号-2
《中国塑料》编辑部 ©2008-2024 版权所有
地址:北京市海淀区阜成路11号 邮编:100048
编辑部:010-68985541 联系信箱:cp@plaschina.com.cn
广告部/发行部:010-68985253 本系统由北京玛格泰克科技发展有限公司设计开发
中国塑料 ›› 2025, Vol. 39 ›› Issue (11): 118-124.DOI: 10.19491/j.issn.1001-9278.2025.11.018
• 塑料与环境 • 上一篇
孟坤1,2(
), 曹金鹏2, 张彦君2, 王二龙2, 陈敏剑1,2
收稿日期:2025-05-16
出版日期:2025-11-26
发布日期:2025-11-21
作者简介:孟坤(1991-),男,工程师,主要从事塑料标准化工作,645359172@qq.com
MENG Kun1,2(
), CAO Jinpeng2, ZHANG Yanjun2, WANG Erlong2, CHEN Minjian1,2
Received:2025-05-16
Online:2025-11-26
Published:2025-11-21
摘要:
简要综述了废塑料回收当前的回收状况和研究进展,并分别介绍了物理回收和化学回收在近几年取得的成果,提出了目前急需解决的问题,并对未来发展进行了展望。
中图分类号:
孟坤, 曹金鹏, 张彦君, 王二龙, 陈敏剑. 废塑料回收当前技术和面临的挑战[J]. 中国塑料, 2025, 39(11): 118-124.
MENG Kun, CAO Jinpeng, ZHANG Yanjun, WANG Erlong, CHEN Minjian. Current technologies and challenges for waste plastic recycling[J]. China Plastics, 2025, 39(11): 118-124.
| 热裂解 | ||||
| 溶剂分解(以PET为主) | ||||
| 加氢裂解 |
| 热裂解 | ||||
| 溶剂分解(以PET为主) | ||||
| 加氢裂解 |
| [1] | VUPPALADADIYAM S S V, VUPPALADADIYAM A K, SAHOO A, et al. Waste to energy: Trending key challenges and current technologies in waste plastic management [J].Science of the Total Environment, 2024,913:169436. |
| [2] | 唐茂株.2022—2023年世界塑料工业进展(I):通用塑料[J].塑料工业,2024,52(3):1⁃19. |
| [3] | BORRELLE S B, RINGMA J, LAW K L, et al. Predicted growth in plastic waste exceeds efforts to mitigate plastic pollution [J]. Science, 2020, 369: 1 515⁃1 518. |
| [4] | ZHANG F, ZHAO Y T, WANG D D, et al. Current technologies for plastic waste treatment: a review[J]. Journal of Cleaner Production, 2021, 282(2): 124523. |
| [5] | 中国物资再生协会.2024中国再生资源回收行业发展报告[J].资源再生,2024(7):27⁃38. |
| [6] | 徐灿,崔安琪,梁进欣,等.废弃塑料的化学回收:方法,现状及前景展望[J].塑料工业,2024,52(1):9⁃17. |
| [7] | SCHYNS Z O G, SHAVER M P. Mechanical recycling of packaging plastics: a review[J]. Macromol Rapid Commun,2021,42: 2000415. |
| [8] | ZHAO Y B, LV X D, NI H G. Solvent⁃based separation and recycling of waste plastics: a review [J]. Chemosphere, 2018, 209: 707⁃720. |
| [9] | VOLLMER I, JENKS M J F, ROELANDS M C P, et al. Beyond mechanical recycling: giving new life to plastic waste[J]. Angewandte Chemie International Edition, 2020,59(36):15 402⁃15 423. |
| [10] | RAGAERT K, DELVA L, GEEM K V. Mechanical and chemical recycling of solid plastic waste[J]. Waste Management, 2017,69(11):24⁃58. |
| [11] | ASCHENBRENNER D, GROS J, FANGEROW N, et al. Recyclebot—using robots for sustainable plastic recycling[J]. Science Direct, 2023,116:275⁃280. |
| [12] | ZHENG K, WU Y, HU Z X, et al. Progress and perspective for conversion of plastic wastes into valuable chemicals[J]. Chemical Society Reviews,2023, 52 (1): 8⁃29. |
| [13] | ELLIS L D, RORRER N A, SULLIVAN K P, et al. Beckham, Chemical and biological catalysis for plastics recycling and upcycling[J]. Nature Catalysis, 2021, 4 (7) :539⁃556. |
| [14] | AL⁃SALEM S M, ANTELAVA A, CONSTANTINOU A, et al. A review on thermal and catalytic pyrolysis of plastic solid waste (PSW) [J]. Journal of Environmental Management, 2017, 197 (7) :177⁃198. |
| [15] | KIN D, HAN M, KIN N, et al. Waste Plastic Pyrolysis Industry: Current Status and Prospects [J]. Korean Society of Environmental Engineers, 2024, 46(7): 395⁃407. |
| [16] | ALI A, USAMA A, NABEEL A, et al. A review of hydrogen generation through gasification and pyrolysis of waste plastic and tires: Opportunities and challenges [J]. International Journal of hydrogen energy,2024, 77(8):1 185⁃1 204. |
| [17] | BEHZAD V, SOHEIL V, HYUNJIN K, et al. Production of light olefins and monocyclic aromatic hydrocarbons from the pyrolysis of waste plastic straws over high⁃silica zeolite⁃based catalysts[J]. Environmental Research, 2024, 245(3):118076. |
| [18] | DOMINIK H, SZABINA T, NORBERT M. Thermo⁃catalytic co⁃pyrolysis of waste plastic and hydrocarbon by⁃products using β⁃zeolite[J]. Clean Technologies and Environmental Policy, 2024, 26 (1):235⁃244. |
| [19] | LIU Y X, TEE M Y, MONG G R, et al. Kinetic and Synergism Analysis on Pyrolysis of Waste Plastic Mixture through TGA [J]. Chemical engineering transactions, 2024, 113(11):2 283. |
| [20] | KIM D, YOON Y M, JANG J J,et al. Development of a circulating fluidized bed for a 100 kg/day waste plastic pyrolysis⁃combustion system [J]. Chemical Engineering Journal, 2024, 499(11):156257. |
| [21] | CULSUM N T U, KISMANTO A, ZULDIAN P, et al. An overview of catalytic pyrolysis of plastic waste over base catalysts [J]. Journal of Analytical and Applied Pyrolysis, 2024, 183(10): 106828. |
| [22] | SONG J X, LV J B, PAN Y H, et al. Low⁃temperature hydrogen production from waste polyethylene by nonthermal plasma (NTP)⁃assisted catalytic pyrolysis using NiCeOx/β catalyst[J]. Chemical Engineering Journal, 2024, 490(6):151676. |
| [23] | PETRA K, JANOS B, BENCE K, et al. Glass wool recycling by water⁃based solvolysis [J]. Chem Engineering, 2024, 8(5): 93. |
| [24] | ZHANG X H, SIBARI R, CHAKRABORTY S, et al. Epoxy‐based carbon fiber‐reinforced plastics recycling via solvolysis with non‐oxidizing methanesulfonic acid [J]. Chemie ingenieur technik, 2024, 96(7):987⁃997. |
| [25] | LI J, SONG F M, GUO J Z, et al. Environmental protection and sustainable waste⁃to⁃energy scheme through plastic waste gasification in a combined heat and power system[J]. Process safety and environmental protection, 2024, 190(10): 1 562⁃1 574. |
| [26] | FRANCESCO P, FILOMENA A, CARMINE B, et al. Mixed plastic waste gasification in a large pilot⁃scale fluidized bed reactor operated with oxygen⁃enriched air and steam[J]. Energy & fuels, 2024, 38 (22):22 172⁃22 181. |
| [27] | ZHANG P, LIANG C, WU M D, et al.Sustainable microwave⁃driven CO2 gasification of plastic waste for high⁃yield H2 and CO production[J]. Applied catalysis B, Environmental, 2024, 345(5): 123718. |
| [28] | AZAM M U, FERNANDES A, FERREIRA M J, et al. Pore⁃structure engineering of hierarchical β Zeolites for the enhanced hydrocracking of waste plastics to liquid fuels [J]. ACS catalysis, 2024,14 (21):16 148⁃16 165. |
| [29] | ZHANG G Q, MAO Q G, YUE Y Q, et al. Ni⁃based catalysts supported on Hbeta zeolite for the hydrocracking of waste polyolefin[J]. RSC advances, 2024,14 (23):15 856⁃15 861. |
| [30] | ZHONG X, LIU J, GAO L, et al. Constructing the Al deficiency in Si⁃O(H)⁃Al units based on Pt/ZSM-5 for enhanced hydrocracking of polyethylene into high⁃quality liquid fuel[J]. Nano research, 2024,17 (11):10 088⁃10 098. |
| [31] | ASGHAR W, QAZI I A, ILYAS H, et al. Comparative solid phase photocatalytic degradation of polythene films with doped and undoped TiO2 nanoparticles [J]. Journal of Nanomaterials, 2010(8):461930. |
| [32] | ZHAO X, LI Z W, CHEN Y, et al. Enhancement of photocatalytic degradation of polyethylene plastic with CuPc modified TiO2 photocatalyst under solar light irradiation [J]. Applied surface science, 254(6):1 825⁃1 829. |
| [33] | VERMA R, SINGH S, DALAI M K, et al. Photocatalytic degradation of polypropylene film using TiO2⁃based nanomaterials under solar irradiation[J]. Materials and Design, 2017, 133 (10):10⁃18. |
| [34] | GARCÍA⁃MONTELONGO X L, MARTÍNEZ⁃DE LA CRUZ A, AZQUEZ⁃RODRÍGUEZ S, et al. Photo⁃oxidative degradation of TiO2/polypropylene films [J]. Materials Research Bulletin, 2014, 51(3):56⁃62. |
| [35] | SHANG J, CHAI M, ZHU Y F. Solid⁃phase photocatalytic degradation of polystyrene plastic with TiO2 as photocatalyst[J]. Journal of solid state chemistry, 2003,174(1):104⁃110. |
| [36] | NABI I, BACHA A, LI K J, et al. Complete photocatalytic mineralization of microplastic on TiO2 nanoparticle film [J]. Iscience, 2020, 23(7):101326. |
| [37] | CHO S, CHOI W. Solid⁃phase photocatalytic degradation of PVC⁃TiO2 polymer composites [J]. Journal of photochemistry and photobiology A:Chemistry, 2001, 143(2/3):221⁃228. |
| [38] | GU C, LI C F, MINEZAWA N, et al. Multi⁃stimuli⁃responsive polymer degradation by polyoxometalate photocatalysis and chloride ions[J]. Nanoscale, 2024, 16 (16): 813⁃819. |
| [39] | NAGARAJ S, THANIKAIVELAN P. Harnessing protein waste into reduced graphitic carbon oxide‐copper‐collagen nanocomposite for visible light photocatalytic degradation of nano plastics[J]. Advanced sustainable systems, 2024,8 (7): 487. |
| [40] | WAN Y, WANG H J, LIU J J, et al. Enhanced degradation of polyethylene terephthalate plastics by CdS/CeO2 heterojunction photocatalyst activated peroxymonosulfate[J]. Journal of hazardous Materials, 2023, 452(6):131375. |
| [41] | UEKERT T, KUEHNEL M F, WAKERLEY D W, et al. Plastic waste as a feedstock for solar⁃drive H2 generation[J]. Energy and environmental science, 2018(10):2 853⁃2 857. |
| [42] | JIAO X C, ZHENG K, CHEN Q X, et al. Photocatalytic conversion of waste plastics into C2 fuels under simulated natural environment conditions[J]. Angewandte chemie international edition,2020, 59:(36):15 497⁃15 501. |
| [43] | MONTAZER Z, HABIBI⁃NAJAFI M B, MOHEBBI M, et al. Microbial degradation of UV⁃pretreated low⁃density polyethylene films by novel polyethylene⁃degrading bacteria isolated from plastic⁃dump soil[J]. Journal of Polymers and the Environment, 2018, 26(5):3 613⁃3 625. |
| [44] | JAIN K, BHUNIA H, REDDY M S. Degradation of polypropylene⁃poly⁃Llactide blend by bacteria isolated from compost [J]. Bioremediation Journal, 2018, 22(3⁃4):73⁃90. |
| [45] | GIACOMUCCI L, RADDADI N, SOCCIO M, et al. Polyvinyl chloridebiodegradation by Pseudomonas citronellolis and Bacillus flexus[J]. New biotechnology, 2019, 52 (9):35⁃41. |
| [46] | SHILPA, BASAK N, MEENA S S. Biodegradation of low⁃density polythene (LDPE) by a novel strain of Pseudomonas aeruginosa WD4 isolated from plastic dumpsite[J]. Biodegradation, 2024,35 (5):641⁃655. |
| [47] | TOURNIER V, TOPHAM C M, GILLES A, et al. An engineered PET depolymerase to break down and recycle plastic bottles [J]. Nature,2020, 580 (4):216⁃219. |
| [48] | YOSHIDA S, HIRAGA K, TAKEHANA T, et al. A bacterium that degrades and assimilates poly(ethylene terephthalate)[J]. Science,2016, 351 (6278): 1 196⁃1 199. |
| [1] | 冯硕, 林小淇, 朱艳丽, 高维常, 翁云宣, 张彩丽. 生物降解塑料PBAT的化学回收与生命周期评价:现状、挑战与前景[J]. 中国塑料, 2025, 39(7): 102-111. |
| [2] | 梁永煌, 刘京, 葛冬琦. 我国塑料化学回收产业现状、存在问题及发展趋势[J]. 中国塑料, 2025, 39(7): 112-120. |
| [3] | 梁济峰, 瞿金平. 体积脉动注塑rPE⁃HD/rPET混杂体系结构性能演变[J]. 中国塑料, 2024, 38(8): 1-7. |
| [4] | 胡延庆, 胡凡, 周剑池, 豆义波. 废弃塑料回收与转化的研究进展[J]. 中国塑料, 2024, 38(4): 79-87. |
| [5] | 罗冠群, 赵乐, 潘雅琪. 废弃PE与PET共热解特性与动力学特性研究[J]. 中国塑料, 2024, 38(3): 86-93. |
| [6] | 林良斌, 周为明, 薛珲, 钱庆荣, 杨松伟, 曹长林, 陈庆华. 基于光催化降解的微塑料污染治理研究进展[J]. 中国塑料, 2024, 38(12): 172-178. |
| [7] | 全淑苗, 张彦军, 宋小飞, 杜闰萍, 于丹. 废塑料脱氯技术现状及产业化进展[J]. 中国塑料, 2022, 36(9): 122-130. |
| [8] | 马腾, 刘倩倩, 魏晓丽, 宋海涛, 李明丰. 废塑料热解油中杂质硅、氯的影响及应对策略探讨[J]. 中国塑料, 2022, 36(8): 127-134. |
| [9] | 周迎鑫, 翁云宣, 张彩丽, 刁晓倩, 宋鑫宇. 聚对苯二甲酸乙二醇酯回收技术和标准现状[J]. 中国塑料, 2021, 35(8): 162-171. |
| [10] | 孙小东, 曹鼎, 胡倩倩, 姚文清, 李景虹, 冯拥军. 废弃塑料的化学回收资源化利用研究进展[J]. 中国塑料, 2021, 35(8): 44-54. |
| [11] | 李明丰, 蔡志强, 邹亮, 魏晓丽, 习远兵, 王国清, 蔡立乐, 张哲民, 夏国富, 蒋海滨. 中国石化废旧塑料化学回收与化学循环技术探索[J]. 中国塑料, 2021, 35(8): 64-76. |
| [12] | 蔡毅, 田晖, 谢淼雪. 废旧家用电器塑料资源化利用及发展趋势[J]. 中国塑料, 2021, 35(8): 77-83. |
| [13] | 胡慧廉, 施嘉亮, 郎蕾, 施超欧, 姚建磊. 热裂解气质联用鉴别PA56、PA66和PA6[J]. 中国塑料, 2021, 35(11): 120-124. |
| [14] | 杨秀琴, 严亚如, 张效琳, 安彦飞, 于翔. 低VOCs含量的PET/TiO2@Ag共混体系的研究[J]. 中国塑料, 2020, 34(5): 32-37. |
| [15] | 卢晓龙, 柳炫羽, 丁恩普, 张贝贝, 于翔, 秦刚. PAN/TiO2纳米纤维膜的制备与性能分析[J]. 中国塑料, 2020, 34(4): 30-34. |
| 阅读次数 | ||||||
|
全文 |
|
|||||
|
摘要 |
|
|||||
京公网安备11010802034965号
京ICP备13020181号-2