中国塑料 ›› 2014, Vol. 28 ›› Issue (08): 78-83 .DOI: 10.19491/j.issn.1001-9278.2014.08.016

• 助剂 • 上一篇    

氰乙酰脲对聚氯乙烯的热稳定作用

晏苏学,施海峰,夏佳峰   

  1. 浙江传化华洋化工有限公司
  • 收稿日期:2014-02-11 修回日期:2014-04-04 出版日期:2014-08-26 发布日期:2014-08-26

Thermal Stabilization of Cyanoacetylurea in PVC

  • Received:2014-02-11 Revised:2014-04-04 Online:2014-08-26 Published:2014-08-26

摘要: 以三盐基硫酸铅(TLS)及N,N-二甲基-6-氨基尿嘧啶(DMAU)为参照,通过刚果红法和烘箱热老化法研究了N,N-二甲基氰乙酰基脲(DMCAU)对聚氯乙烯(PVC)的热稳定作用。结果表明,DMCAU的热稳定特性与DMAU类似, 单独使用时,刚果红试纸变色时间在较低用量条件下长于TLS,但随添加量的增加变化不如TLS明显,抗着色性亦不比TLS强;与硬脂酸钙(CaSt)并用对烘箱热老化没有明显效果,但在刚果红试验中有协同效应,最佳配比为1∶1。

关键词: 氰乙酰脲, 聚氯乙烯, 热稳定

Abstract: By comparison with tribasic lead sulfate (TLS) and N,N-dimethyl-6-aminouracil (DMAU), the thermal stabilization of N,N-dimethylcyanoacetylurea (DMCAU) in poly(vinyl chloride)(PVC) was studied by Congo red and oven aging method. It showed that the thermal stability of DMCAU based system was similar to that based on DMAU. When DMCAU was used alone and the dosage was low, the Congo red test time was longer than that of TLS. With increasing dosage, the increase in test time was far slower than TLS, and the inhibiting effect for PVC′s discoloration in oven was no better than TLS. When DMCAU was used with CaSt, a synergistic effect was observed in Congo red test, and the optimal proportion was 1∶1.

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