›› 2023, Vol. 37 ›› Issue (6): 31-36.

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PE-LD/PE-HD/CSW的共混改性及发泡性能研究

徐杰,李广富,付栋梁,钟进福   

  1. 浙江润阳新材料科技股份有限公司
  • 收稿日期:2023-01-20 修回日期:2023-03-08 出版日期:2023-06-26 发布日期:2023-06-26

Compounding modification and foaming performance of PE-LD/PE-HD/CSW composites

  • Received:2023-01-20 Revised:2023-03-08 Online:2023-06-26 Published:2023-06-26

摘要: 以低密度聚乙烯 (PE-LD)和高密度聚乙烯(PE-HD)为基体树脂,硫酸钙晶须(CSW)为增强剂,偶氮二甲酰胺(ADC)为发泡剂,采用辐照交联技术制备出PE-LD/PE-HD/CSW复合发泡材料。研究了不同CSW含量对PE-LD/PE-HD/CSW共混体系的熔体流动速率、热性能及发泡行为、力学性能、导热性能和热稳定性能的影响。结果表明,CSW的加入使PE-LD/PE-HD/CSW共混体系的熔体流动速率有所降低,热稳定性有所提高;与纯PE-LD/PE-HD发泡材料相比,当CSW含量为8 %时,PE-LD/PE-HD/CSW复合发泡材料的拉伸强度提高21.3 %,压缩强度提高17.8 %,压缩模量提高31.3 %,硬度提高10.9 %、撕裂强度提高16.4 %,而导热系数降低15.5 %。

关键词: 聚乙烯, 硫酸钙晶须, 力学性能, 热稳定性, 发泡行为

Abstract: A type of composite foams was fabricated by using low-density polyethylene (PE-LD) and high-density polyethylene (PE-HD) as matrix resins, calcium sulfate whisk (CSW) as a reinforcing agent, and azodicarbonamide as a foaming agent. The effect of CSW content on the melt flow rate, thermal properties, foaming behavior, mechanical properties, thermal conductivity, and thermal stability of the PE-LD/PE-HD/CSW blends were investigated. The results indicated that the introduction of CSW reduced the melt flow rate of the blends but improved their thermal stability. Compared to pure PE-LD/PE-HD complex foam, the PE-LD/PE-HD/CSW complex foams obtained better comprehensive properties at a CSW content of 8 wt%. Under such a CSW loading, the complex foams achieved an increase in tensile strength by 21.3 %, in compression strength by 17.8 %, in compression modulus by 31.3 %, in hardness by 10.9 %, and in tear strength by 16.4 %, but a decrease in thermal conductivity by 15.5 %.

Key words: polyethylene, calcium sulfate whisk, mechanical property, thermal stability, foam behavior