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中国塑料 ›› 2025, Vol. 39 ›› Issue (8): 124-130.DOI: 10.19491/j.issn.1001-9278.2025.08.020
收稿日期:
2024-08-09
出版日期:
2025-08-26
发布日期:
2025-07-30
作者简介:
谢爽(1991—),女,博士后,从事工程塑料合成等研究,2471809448@qq.com
Received:
2024-08-09
Online:
2025-08-26
Published:
2025-07-30
摘要:
作为特种工程塑料的聚砜具有优异的综合性能,其市场不断扩大,得到了广泛的应用。本文主要介绍聚砜膜材料的合成,以及其在材料工程、生物技术和医学、水净化领域的最新研究情况,并进一步对聚砜及膜产品以及单体进行了展望。
中图分类号:
谢爽. 聚砜膜材料研究进展[J]. 中国塑料, 2025, 39(8): 124-130.
XIE Shuang. Research progress in polysulfone membrane materials[J]. China Plastics, 2025, 39(8): 124-130.
[1] | Rising Demand for sulfone polymers in key industries: market projected to grow at 6.2% CAGR[EB/OL]. [2023⁃10⁃05].. |
[2] | Wasyłeczko M, Wojciechowski C, Chwojnowski A, et al. Polyethersulfone polymer for biomedical applications and biotechnology[J]. International Journal of Molecular Sciences, 2024,25:28. |
[3] | Brandt T, Wiese F, et al. Physical and Chemical Characteristics of Different Polyethersulfone Membranes[J]. Polymer, Membrane and Filter Characteristics, 2003, 138:1⁃12. |
[4] | Serbanescu O S, Voicu S I, Thakur V K, et al. Polysulfone functionalized membranes: Properties and challenges[J]. Materials Today Chemistry, 2020,17:24. |
[5] | Mamah S C, Goh P S, Ismail A F, et al. Recent development in modification of polysulfone membrane for water treatment application[J]. Journal of Water Process Engineering, 2021,40: 101835. |
[6] | Alenazi N A, Hussein M A, Alamry K A,et al. Modified polyether⁃sulfone membrane: a mini review[J]. Designed Monomers and Polymers, 2017, 20(1): 532⁃546. |
[7] | Irfan M, Idris A.Overview of PES biocompatible/hemodialysis membranes: PES–blood interactions and modification techniques[J]. Materials Science and Engineering: C,2015, 56: 574⁃592. |
[8] | Zhang G, Li D, Yan G, et al. Design and fabrication of a low dielectric constant poly(arylene ether sulfone) film⁃containing cyclohexane group[J]. Industrial & Engineering Chemistry Research, 2020, 59(20): 9 541⁃9 549. |
[9] | Ren W, Huang X, Yan G, et al. Structuring multiscale porous architecture in polyether sulfone films for ultra⁃low dielectric constant[J]. Polymer, 2023,272: 125832. |
[10] | Liu S, Peng M, Xu X, et al. PES⁃g⁃BST/PEEK composites modified by surface grafting with high dielectric tunability[J]. Journal of Materials Research and Technology, 2023, 27: 7 895⁃7 904. |
[11] | Chen H W, Kuo Y L, Huang S H, et al. Dual⁃functional membranes of CQDs/TiO2 @PI/PES nanofibers for the high filter efficiency of ultrafine particles and photocatalytic activity[J]. Journal of Environmental Chemical Engineering, 2024, 12(1):111680. |
[12] | Zhao H, Huang Y, Han Y, et al. Flexible and lightweight porous polyether sulfone/Cu composite film with bidirectional differential structure for electromagnetic interference shielding and heat conduction[J]. Chemical Engineering Journal, 2022,440: 135919. |
[13] | Al⁃Kadhi N S, Ahmed H A, Pashameah R A, et al. Enhancement of optical and electrical properties of polyether sulfone by addition of Li4Ti5O12 NPs[J]. Journal of Materials Research and Technology, 2023, 23: 1 177⁃1 188. |
[14] | Alrefaee S H, Alkallas F H, Ben Gouider Trabelsi A, et al. Laser assisted method for synthesis Li4Ti5O12/polyether sulfone composite for lithium ion batteries anodic materials[J]. Journal of Materials Research and Technology, 2023, 25: 440⁃450. |
[15] | Yan S, Qiu Y. Improving Hemocompatibility of polysulfone membrane by UV⁃assisted grafting of sulfonated chitosan[J]. Polymers, 2024, 16(11): 16111555. |
[16] | Kalugin D, Bahig J, Shoker A, et al. Superhydrophobic polyether sulfone (PES) dialysis membrane with enhanced hemocompatibility and reduced human serum protein interactions: Ex vivo, in situ synchrotron imaging, experimental, and computational studies[J]. Separation and Purification Technology, 2024,335:14. |
[17] | Fu X, Lei T, Li S L, et al. Construction of novel antiplatelet modified polyethersulfone membrane and study into its blood compatibility[J]. Biomaterials Advances, 2022,135: 112659. |
[18] | Fu X, Lei T, Xiao Y, et al. Preparation and blood compatibility of polyethersulfone dialysis membrane modified by apixaban as coagulation factor Xa inhibitor[J]. Biomaterials Advances, 2022, 139: 213012. |
[19] | Lusiana R A, Nuryanto R, Muna N, et al. High⁃performance sulfonated polyether sulfone/chitosan membrane on creatinine transport improved by lithium chloride[J]. International Journal of Biological Macromolecules, 2024, 261: 129784. |
[20] | Zhong D, Wang Z, Zhou J, et al. Additive⁃free preparation of hemodialysis membranes from block copolymers of polysulfone and polyethylene glycol[J]. Journal of Membrane Science, 2021, 618: 118690. |
[21] | Weng R, Zhang L, Cao Y, et al. Two⁃dimensional borocarbonitrides nanosheets engineered sulfonated polyether sulfone microspheres as highly efficient and photothermally recyclable adsorbents for hemoperfusion[J]. Chemical Engineering Journal, 2023,463:9. |
[22] | Zhang G, Yuan S, Cao S, et al. Functionalized poly(arylene ether sulfone) containing hydroxyl units for the fabrication of durable[J]. Superhydrophobic Oil/Water Separation Membranes, Nanoscale, 2019, 11(15): 7 166⁃7 175. |
[23] | Yan G, Lu H, Yuan S, et al. Side grafting tertiary amine in polyaryl ether sulfone membranes for reversible⁃multiple separations[J]. Journal of Membrane Science, 2023:677. |
[24] | Lim Y H, Wong E C, Chong W C, et al. Introducing self⁃healing properties to polyethersulfone (PES) membrane via poly(vinyl alcohol)/ polyacrylic acid (PVA/PAA) surface coating[J]. Chemosphere, 2024, 349: 140772. |
[25] | Poolachira S, Velmurugan S. Efficient removal of lead ions from aqueous solution by graphene oxide modified polyethersulfone adsorptive mixed matrix membrane[J]. Environmental Research, 2022, 210: 112924. |
[26] | Goyat R, Singh J, Umar A, et al. Synthesis and characterization of nanocomposite based polymeric membrane (PES/PVP/GO⁃TiO2) and performance evaluation for the removal of various antibiotics (amoxicillin, azithromycin & ciprofloxacin) from aqueous solution[J]. Chemosphere, 2024, 353: 141542. |
[27] | Misra U, Jashrapuria K, Singh S P. Fabrication of polyether sulfone⁃laser induced graphene composite electroconductive membrane and its application in biofouling control and chromium removal[J]. Journal of Membrane Science, 2024, 694: 122394. |
[28] | Yue R Y, Liu L N, Guan J, et al. Organic sandwich⁃structured carbon fiber/SiO2/PES electrochemical membrane with significantly improved charge transfer efficiency and water permeability[J]. Separation and Purification Technology, 2024, 341: 126880. |
[29] | Almanassra I W, Jaber L, Backer S N, et al. Oxidized carbide⁃derived carbon as a novel filler for improved antifouling characteristics and permeate flux of hybrid polyethersulfone ultrafiltration membranes[J]. Chemosphere, 2023, 313: 137425. |
[30] | Haddad Irani⁃nezhad M, Khataee A, Vatanpoor V, et al. Incorporation of 2D⁃biotene to polyethersulfone ultrafiltration membrane with superhydrophilicity and antifouling properties for removal of organic pollutants[J]. Chemosphere, 2023, 318: 137952. |
[31] | Kucukosman R, Isik Z, Ocakoglu K, et al. Boron⁃based magnesium diboride nanosheets preparation and tested for antimicrobial properties for PES membrane[J]. Chemosphere, 2023, 339: 139340. |
[32] | Gowriboy N, Kalaivizhi R, Kaleekkal N J, et al. Fabrication and characterization of polymer nanocomposites membrane (Cu⁃MOF@CA/PES) for water treatment[J]. Journal of Environmental Chemical Engineering, 2022, 10(6): 4156671. |
[33] | Zheng S, Ding L, Hu F, et al. Construction of PES composite ultrafiltration membrane with high permeability and selectivity assisted by three⁃dimensional Ni⁃Zn MOF@Multi CNC[J]. Separation and Purification Technology, 2025, 354: 129091. |
[34] | Almanassra I W, Jaber L, Chatla A, et al. Unveiling the relationship between MOF porosity, particle size, and polyethersulfone membranes properties for efficient decontamination of dye and organic matter[J]. Chemical Engineering Journal, 2023:471. |
[35] | Yogarathinam L T, Goh P S, Ismail A F, et al. Nanocrystalline cellulose incorporated biopolymer tailored polyethersulfone mixed matrix membranes for efficient treatment of produced water[J]. Chemosphere, 2022, 293: 133561. |
[36] | Khosravi M J, Hosseini S M, Vatanpour V. Performance improvement of PES membrane decorated by Mil-125(Ti)/chitosan nanocomposite for removal of organic pollutants and heavy metal[J]. Chemosphere, 2022, 290: 133335. |
[37] | Yahya R, Elshaarawy R F M. Cross⁃linked quaternized polyethersulfone⁃amino crystalline nanocellulose composite membrane for enhanced phosphate removal from wastewater[J]. International Journal of Biological Macromolecules, 2023, 236: 123995. |
[38] | Hussein Al⁃Timimi D A, Alsalhy Q F, AbdulRazak A A, et al. Novel polyether sulfone/polyethylenimine grafted nano⁃silica nanocomposite membranes: Interaction mechanism and ultrafiltration performance[J]. Journal of Membrane Science, 2022, 659: 120784. |
[39] | Kraiem N B, Rhimi A, Zlaoui K, et al. Development of polysulfone membranes and their application for removing rare earth ions from aqueous solutions by polyvinyl alcohol⁃enhanced ultrafiltration[J]. Iranian Polymer Journal, 2024,33: 1 481–1 491. |
[40] | Zhang Y, Luo T, Yang X, et al. Superior diffusion dialysis anion exchange membranes from miscible polyether sulfone–poly(vinyl pyrrolidone⁃co⁃styrene) blends[J]. Journal of Membrane Science, 2023, 680: 121704. |
[41] | Zhang Y, Song G, Luo T, et al. Acid⁃triggered polyether sulfone ⁃ Polyvinyl pyrrolidone blend anion exchange membranes for the recovery of titania waste acid via diffusion dialysis[J]. Journal of Membrane Science, 2022, 662: 120980. |
[42] | Mishra D, Singh S K, Adhikari A, et al. Polyaniline and polypyrrole impregnated polyethersulfone based composite polymer beads for defluoridation application[J]. Journal of Environmental Chemical Engineering, 2022, 10(5): 95–104. |
[43] | Zhao J, Tian S, Huang Q, et al. Ultra⁃highly photocatalytic removal of pollutants by polypyrrole/cadmium sulfide/polyether sulfone hybrid porous membrane in single⁃pass mode[J]. Chemical Engineering Journal, 2022, 432: 134300. |
[44] | Wang K, Wang S, Gu K, et al. Ultra⁃low pressure PES ultrafiltration membrane with high⁃flux and enhanced anti⁃oil⁃fouling properties prepared via in⁃situ polycondensation of polyamic acid[J]. Science of The Total Environment, 2022, 842: 156661. |
[45] | Gholamiveisi M, Zinadini S, Zinatizadeh A A. High⁃performance CPES nanofiltration membrane decorated by cinnamon extract with efficient antibacterial/anti⁃fouling property for post treatment of biologically treated industrial wastewater[J]. Journal of Environmental Chemical Engineering, 2023, 11(5): 110906. |
[46] | Jiang H, Liu S. Construction of self⁃healing polyethersulfone ultrafiltration membrane by cucurbit[8]uril hydrogel via RTIPS method and host⁃guest chemistry[J]. Chemosphere, 2023, 311: 137079. |
[47] | Zhou P, Wang T, Du C H, et al. Construction of PES mixed matrix membranes incorporating ZnFe2O4 @MXene composites with high permeability and antifouling performance[J]. Journal of Environmental Chemical Engineering, 2023, 11(4): 256496319. |
[48] | Vatanpour V, Naziri Mehrabani S A, Dehqan A, et al. Performance improvement of polyethersulfone membranes with Ti3AlCN MAX phase in the treatment of organic and inorganic pollutants[J]. Chemosphere, 2024, 362: 142583. |
[49] | 郑吉富,李胜海,张所波. 一种聚砜类树脂的制备方法:CN109721733B[P]. 2022⁃06⁃11. |
[50] | 仇伟,张鑫. 一种低环聚物含量的砜聚合物的制备方法:CN115058009B[P]. 2023⁃10⁃20. |
[51] | 史碧波,王敏,廖广明. 双封端聚砜制备方法:CN113388112B[P]. 2021⁃11⁃02 |
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