China Plastics ›› 2013, Vol. 27 ›› Issue (03): 92-95 .DOI: 10.19491/j.issn.1001-9278.2013.03.017

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Preparation and Application of A New Reactive-type Flame Retardant Containing P-N Elements

  

  • Received:2012-11-01 Revised:1900-01-01 Online:2013-03-26 Published:2013-03-26

Abstract: A new type of phosphorus and nitrogen containing flame retardant ---β-(N-phenyl carboxamide)ethyl methyl phosphinic acid (CEMP) was synthesized by the reaction of 2-methy-2,5-dioxo-1,2-oxaphospholane(OP) with aniline. The structure of CEMP was characterized with FTIR and 1H-NMP. The flame retarding performance and glass transition temperature (Tg) of CEMP filled epoxy resin was investigated. The composite containing 20 % CEMP reached the UL 94 V-0 rating with limiting oxygen index value of 29.4 %. The flexural strength of the composite was increased by adding the CEMP, while the flexural modulus and Tg of system were reduced with increasing CEMP.

Key words: β-(N-phenyl carboxamide)ethyl methyl phosphinic acid, flame retardancy, epoxy, composite