中国塑料 ›› 2008, Vol. 22 ›› Issue (03): 82-85.DOI: 10.19491/j.issn.1001-9278.2008.03.018

• 标准与测试 • 上一篇    下一篇

塑料水管中挥发性有机物的迁移研究

孟平蕊,康智慧,李良波,宋庆群,董晨光   

  1. 济南大学化学与化工学院,山东济南250022
  • 收稿日期:2007-12-02 修回日期:1900-01-01 出版日期:2008-03-26 发布日期:2008-03-26

Study on Volatile organic Components Migrating from Plastics Pipes into Drinking Water

MENG Ping-rui,KANG Zhi-hui,LI Liang-bo,DONG Chen-guang,SONG Qing-qun   

  1. School of Chemistry and Chemical Engineering, University of Ji nan,250022, China
  • Received:2007-12-02 Revised:1900-01-01 Online:2008-03-26 Published:2008-03-26
  • Contact: MENG Ping-rui

摘要: 介绍了高密度聚乙烯管(PE-HD)、交联聚乙烯管(PE-X)和硬质聚氯乙烯管(PVC-U)中的挥发性有机成分向水中的迁移测定研究。PE-HD中主要的迁移成分是2,4-二-间-丁基-苯酚(2,4.-DTBP),是酚类抗氧化剂的降解产物,除此之外降解产物还有醋、乙醛、酮、芳香烃和菇类化合物。根据塑料管接触水的极限臭味值(TON)估测,在测试的7种PE-HD管材中有5种PE-HD管的TON-4; 2种PE-HD管释放到水中挥发性有机物(VOC)的总量基本恒定;PEX管迁移实验显示大量的VOC迁移到水中(TON-5),其中一些迁移的VOC成分不确定;HPVC管向水中迁移的挥发性物质很少。

关键词: 塑料水管, 挥发性有机物, 迁移

Abstract: Water pipes of high-density polyethylene (PE-HD),crosslinked polyethylene pipes (PE-X),and rigid polyvinyl chloride) (PVC-U) were tested with respect to migration of volatile organic components ( VOC) into water. the odour of water in contact with plastic pipes was assessed according to the quantitative threshold odour number (SON).the major migrating component from PE-HD pipe was 2,4-di-tert-butyl-phenol (2,4-DTBP) which is a degradation product from phenol antioxidants. In addition, esters, aldehydes, ketones, aromatic hydrocarbons, and terpenoids were identified as migrationproducts from PE-HI)pipe. Water in contact with 5/7 PE-HDpipe was assessed as TON≥4.A significant amount of VAC migrated from PE-X pipe into water with TON≥5,some of the migrated VOC were not identified. In contrast, PVC-U pipes released few volatile migrants into water, from which no obvious odour detected.

Key words: plastics water pipe, volatile organic component, migration