中国塑料 ›› 2008, Vol. 22 ›› Issue (08): 41-45 .DOI: 10.19491/j.issn.1001-9278.2008.08.009

• 材料与性能 • 上一篇    下一篇

环氧树脂/纳米Si3N4复合材料的制备与性能研究

吉小利,徐国财,王君
  

  1. 安徽理工大学化学工程学院,安徽淮南232001
  • 收稿日期:2008-04-26 修回日期:1900-01-01 出版日期:2008-08-26 发布日期:2008-08-26

Preparation and Properties of Epoxy/Nano Si3N4 Composites

JI Xiao-li,XU Guo-cai,WANG J un   

  1. School of Chemical Engineering,Anhui University of Science and Technology,Huainan 232001,C;hina
  • Received:2008-04-26 Revised:1900-01-01 Online:2008-08-26 Published:2008-08-26
  • Contact: JI Xiao-li

摘要: 以纳米Si3; N4为填料制备了环氧树脂/纳米Si3; N4复合材料。通过透射电镜观察到,纳米粒子在有机基体中分散均匀。研究了纳米Si;N}对复合材料性能的影响,结果表明,添加纳米Si3; N4使复合材料的力学性能增加,当改性环氧树脂/纳米Si3; N4为100 /3(质量比,下同)时,复合材料的拉伸强度、弯曲强度、冲击强度提高幅度最大,分别提高了145% ,241 % ,255%。此时,复合材料的击穿场强提高的幅度也达到最大,在直流电压和交流电压下,分别提高了249 % ,146%;但添加纳米Si3; N4使复合材料的介电常数和介质损耗值减小;热重分析表明,环氧树脂/纳米Si3; N4复合材料耐热性能有明显提高。并用“核一壳过渡层”结构模型初步探讨了各项性能改善的原因。

关键词: 环氧树脂, 纳米氮化硅, 复合材料, 力学性能, 电学性能

Abstract: Epoxy/nano Si3}4 composites were prepared and their properties were investigated. The uni-form dispersion of nanoparticles in epoxy matrix was observed via TEM. When the loading of surface treated nano-Si3}4 was 3 wt%,the impact,tensile, and flexural strengths of the composites were in-
creased by 14S%,241%,and 2SS%,respectively; the electrical breakdown voltages under八C and DC were increased by 249%and 146%,respectively. The dielectric loss factor tan } and the dielectric constant s of nanocomposites were decreased.TG determination showed a better heat-resistance for the nanocomposites. The improvement in these properties was discussed with a model of "kernel- transition-al shell" structure.

Key words: epoxy resin, nano-silicon nitride, composite, mechanical property, electrical property