中国塑料 ›› 2010, Vol. 24 ›› Issue (12): 89-93 .DOI: 10.19491/j.issn.1001-9278.2010.12.019

• 加工与应用 • 上一篇    下一篇

水发泡抗静电半硬质聚氨酯泡沫塑料的制备和性能研究

梁书恩 田春蓉 王建华 蔚春蓉   

  1. 中国工程物理研究院化工材料研究所
  • 收稿日期:2010-09-13 修回日期:2010-10-14 出版日期:2010-12-26 发布日期:2010-12-26

Research on Preparation and Properties of Water Blown Antistatic Semi-rigid Polyurethane Foams

Liang Shu-En TIAN Chun-rong TIAN WANG Jian-hua WANG WEI Chun-rong WEI   

  • Received:2010-09-13 Revised:2010-10-14 Online:2010-12-26 Published:2010-12-26
  • Contact: Liang Shu-En

摘要: 采用内部添加导电炭黑(CB)方法,通过一步法模塑成型工艺制备了不同导电炭黑或硬段(HS)含量的水发泡抗静电半硬质聚氨酯泡沫塑料(SRPUF)。测试了SRPUF的红外光谱、导电性能、力学性能和黏弹性。结果表明,随着导电炭黑或硬段含量的增加,SRPUF的体积电阻率下降;随着导电炭黑含量的增加,SRPUF的拉伸模量提高,拉伸强度和断裂伸长率显著下降;随着硬段含量的增加,SRPUF的拉伸和压缩模量增大,抗压能力提高,拉伸强度基本不变,而断裂伸长率显著下降;随着导电炭黑或硬段含量的增加,SRPUF的玻璃化转变温度(Tg)分别向低温和高温方向移动,动态模量则均在温度低于Tg时逐渐下降,温度高于Tg时逐渐提高。

关键词: 聚氨酯, 泡沫塑料, 抗静电, 力学性能, 粘弹性

Abstract: Water blown antistatic semi-rigid polyurethane foams (SRPUF) with different content of conductive carbon black (CB) or hard segment (HS) were prepared through one-step moulding process. IR spectra, electro conductivity, mechanical and viscoelastic properties of SRPUF were characterized. With increasing content of CB or HS, volumetric resitivity of SRPUF decreased. With increasing content of CB, tensile modulus of SRPUF increased, but tensile strength and elongation at break decreased. With increasing content of HS, modulus and compressive strength increased, tensile strength remained unchanged, but elongation at break decreased obviously. With increasing content of CB or HS, glass transition temperature (Tg) of SRPUF moved to lower temperature or higher temperature respectively, but dynamic modulus changed similarly: decreased gradually at lower temperature than Tg, and increased gradually at higher temperature than Tg.

Key words: Polyurethane, Foam, antistatic behavior, mechanical property, Viscoelastic Property