中国塑料 ›› 2011, Vol. 25 ›› Issue (01): 97-101 .DOI: 10.19491/j.issn.1001-9278.2011.01.022

• 助剂 • 上一篇    下一篇

新型受阻酚类抗氧剂的合成与性能研究

李翠勤 王俊 方宏 葛腾杰   

  1. 东北石油大学(原大庆石油学院)化学化工学院
  • 收稿日期:2010-10-11 修回日期:2010-11-08 出版日期:2011-01-26 发布日期:2011-01-26

Synthesis and Properties of Novel Hindered Phenolic Antioxidant

LI Cuiqin WANG Jun FANG Hong GE Tengjie   

  • Received:2010-10-11 Revised:2010-11-08 Online:2011-01-26 Published:2011-01-26
  • Contact: LI Cuiqin

摘要: 以2,6-二叔丁基苯酚原料,合成了1种新型受阻酚抗氧剂2,6-二叔丁基-4-氨基苯酚,研究了该新型抗氧剂对聚烯烃材料的抗氧化作用。结果表明,以锌粉为还原剂,8.5 %氯化钙水溶液用量为90 mL,溶剂乙醇用量为100 mL, 在80 ℃下反应8 h,新型受阻酚抗氧剂的产率达80 %以上,熔程为112.2~113.3 ℃。该抗氧剂在2种聚烯烃材料中均具有良好的加工稳定性和抗氧化性能,氧化诱导期与市售抗氧剂1076相当,优于抗氧剂BHT;经5次挤出后,添加新型抗氧剂的聚烯烃材料的熔体流动速率变化很小,但拉伸强度和断裂伸长率大幅度提高。

关键词: 2, 6-二叔丁基-4-氨基苯酚, 氧化诱导期, 抗氧化性能, 2, 6-二叔丁基苯酚, 受阻酚抗氧剂

Abstract: A novel hinderd phenolic antioxidant 2,6-di-tert-butyl-4-aminophenol was synthesized with 2,6-di-tert-butylphenol as a raw material. When zinc powder was used as a reducing agent, ethanol as a solvent was 100 mL, the amount of calcium chloride solution was 90 mL, the reaction temperature was 80℃ and the reaction time was 8 h, the yield of the product reached 80 % and its melting point was between 112.2 ℃and 113.3 ℃. When loaded in polyolefin resins, the anti-oxidation property of the novel one was equal to antioxidant 1076 and was superior to antioxidant BHT. After 5 times extrusion, the melt flow rate of the two polyolefins containing the novel antioxidant changed a little, and the tensile strength and the elongation at break increased.

Key words: 2, 6-di-tert-butyl-4-aminophenol, oxidation induction time, oxidation resistance property, 2, 6-di-tert-butylphenol, hinderd phenolic antioxidant