中国塑料 ›› 2011, Vol. 25 ›› Issue (07): 17-22 .DOI: 10.19491/j.issn.1001-9278.2011.07.004

• 材料与性能 • 上一篇    下一篇

大豆分离蛋白/聚乙烯醇塑料的制备及性能研究

刘亮 张丽叶   

  1. 北京化工大学 北京化工大学生命科学与技术学院
  • 收稿日期:2011-04-13 修回日期:1900-01-01 出版日期:2011-07-26 发布日期:2011-07-26

Preparation and Properties of Soy Protein Isolate/PVA Plastics

LIU Liang;ZHANG Liye   

  • Received:2011-04-13 Revised:1900-01-01 Online:2011-07-26 Published:2011-07-26
  • Contact: ZHANG Liye

摘要: 将聚乙烯醇(PVA)按不同比例与大豆分离蛋白(SPI)混合,采用丙三醇作为增塑剂,经模压成型制备SPI/PVA塑料,采用X射线衍射仪、动态热机械分析仪、差示扫描量热仪、万能电子拉力试验机、扫描电子显微镜等研究了SPI/PVA塑料的结构、形态和性能。结果表明,丙三醇增塑的SPI会出现微相分离,即出现富丙三醇微区和富蛋白微区,而PVA的加入主要破坏了SPI在富丙三醇微区的晶体结构,并使富丙三醇微区的玻璃化转变温度向高温方向偏移。PVA的加入还明显提高了SPI/PVA塑料的拉伸强度,当PVA含量为1份时,其拉伸强度比纯SPI塑料提高了41.5 %;PVA的加入对SPI/PVA塑料的吸水性也有明显改善,其24 h吸水率从134.86 %下降到77.38 %。

关键词: 大豆分离蛋白, 聚乙烯醇, 结构, 力学性能, 吸水性

Abstract: Polymer blends were prepared via thermo-pressing mixtures of soy protein isolate(SPI) and poly (vinyl alcohol) (PVA) using glycerol as a plasticizer. The structure, morphology, and properties of the blends were investigated using X-ray diffraction, dynamic mechanical analyzer, differential scanning calorimetry analyzer, universal electronic tensile testing machine, and scanning electron microscopy. Phase separation was observed between glycerol and SPI forming glycerol-rich and protein-rich domains. The addition of PVA significantly damaged the crystalline structure of SPI in glycerol-rich domain, and increased its glass transition temperature. When the content of PVA was 1 phr, the tensile strength of SPI/PVA increased by 41.5 %, and the 24 h water absorption of SPI/PVA decreased from 134.86 % to 77.38 %, based on neat SPI.

Key words: soy protein isolate, poly (vinyl alcohol), structure, mechanical property, water absorption ability

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