中国塑料 ›› 2012, Vol. 26 ›› Issue (06): 22-27 .DOI: 10.19491/j.issn.1001-9278.2012.06.004

• 材料与性能 • 上一篇    下一篇

聚氨酯/环氧树脂泡沫材料的制备及性能研究

张文博 佘文骊 董炜星 张月芳 武德珍   

  1. 北京化工大学 北京化工大学
  • 收稿日期:2012-01-10 修回日期:1900-01-01 出版日期:2012-06-26 发布日期:2012-06-26

Study on Preparation and Properties of Polyurethane/Epoxy Resin Foam

Wenbo ZHANG Wenli SHE Weixing DONG Yuefang ZHANG Dezhen WU   

  • Received:2012-01-10 Revised:1900-01-01 Online:2012-06-26 Published:2012-06-26
  • Contact: Dezhen WU

摘要: 采用环己烷、水为共发泡剂制备了聚氨酯、环氧树脂、聚乙二醇为主体成分的硬质泡沫材料,利用热失重仪、光学显微镜等对泡沫材料的热性能、力学性能及泡孔结构进行了研究。结果表明,随着聚乙二醇的加入,泡沫材料的压缩强度和冲击强度均呈现先增大后减小的趋势,当聚乙二醇含量为30份(质量份数,下同)时,泡沫材料的压缩强度和冲击强度均达到较佳水平;加入环氧树脂能够提高泡沫材料的热分解温度,且当其含量为15~20份时,泡沫材料的压缩强度和冲击强度均达到较高水平;泡沫材料的压缩强度、冲击强度在环己烷与水质量比为10/1时达到最大值。

关键词: 泡沫材料, 聚氨酯, 环氧树脂, 聚乙二醇, 力学性能

Abstract: Polyurethane/epoxy resin foam was prepared by one step method with cyclohexane and water as the foaming agent. Universal testing machine was used to test the mechanical strengths, thermo-gravimetric analysis was used to analyze thermal properties and optical microscope was used to characterize the cell structure. Effects of polyethylene glycol, epoxy resin on the apparent density, mechanical property and thermal stability of the polyurethane foam were studied. With increasing contents of polyethylene glycol, compressive and impact strength of the foam both first increased and then decreased. When contents of the polyethylene glycol were 30 phr, both compressive strength and impact strength achieved the best level. Thermal stability of foam increased when added epoxy resin to the system. When epoxy resin were 15~20 phr, the overall mechanical properties of foam were the best. Maximum compressive and impact strength were obtained when the cyclohexane/water was 10/1.

Key words: foam, polyurethane, epoxy resin, polyethylene glycol, mechanical property

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