中国塑料 ›› 2015, Vol. 29 ›› Issue (06): 53-58.DOI: 10.19491/j.issn.1001-9278.2015.06.010

• 材料与性能 • 上一篇    下一篇

环氧树脂/有机硅改性双马来酰亚胺的性能研究

王登武1,王芳2   

  1. 1. 西京学院2. 陕西学前师范学院
  • 收稿日期:2015-01-21 修回日期:2015-03-10 出版日期:2016-06-26 发布日期:2016-06-26

Properties of Epoxy/BMI Blends Modified with Organosilicone

  • Received:2015-01-21 Revised:2015-03-10 Online:2016-06-26 Published:2016-06-26

摘要: 以二(4氨基苯氧基)二甲基硅烷(SIDA)、双马来酰亚胺(BMI)和双酚A型环氧树脂(E-51)为原料,通过扩链反应制备了E-51/BMI/SIDA共混物。结果表明,当SIDA含量为20 %(质量分数,下同)时,E-51/BMI/SIDA的冲击强度和弯曲强度分别为38.52 kJ/m2和120.54 MPa;E-51/BMI/SIDA热失重5 %时的温度为336.8 ℃,600 ℃时的残炭量高达55.4 %;E-51/BMI/SIDA的吸水率在8 d时仅为0.78 %。

关键词: 双马来酰亚胺, 环氧树脂, 有机硅, 力学性能, 热性能

Abstract: A modified resin system of E-51/BMI/SIDA was prepared by expanding chain reaction of bis (4-aminophenoxy) dimethylsilane (SIDA) and BMI. When the content of SIDA was 20 wt %, the impact strength and flexural strength of E-51/BMI/SIDA was 38.52 kJ/m2 and 120.54 MPa, respectively. The 5 % weight loss temperature of E-51/BMI/SIDA was 336.8 ℃, and the char yield of the blends was 55.4 % at 600 ℃, the water absorption performance of E-51/BMI/SIDA was 0.78 % at 8 days.

Key words: N, N'-4, 4' -diphenylmethanebismaleimide, epoxy resin, organic silicon, mechanical property , thermal behavior