热塑性聚醚砜、聚醚酰亚胺泡沫材料的制备与研究现状

doi:10.19491/j.issn.1001-9278.2021.02.020

中国塑料 ›› 2021, Vol. 35 ›› Issue (2): 132-142.DOI: 10.19491/j.issn.1001-9278.2021.02.020

• 综述 • 上一篇

热塑性聚醚砜、聚醚酰亚胺泡沫材料的制备与研究现状

王从龙, 张一辉, 王向东(), 徐海云

北京工商大学化学与材料工程学院，北京 100036

收稿日期:2020-07-19 出版日期:2021-02-26 发布日期:2021-02-22

Current Statue in Preparation and Research of Thermoplastic Polyether Sulfone and Polyetherimide Foam

WANG Conglong, ZHANG Yihui, WANG Xiangdong(), XU Haiyun

College of Chemistry and Materials Engineering，Beijing Technology and Business University，Beijing 100036，China

Received:2020-07-19 Online:2021-02-26 Published:2021-02-22
Contact: WANG Xiangdong E-mail:wangxiangdong@th.btbu.edu.cn

摘要/Abstract

摘要：

介绍了高性能聚合物泡沫聚醚砜（PES）和聚醚酰亚胺（PEI）的制备工艺；综述了制备工艺、加工条件、纳米填料、共混等对于泡孔结构与泡沫性能的影响；并列举了PES和PEI泡沫的应用和发泡行为的异同。

关键词: 聚醚砜, 聚醚酰亚胺, 纳米填料, 共混, 固态发泡, 应用

Abstract:

This paper introduced the preparation technologies of high-performance polyethersulfone （PES） and polyetherimide （PEI） foams. The influences of preparation technology， processing conditions， nano-fillers and blends on the structure and properties of the foams were discussed. The similarity and difference between the PES and PEI foams in their applications and foaming behaviors were also presented.

Key words: polyethersulfone, polyetherimide, nano-packing, blending, solid foaming, application

中图分类号:

TQ323

王从龙, 张一辉, 王向东, 徐海云. 热塑性聚醚砜、聚醚酰亚胺泡沫材料的制备与研究现状[J]. 中国塑料, 2021, 35(2): 132-142.

WANG Conglong, ZHANG Yihui, WANG Xiangdong, XU Haiyun. Current Statue in Preparation and Research of Thermoplastic Polyether Sulfone and Polyetherimide Foam[J]. China Plastics, 2021, 35(2): 132-142.

图/表 11

图1 PES纳米复合泡沫泡孔密度与发泡温度的关系

Fig.1 The relationship between PES nanocomposite foam cell density and foaming temperature

图2 改性化学镀工艺原理

Fig.2 Schematic of modified electroless plating process

图3 在DMF中表面溶剂溶解后，PES微纳级泡沫表面图

Fig.3 Surface of PES micro?nano graded foam after surface solvent dissolution in DMF

图4 由斜冲击试验得到的标准头盔和原型头盔的加速度?时间曲线图

Fig.4 Resultant acceleration?time curves obtained from oblique impact test for standard and prototype helmets

图5 WVIPS法制备PEI?GnP泡沫

Fig.5 Preparation of PEI?GNP foam by WVIPS

聚合物

导热系数/

W·(mK)^-1

拉伸应力/

MPa

密度/

g·cm^-3

表1 PEI和PES的性能

Tab.1 Performance of PEI and PES

图6 PEI微纳过渡泡沫的微观结构

Fig.6 Microstructure of PEI micro?nano transition foam

图7 固态发泡中，纯PES、PEI、PPSU、PEN的发泡性能

Fig.7 Foaming behavior of pure PES, PEI, PPSU and PEN in solid foaming

图8 各聚合泡沫在CO2被去除后的孔隙度

Fig.8 Porosity of each polymerization foam after CO2 removal

图9 PEI和PES的内压力与等效泡孔直径的关系

Fig.9 Dependence of the internal pressure of PEI and PES with the equivalent cell diameter

图10 PES与PEI的分子结构式

Fig.10 Molecular structure of PES and PEI

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热塑性聚醚砜、聚醚酰亚胺泡沫材料的制备与研究现状

Current Statue in Preparation and Research of Thermoplastic Polyether Sulfone and Polyetherimide Foam

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