聚乳酸/热塑性聚氨酯共混材料研究进展

doi:10.19491/j.issn.1001-9278.2023.09.011

中国塑料 ›› 2023, Vol. 37 ›› Issue (9): 75-82.DOI: 10.19491/j.issn.1001-9278.2023.09.011

聚乳酸/热塑性聚氨酯共混材料研究进展

崔成志¹^,², 曹金星¹, 刘建兰², 张辉¹()

^1.南京晓庄学院，南京 211171
^2.南京工业大学，南京 211816

收稿日期:2023-04-21 出版日期:2023-09-26 发布日期:2023-09-18
通讯作者: 张辉（1964-），男，教授，从事分子材料设计合成等，357585200@qq.com
E-mail:357585200@qq.com

Research progress in poly(lactic acid)/thermoplastic polyurethane blends

CUI Chengzhi¹^,², CAO Jinxing¹, LIU Jianlan², ZHANG Hui¹()

^1.NanJing XiaoZhuang University，Nanjing 211171，China
^2.Nanjing Tech University，Nanjing 211816，China

Received:2023-04-21 Online:2023-09-26 Published:2023-09-18
Contact: ZHANG Hui E-mail:357585200@qq.com

摘要/Abstract

摘要：

对聚乳酸/热塑性聚氨酯共混材料的界面、功能化、形状记忆性能改性研究进行了综述，并对该共混材料的研究发展方向进行了展望。

关键词: 聚乳酸, 热塑性聚氨酯, 界面, 功能化, 形状记忆性能

Abstract:

This article reviewed the research progress in the interface， functionalization， and shape memory modification of poly（lactic acid）/thermoplastic polyurethane blends and prospected the future direction in the research and development of the blends.

Key words: poly（lactic acid）, thermoplastic polyurethane, interface, functionalization, shape memory performance

中图分类号:

TQ321

崔成志, 曹金星, 刘建兰, 张辉. 聚乳酸/热塑性聚氨酯共混材料研究进展[J]. 中国塑料, 2023, 37(9): 75-82.

CUI Chengzhi, CAO Jinxing, LIU Jianlan, ZHANG Hui. Research progress in poly(lactic acid)/thermoplastic polyurethane blends[J]. China Plastics, 2023, 37(9): 75-82.

图/表 9

图1 PLA的水解降解机理［10］

Fig.1 Hydrolytic degradation mechanism of PLA［10］

图2 （a）PLA与TPU间可能的氢键和（b）TPU链间可能的氢键［19］

Fig.2 （a） Possible hydrogen bonds between PLA and TPU；（b） Possible hydrogen bonds between TPU chains［19］

图3 PLA/TPU（质量比90∶10）海岛结构SEM照片［22］

Fig.3 SEM of PLA/TPU （mass ratio 90∶10） island structure［22］

图4 TPU纤维网络SEM照片［23］

Fig.4 SEM diagram of TPU fiber network［23］

图5 PUEP增容改性实验流程示意图［28］

Fig.5 Schematic diagram of experimental flow for compatibilization and modification of PUEP［28］

图6 连续TPU中的纤维网络［31］

Fig.6 Fiber network in continuous TPU［31］

图7 TPU与GO纳米片相互作用示意图［22］

Fig.7 Schematic diagram of the interaction between TPU and GO nanosheet［22］

图8 TPU热响应形状恢复机制［40］

Fig.8 TPU thermal response shape recovery mechanism［40］

图9 PLA/TPU共混物形状记忆机理示意图［7］

Fig.9 Schematic diagram of shape memory mechanism of PLA/TPU blends［7］

参考文献 47

1	Mohamed Ali E Kshad，Hani E Naguib. Development and modeling of multi⁃phase polymeric origami inspired architecture by using pre⁃molded geometrical features［J］. Smart Materials and Structures，2017，26（2）：10.1088/1361⁃665x/26/2/025012.
2	Denizhan Yavas， Liu Qingyang， Zhang Ziyang， Wu Dazhong，et al. Design and fabrication of architected multi⁃material lattices with tunable stiffness， strength， and energy absorption［J］. Materials & Design，2022，217：10.1016/j.matdes.2022.110613.
3	Aishwarya Gosavi， Atul Kulkarni， Yogiraj Dama， Abhijeet Deshpande， Bhagwan Jogi，et al. Comparative analysis of drop impact resistance for different polymer based materials used for hearing aid casing［J］. Materials Today： Proceedings，2022，49（P5）：2 433⁃2 441.
4	Hu Qingxi， Zhang Rennan， Zhang Haiguang，et al. Topological structure design and fabrication of biocompatible PLA/TPU/ADM mesh with appropriate elasticity for hernia repair［J］. Macromolecular Bioscience，2021，21（6）：e2000423.
5	Cuellar Juan Sebastian， Dick Plettenburg， Zadpoor Amir A，et al. Design of a 3D⁃printed hand prosthesis featuring articulated bio⁃inspired fingers.［J］. Proceedings of the Institution of Mechanical Engineers. Part H， Journal of Engineering in Medicine，2020，235（3）：336⁃345.
6	Mi Hao⁃Yang， Salick Max R， Xin Jing，et al. Characterization of thermoplastic polyurethane/polylactic acid （TPU/PLA） tissue engineering scaffolds fabricated by microcellular injection molding［J］. Materials Science & Engineering C，2013，33（8）：4 767⁃4 776.
7	Xin Jing， Hao Yang Mi， Xiang Fang Peng，et al. The morphology， properties， and shape memory behavior of polylactic acid/thermoplastic polyurethane blends［J］. Polymer Engineering & Science，2015，55（1）：70⁃80.
8	Lou Ching⁃Wen， Lu Chao⁃Tsang， Lin Chin⁃Mei，et al.Process technology and performance evaluation of functional knee pad［J］. Fibers and Polymers，2010，11（1）：136⁃141.
9	Khalili N， Asif H， Naguib H E. Towards development of nanofibrous large strain flexible strain sensors with programmable shape memory properties［J］. Smart Materials and Structures，2018，27（5）：10.1088/1361⁃665X/aab417.
10	Rosli Noor Afizah， Mehlika Karamanlioglu， Hanieh Kargarzadeh，et al. Comprehensive exploration of natural degradation of poly（lactic acid） blends in various degradation media： A review.［J］. International Journal of Biological Macromolecules，2021，187：732⁃741.
11	Khalifa Mohammed， Anandhan S， Wuzella Günter，et al. Thermoplastic polyurethane composites reinforced with renewable and sustainable fillers – a review［J］. Polymer⁃Plastics Technology and Materials，2020，59（16）：1⁃19.
12	Rizvi Reza， Naguib Hani. Porosity and composition dependence on electrical and piezoresistive properties of thermoplastic polyurethane nanocomposites［J］. Journal of Materials Research，2013，28（17）：2 415⁃2 425.
13	Strankowski Michał， Korzeniewski Piotr， Strankowska Justyna，et al. Morphology，mechanical and thermal properties of thermoplastic polyurethane containing reduced graphene oxide and graphene nanoplatelets［J］. Materials，2018，11（1）：82⁃82.
14	Aruna Kumar Barick，Deba Kumar Tripathy. Effect of nanofiber on material properties of vapor⁃grown carbon nanofiber reinforced thermoplastic polyurethane （TPU/CNF） nanocomposites prepared by melt compounding［J］. Composites Part A，2010，41（10）：1 471⁃1 482.
15	Bi Hongjie， Ren Zechun， Rui Guo，et al. Fabrication of flexible wood flour/thermoplastic polyurethane elastomer composites using fused deposition molding［J］. Industrial Crops & Products，2018，122：76⁃84.
16	Abu Bakar Sulong，Tayser Sumer Gaaz， Sahari Jaafar. Mechanical and physical properties of injection molded halloysite nanotubes⁃thermoplastic polyurethane nanocomposites［J］. Procedia ⁃ Social and Behavioral Sciences，2015，195（C）：2 748⁃2 752.
17	Mi Hao⁃Yang， Salick Max R， Jing Xin，et al. Electrospinning of unidirectionally and orthogonally aligned thermoplastic polyurethane nanofibers： fiber orientation and cell migration.［J］. Journal of Biomedical Materials Research， Part A，2015，103（2）：593⁃603.
18	Dasdemir Mehmet， Topalbekiroglu Mehmet， Demir Ali. Electrospinning of thermoplastic polyurethane microfibers and nanofibers from polymer solution and melt［J］. Journal of Applied Polymer Science，2013，127（3）：1 901⁃1 908.
19	Oliaei Erfan， Kaffashi Babak， Davoodi Saeed. Investigation of structure and mechanical properties of toughened poly（ l⁃lactide）/thermoplastic poly（ester urethane） blends［J］. Journal of Applied Polymer Science，2016，133（15）：10.1002/app.43104.
20	Liu Zheng⁃Wei， Chou Hung⁃Chia， Chen Szu⁃Hsien，et al.Mechanical and thermal properties of thermoplastic polyurethane⁃toughened polylactide⁃based nanocomposites［J］. Polymer Composites，2014，35（9）：1 744⁃1 757.
21	Fei Feng， Lin Ye. Morphologies and mechanical properties of polylactide/thermoplastic polyurethane elastomer blends［J］. Journal of Applied Polymer Science，2011，119（5）：2 778⁃2 783.
22	Fatemeh Azadi，Khonakdar Hossein Ali，Jafari Seyed Hassan，et al. The effect of tailoring morphology on rheology and dielectric properties of poly （lactic acid） /thermoplastic polyurethane/graphene oxide nanocomposites［J］. Materials Today Communications，2022，33：10.1016/j.mtcomm.2022.104497.
23	Sun Haibin， Jing Hu， Xue Bai，et al. Largely improved toughness of poly（lactic acid） by unique electrospun fiber network structure of thermoplastic polyurethane［J］. Polymer Testing，2017，64：250⁃253.
24	Sebnem Kemaloglu Dogan，Efren Andablo Reyes， Rastogi Sanjay，et al. Reactive compatibilization of PLA/TPU blends with a diisocyanate［J］. Journal of Applied Polymer Science，2014，131（10）：10.1002/app.40251.
25	Dogan S K， Boyacioglu S， Kodal M，et al. Thermally induced shape memory behavior， enzymatic degradation and biocompatibility of PLA/TPU blends： “Effects of compatibilization”［J］. Journal of the Mechanical Behavior of Biomedical Materials，2017，71：349⁃361.
26	Mo Xian⁃Zhong， Wei Fu⁃Xiang， Tan Deng⁃Feng，et al. The compatibilization of PLA⁃g⁃TPU graft copolymer on polylactide/thermoplastic polyurethane blends［J］. Journal of Polymer Research，2020，27（17）：19⁃640.
27	Yusuf Kahraman， Burcu Özdemir， Volkan Kılıç，et al. Super toughened and highly ductile PLA/TPU blend systems by in situ reactive interfacial compatibilization using multifunctional epoxy‐based chain extender［J］. Journal of Applied Polymer Science，2021，138（20）：10.1002/APP.50457.
28	Zhang Hai⁃Chen， Kang Ben⁃hao， Chen Le⁃Shan，et al. Enhancing toughness of poly （lactic acid）/Thermoplastic polyurethane blends via increasing interface compatibility by polyurethane elastomer prepolymer and its toughening mechanism［J］. Polymer Testing，2020，87（C）：10.1016/j.polymertesting.2020.106521.
29	Zahra Shakouri， Hossein Nazockdast. Microstructural development and mechanical performance of PLA/TPU blends containing geometrically different cellulose nanocrystals［J］. Cellulose，2018，25（12）：7 167⁃7 188.
30	Fang Hui， Zhang Lingjie， Chen Anlin，et al. Improvement of mechanical property for PLA/TPU blend by adding PLA⁃TPU copolymers prepared via in situ ring⁃opening polymerization［J］. Polymers，2022，14（8）：1 530.
31	Qian Kaiyao， Xin Qian， Chen Yulong，et al. Poly（lactic acid）–thermoplastic poly（ether）urethane composites synergistically reinforced and toughened with short carbon fibers for three‐dimensional printing［J］. Journal of Applied Polymer Science，2018，135（29）：10.1002/app.46483.
32	Pandey Kalpana， Antil Rohit， Saha Sampa，et al. Poly（lactic acid）/thermoplastic polyurethane/wood flour composites： evaluation of morphology， thermal， mechanical and biodegradation properties［J］. Materials Research Express，2019，6（12）：125306.
33	Bahareh Ghassemi， Sara Estaji，Mousavi Seyed Rasoul，et al. In⁃depth study of mechanical properties of poly（lactic acid）/thermoplastic polyurethane/hydroxyapatite blend nanocomposites［J］. Journal of Materials Science，2022，57（14）：7 250⁃7 264.
34	Zhang Zixi， Xiang Dong， Wu Yuanpeng，et al. Effect of carbon black on the strain sensing property of 3D printed conductive polymer composites［J］. Applied Composite Materials，2022（prepublish）：1⁃14.
35	Yuan Wei， Rui Huang， Peng Dong，et al. Preparation of polylactide/poly（ether）urethane blends with excellent electro⁃actuated shape memory via incorporating carbon black and carbon nanotubes hybrids fillers［J］. Chinese Journal of Polymer Science，2018，36（10）：1 175⁃1 186.
36	Krishnendu Nath， Sabyasachi Ghosh，Ghosh Suman Kumar，et al. Facile preparation of light‐weight biodegradable and electrically conductive polymer based nanocomposites for superior electromagnetic interference shielding effectiveness［J］. Journal of Applied Polymer Science，2021，138（22）：10.1002/APP.50514.
37	Xu Daifang， Yu Kejing， Qian Kun，et al. Foaming behavior of microcellular poly（lactic acid）/TPU composites in supercritical CO₂ ［J］. Journal of Thermoplastic Composite Materials，2018，31（1）：61⁃78.
38	Qu Zhongjie， Yin Dexian， Zhou Hongfu，et al. Cellular morphology evolution in nanocellular poly （lactic acid）/thermoplastic polyurethane blending foams in the presence of supercritical N₂ ［J］. European Polymer Journal，2019，116：291⁃301.
39	Shen Wanting， Wu Wei， Liu Chao，et al. Thermal conductivity enhancement of PLA/TPU/BN composites by controlling BN distribution and annealing treatment［J］. Plastics， Rubber and Composites，2020，49（5）：204⁃213.
40	He Shaoyun， Hu Shikai， Wu Yaowen，et al. Polyurethanes based on polylactic acid for 3D printing and shape⁃memory applications［J］. Biomacromolecules，2022：10.1021/ACS.BIOMAC.2C00662.
41	Boyacioglu S， Kodal M， Ozkoc G. A comprehensive study on shape memory behavior of PEG plasticized PLA/TPU bio⁃blends［J］. European Polymer Journal，2020，122（C）：109372.
42	Sorimpuk Neilson Peter， Wai Heng Choong， BihLii Chua. Thermoforming characteristics of PLA/TPU multi⁃material specimens fabricated with fused deposition modelling under different temperatures［J］. Polymers，2022，14（20）：4304.
43	Cai Shenyang， Sun Yu⁃Chen， Ren Jie，et al. Toward the low actuation temperature of flexible shape memory polymer composites with room temperature deformability via induced plasticizing effect.［J］. Journal of Materials Chemistry， B，2017，5（44）：8 845⁃8 853.
44	Fatemeh Azadi，Jafari Seyed Hassan，Khonakdar Hossein Ali，et al. Influence of graphene oxide on thermally induced shape memory behavior of PLA/TPU blends： correlation with morphology， creep behavior， crystallinity， and dynamic mechanical properties［J］. Macromolecular Materials and Engineering，2020，306（2）：10.1002/MAME.202000576.
45	Lai Sun⁃Mou， Wu Wan⁃Ling， Wang Yu⁃Jhen. Annealing effect on the shape memory properties of polylactic acid （PLA）/thermoplastic polyurethane （TPU） bio⁃based blends［J］. Journal of Polymer Research，2016，23（5）：10.1007/s10965⁃016⁃0993⁃6.
46	Liu Han， Wang Feifan， Wu Wenyang，et al. 4D printing of mechanically robust PLA/TPU/Fe₃O₄ magneto⁃responsive shape memory polymers for smart structures［J］. Composites Part B，2023，248：10.1016/J.COMPOSITESB.2022.110382.
47	Dong Ke，Panahi Sarmad Mahyar， Cui Ziying，et al. Electro⁃induced shape memory effect of 4D printed auxetic composite using PLA/TPU/CNT filament embedded synergistically with continuous carbon fiber： A theoretical & experimental analysis［J］. Composites Part B： Engineering，2021（prepublish）：10.1016/J.COMPOSITESB.2021.108994.

[1]	王磊, 赵敏, 翁云宣, 张彩丽. 机器学习在聚乳酸加工及性能预测中的应用研究进展[J]. 中国塑料, 2023, 37(8): 127-134.
[2]	赵萌萌, 杨红娟, 沈思宇, 冯硕, 张伟蒙, 胡晶. 聚乙二醇二缩水甘油醚对PLA/PBAT共混材料相容性及性能的影响[J]. 中国塑料, 2023, 37(8): 20-27.
[3]	杜乐, 胡娅洁, 胡健, 孙滔, 云雪艳, 董同力嘎. UV固化制备聚（L⁃乳酸）/壳聚糖薄膜及其热学、力学及抑菌性能研究[J]. 中国塑料, 2023, 37(8): 38-44.
[4]	陈宇, 张春辉, 崔正, 孙同兵. 复合塑料软包装材料健康发展的机遇和挑战[J]. 中国塑料, 2023, 37(2): 56-61.
[5]	汪杰, 张伟蒙, 胡晶. 聚乳酸⁃羟基乙酸共聚物涂层对聚乳酸3D打印支架的性能影响[J]. 中国塑料, 2023, 37(1): 1-7.
[6]	周新星, 郑玉婴, 陈乘鑫, 孔繁盛. 热塑性聚氨酯/石墨烯改性聚氨酯注浆材料的制备与性能研究[J]. 中国塑料, 2023, 37(1): 54-59.
[7]	孟鑫, 王小龙, 公维光, 金谊. “三源一体”壳核型阻燃剂的制备及其在聚乳酸中的应用[J]. 中国塑料, 2022, 36(9): 96-104.
[8]	宋丹阳, 郑红娟, 李一龙. 聚乳酸基油水分离材料研究进展[J]. 中国塑料, 2022, 36(9): 187-192.
[9]	曲玉婷, 王立梅, 齐斌. 聚乙二醇对聚乳酸/淀粉纳米晶复合材料性能的影响[J]. 中国塑料, 2022, 36(8): 56-61.
[10]	沈雪梅, 朱小龙, 胡燕超, 宋任远, 张现峰, 李席. 静电喷雾法制备聚乳酸/布洛芬微球及其性能研究[J]. 中国塑料, 2022, 36(7): 61-67.
[11]	周舒毅, 朱敏, 刘忆颖, 曹舒惠, 蔡启轩, 聂慧, 张玉霞, 周洪福. 高分子止血材料研究进展[J]. 中国塑料, 2022, 36(7): 74-84.
[12]	李凯泽, 辛勇. 改性碳纳米管增强热塑性聚氨酯复合材料的性能研究[J]. 中国塑料, 2022, 36(6): 1-5.
[13]	邵琳颖, 郗悦玮, 翁云宣. 可降解聚乳酸复合材料研究进展[J]. 中国塑料, 2022, 36(6): 155-164.
[14]	王镕琛, 张恒, 孙焕惟, 段书霞, 秦子轩, 李晗, 朱斐超, 张一风. 医疗卫生用聚乳酸非织造材料的制备及其亲水改性研究进展[J]. 中国塑料, 2022, 36(5): 158-166.
[15]	雷经发, 沈强, 刘涛, 孙虹, 尹志强. 熔融沉积工艺参数对热塑性聚氨酯弹性体静动态力学性能的影响[J]. 中国塑料, 2022, 36(5): 29-35.

聚乳酸/热塑性聚氨酯共混材料研究进展

Research progress in poly(lactic acid)/thermoplastic polyurethane blends

RichHTML

PDF

可视化

摘要/Abstract

引用本文

使用本文

图/表 9

参考文献 47

相关文章 15

编辑推荐

Metrics

本文评价