中国塑料 ›› 2025, Vol. 39 ›› Issue (11): 27-31.DOI: 10.19491/j.issn.1001-9278.2025.11.005

• 材料与性能 • 上一篇    下一篇

发泡剂热解行为及其产气量对聚丙烯基微孔木塑复合材料性能的影响

王苏炜1(), 胡平1, 宗胡曾2, 薛平3()   

  1. 1.南京理工大学化学与化工学院国家特种超细粉体工程技术研究中心,南京 210094
    2.山东非金属材料研究所,济南 250031
    3.北京化工大学塑料机械及塑料工程研究所,北京 100029
  • 收稿日期:2024-11-07 出版日期:2025-11-26 发布日期:2025-11-21
  • 通讯作者: 薛平(1963-),男,教授,从事聚合物高端加工装备成型理论及技术、聚合物基增强复合材料成型加工及聚合物及固体废弃物高值化利用,xueping@mail.buct.edu.cn
    E-mail:wangsw90@163.com;xueping@mail.buct.edu.cn
  • 作者简介:王苏炜(1990-),男,讲师,从事聚合物成型技术研究,wangsw90@163.com
  • 基金资助:
    中央高校基本科研业务费专项资金(30923011018)

Thermal decomposition behavior of foaming agent and its influence of gas yield on properties of microporous PP⁃based wood⁃plastic composites

WANG Suwei1(), HU Ping1, ZONG Huzeng2, XUE Ping3()   

  1. 1.National Special Superfine Powder Engineering Research Center of China,School of Chemistry and Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,China
    2.Institute of Shandong Non?Metallic Material,Jinan 250031,China
    3.Institute of Plastic Machinery and Engineering,Beijing University of Chemical Technology,Beijing 100029,China
  • Received:2024-11-07 Online:2025-11-26 Published:2025-11-21
  • Contact: XUE Ping E-mail:wangsw90@163.com;xueping@mail.buct.edu.cn

摘要:

针对当前木塑制品密度高、韧性差等问题,采用化学发泡技术来赋予材料微孔化的结构特点,进而通过裂纹钝化等方式来实现木塑材料增强增韧的目标,推动其高性能化应用。为此,以偶氮二甲酰胺发泡剂和碳酸氢钠发泡剂为研究对象,通过分析其热稳定性来研究发泡剂热解行为对泡孔形态参数的影响规律,并借助配方优化来进一步探索不同产气量下试样的力学性能变化趋势。结果表明,相较于碳酸氢钠发泡母粒,经过与氧化锌复配后的偶氮二甲酰胺发泡剂更容易获得“小而密”的微孔结构,且其用量为1份时可以获得孔径均值71 μm、分布密度2.7×104 个/cm3的微孔结构并赋予试样6 kJ/m2的冲击强度以及9.7 MPa的拉伸强度和22.1 MPa的弯曲强度。

关键词: 木塑复合材料, 聚丙烯, 发泡剂, 挤出成型, 微孔塑料

Abstract:

To address the high density and low toughness of conventional wood⁃plastic composites (WPCs), this study employed chemical foaming technology to introduce a microcellular structure into the material. Subsequent crack passivation and other methods were applied to achieve simultaneous enhancement and toughening, thereby facilitating high⁃performance applications of WPCs. Using azodicarbonamide (ADC) and sodium bicarbonate (SBC) as foaming agents, the influence of their pyrolysis behavior on cellular morphology was investigated through thermal stability analysis. Formula optimization was further conducted to examine the effect of gas production rate on the mechanical properties of the composites. The results indicated that, compared to SBC⁃based foam masterbatch, ADC foaming agent compounded with zinc oxide was easier to yield a “fine and dense” microcellular structure. At an optimal dosage of 1 phr, a microporous structure with an average cell size of 71 μm and a cell density of 2.7×10⁴ cells/cm³ was achieved. The corresponding impact strength, tensile strength, and flexural strength of the composite reached 6 kJ/m², 9.7 MPa, and 22.1 MPa, respectively.

Key words: wood plastic composite material, polypropylene, foaming agent, extrusion molding, microporous plastic

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