中国塑料 ›› 2014, Vol. 28 ›› Issue (11): 42-46 .DOI: 10.19491/j.issn.1001-9278.2014.11.008

• 材料与性能 • 上一篇    下一篇

聚醚醚酮/多壁碳纳米管复合材料力学及阻燃性能研究

王志1,雷卓研1,张晓玲2,杨甜甜1,徐艳英1   

  1. 1. 沈阳航空航天大学2. 航天精工股份有限公司
  • 收稿日期:2014-05-15 修回日期:2014-05-30 出版日期:2014-11-26 发布日期:2014-11-26

Mechanical and Flame Retardant Properties of PEEK/MWCNT Composites

  • Received:2014-05-15 Revised:2014-05-30 Online:2014-11-26 Published:2014-11-26

摘要: 通过熔融共混法将聚醚醚酮(PEEK)与多壁碳纳米管(MWCNT)混合,利用模压法制备了MWCNT增强型PEEK复合材料,研究了MWCNT对PEEK性能的影响。结果表明,添加一定比例的MWCNT能够提高PEEK的力学和阻燃性能;当MWCNT含量为5%(质量分数,下同)时,PEEK的弯曲强度提高了53%;当MWCNT含量为1%时,锥形量热法测得的热释放速率峰值最低,燃烧性能指数值最大,热重分析显示初始分解温度较纯PEEK提高了13℃,表明MWCNT有效地提高了PEEK的阻燃和热稳定性能。

关键词: 聚醚醚酮, 多壁碳纳米管, 复合材料, 力学性能, 阻燃

Abstract: Poly( ether ether ketone) (PEEK) and multi-walled carbon nanotubes(MWCNT)were mixed via melt blending leading to composites. The effect of MWCNT on the properties of PEEK was analyzed. It showed that a certain amount of MWCNT could improve the mechanical and flame retardant properties of PEEK. When 5%(mass content)of MWCNT was added,the flexural strength increased by 53%. When the mass content of MWCNT was 1% (mass content), the composites had minimum peak heat release rate and maximum cone calorimetry combustion index value. Thermogravimetric analysis showed that the initial decomposition temperature was increased about 13 ℃, which indicates that MWCNT effectively improve the flame retardant and thermal stability of PEEK.

Key words: poly(ether ether ketone), multi-walled carbon nanotube, composite, mechanical property, flame retardancy