
《中国塑料》编辑部 ©2008-2024 版权所有
地址:北京市海淀区阜成路11号 邮编:100048
编辑部:010-68985541 联系信箱:cp@plaschina.com.cn
广告部/发行部:010-68985253 本系统由北京玛格泰克科技发展有限公司设计开发
›› 2023, Vol. 37 ›› Issue (6): 123-130.
宫芳芳1,陶梦伟1,王靖宇1,钱立军2
收稿日期:
2022-11-10
修回日期:
2022-12-04
出版日期:
2023-06-26
发布日期:
2023-06-26
基金资助:
Received:
2022-11-10
Revised:
2022-12-04
Online:
2023-06-26
Published:
2023-06-26
摘要: 综述了近年来热塑性聚烯烃弹性体材料无卤阻燃的研究进展,介绍了各类阻燃剂对材料阻燃和力学性能的影响。用于热塑性聚烯烃弹性体的无卤阻燃剂以金属氢氧化物阻燃剂和膨胀型阻燃剂为主,磷酸盐类膨胀型阻燃剂应用最为广泛,新型单组分膨胀型阻燃剂已成为发展趋势。
宫芳芳 陶梦伟 王靖宇 钱立军. 无卤阻燃热塑性聚烯烃弹性体的研究进展[J]. , 2023, 37(6): 123-130.
[1] PIERRO I, LEONE G, ZANCHIN G, et al. Polyolefin thermoplastic elastomers from 1-octene copolymerization with 1-decene and cyclopentene[J]. European Polymer Journal, 2017, 93: 200-211.[2] 韩吉彬, 陈文泉, 张世甲, 等. 热塑性弹性体的研究与进展[J]. 弹性体, 2020, 30(03): 70-77.HAN J B, CHEN W Q, ZHANG S J, et al. Research and development of thermoplastic elastomers[J]. China Elastomerics, 2020, 30(03): 70-77.[3] 安文秀. 阻燃聚烯烃热塑性弹性体研究进展及相关阻燃法规[J]. 塑料科技, 2014, 42(04): 130-135.AN W X. Research progress and related fire retardant regulations of flame retardant thermoplastic polyolefin elastomer[J]. Plastics Science and Technology, 2014, 42(04): 130-135.[4] WANG W, LIU Y, HAN Z, et al. A coating method combined with bulk addition for efficient flame retardant thermoplastic polyolefin sheet material[J]. Polymer Degradation and Stability, 2020, 174: 109093.[5] HEINZ M, CALLSEN C, ST?CKLEIN W, et al. Halogen-free flame-retardant cable compounds: Influence of magnesium-di-hydroxide filler and coupling agent on EVA/LLDPE blend system morphology[J]. Polymer Engineering and Science, 2022, 62(2): 461.[6] AFZAL A, USAMA M, ABDUL R I, et al. Effect of MgOH/TiO2 on flame retardancy and mechanical behavior of composite[J]. Materials Research Express, 2020, 6(12): 125352.[7] 陈绪煌, 黄碧伟, 龙 鹏, 等. Al(OH)3/POE无卤阻燃复合材料的制备及性能研究[J]. 湖北工业大学学报, 2011, 26(05): 11-14.CHEN X H, HUANG B W, LONG P, et al. Preparation and properties of halogenfree flame retardant Al(OH)3/POE composite[J]. Journal of Hubei University of Technology, 2011, 26(05): 11-14.[8] 周 建, 何 涛, 贾少晋, 等. 辐射制备POE/EPDM/SR/MH无卤阻燃绝缘材料的研究[J]. 辐射研究与辐射工艺学报, 2010, 28(04): 201-207.ZHOU J, HE T, JIA S J, et al. Preparation of non-hologen flame retardant POE/EPDM/SR/MH insulation materials[J]. Journal of Radiation Research and Radiation Processing, 2010, 28(04): 201-207.[9] 陈镜融, 谷晓昱, 孙 军, 等. 氢氧化铝/氢氧化镁复配提高乙烯-醋酸乙烯共聚物阻燃性能[J]. 中国塑料, 2017, 31(09): 68-72.CHEN J R, GU X R, SUN J, et al. Improvement of flame retardancy of ethylene-vinyl acetate copolymer with Al(OH)3 and Mg(OH)2[J]. China Plastics, 2017, 31(09): 68-72.[10] 李初桐, 张胜星, 宋 刚, 等. Mg(OH)2-Al(OH)3-微胶囊红磷协同阻燃POE的研究[J]. 塑料工业, 2016, 44(04): 101-105.LI C T, ZHANG S X, SONG G, et al. Study of synergistic retarding effect of Mg(OH)2-Al(OH)3-microcapsule red phosphorus on POE[J]. China Plastics Industry, 2016, 44(04): 101-105.[11] SABET M, SOLEIMANI H, HOSSEINI S, et al. Thermal and flammable stability of radiated LDPE and composites[J]. International Journal of Plastics Technology, 2019, 23(2): 239-245.[12] 严长浩, 阮金森, 许稳定, 等. 电子束辐射改性无卤阻燃聚烯烃复合材料的性能研究[J]. 塑料科技, 2015, 43(03): 36-40.YAN C H, RUAN J S, XU W D, et al. Study on properties of halogen-free flame retardant polyolefin composites modified with electron beam radiation[J]. Plastics Science and Technology, 2015, 43(03): 36-40.[13] LOPATTANANON N, WALONG A, SAKAI T, et al. Influence of incorporation methods of ATH on microstructure, elastomeric properties, flammability, and thermal decomposition of dynamically vulcanized NR/PP blends[J]. Journal of Applied Polymer Science, 2018, 135(18): 46231.[14] 黄鹭鹭, 宋冠成. TPO防水卷材阻燃性能的初步探讨[J]. 中国建筑防水, 2021, (02): 10-14.HUANG L L, SONG G C. Preliminary discussion on flame-retardant property of TPO waterproofing membrane[J]. China Building Waterproofing, 2021, (02): 10-14.[15] BELTRáN-RAMíREZ F I, RAMOS-DEVALLE L F, RAMíREZ-VARGAS E, et al. Study of the addition of a thermoplastic vulcanizate to a HDPE composite highly filled with magnesium hydroxide and its effect on the tensile and flame retardant properties[J]. Journal of Nanomaterials, 2019, 2019: 4350870.[16] 冯 钠, 刘海秀, 王方明, 等. ATH协同阻燃TPO/MH复合体系性能研究[J]. 塑料科技, 2013, 41(10): 53-56.FENG N, LIU H X, WANG F M, et al. Study on properties of TPO/MH composites synergistically flame-retarded with ATH[J]. Plastics Science and Technology, 2013, 41(10): 53-56.[17] LAN S J, LI L J, XU D F, et al. Surface modification of magnesium hydroxide using vinyltriethoxysilane by dry process[J]. Applied Surface Science, 2016, 382: 56-62.[18] 冯 钠, 常文章, 樊明帅, 等. 低烟无卤阻燃TPO/MH复合体系性能研究[J]. 橡塑技术与装备, 2014, 40(22): 41-45. FENG N, CHANG W Z, FAN M S, et al. Performance of low smoke halogen-free erformance of low smoke halogen-free flame retardant flame retardant TPO/MH composite system[J]. China Rubber/Plastics Technology and Equipment, 2014, 40(22): 41-45.[19] WANG W, LIU Y, HAN Z Q, et al. A coating method combined with bulk addition for efficient flame-retardant thermoplastic polyolefin sheet material[J]. Polymer Degradation and Stability, 2020, 174: 109093.[20] 刘 川, 许苗军, 王景春, 等. 膨胀石墨对乙烯基硅橡胶的阻燃作用研究[J]. 中国塑料, 2022, 36(04): 15-18.LIU C, XU M J, WANG J C, et al. Effect of expandable graphite on flame retardant performance of vinyl silicone rubber[J]. China Plastics, 2022, 36(04): 15-18.[21] SAWANGPET K, WALONG A, THONGNUANCHAN B, et al. Foaming and physical properties, flame retardancy, and combustibility of polyethylene octene foams modified by natural rubber and expandable graphite[J]. Journal of Vinyl and Additive Technology, 2020, 26(4): 423-433.[22] 钱立军. 现代阻燃材料与技术[M]. 北京: 化学工业出版社, 2021: 164. [23] 汤 维, 钱立军, 邱 勇, 等. 聚丙烯材料无卤阻燃改性研究进展[J]. 中国塑料, 2021, 35(01): 136-149.TANG W, QIAN L J, QIU Y, et al. Research progress in halogen-free flame retardant technology for polypropylene[J]. China Plastics, 35(01): 136-149.[24] ZHANG Y F, YU C M, FENG X, et al. Simultaneously improving flame retardant performance, thermal stability and conductivity of copolymers of polyethylene-octene by addition of a ternary composite flame retardant system[J]. ChemistrySelect, 2022, 7(33): e202201778.[25] 李博睿, 肖淑娟, 吴双邯, 等. 聚磷酸铵与次磷酸铝的共微胶囊制备及其在阻燃聚丙烯中的应用[J]. 中国塑料, 2020, 34(11): 1-5.LI B R, XIAO S J, WU S H, et al. Preparation of co-microencapsulated ammonium polyphosphate/aluminum hypophosphite and its application in flame-retardant polypropylene[J]. China Plastics, 2020, 34(11): 1-5.[26] DENG C, YIN H J, LI R M, et al. Modes of action of a mono-component intumescent flame retardant MAPP in polyethylene-octene elastomer[J]. Polymer Degradation and Stability, 2017, 138: 142-150.[27] LI R M, DENG C, DENG C L, et al. An efficient method to improve simultaneously the water resistance, flame retardancy and mechanical properties of POE intumescent flame-retardant systems[J]. RSC Advances, 2015, 5(21): 16328-16339.[28] 钱 丹, 苑会林, 张 胜, 等. 熔融接枝法提高膨胀型阻燃聚丙烯的相容性和阻燃性能[J]. 高分子材料科学与工程, 2009, 25(06): 92-95.QIAN D, YUAN H L, ZHANG S, et al. Improving the compatibility and flammability of an intumescent flame-retardant polypropylene system through melt-grafting[J]. Polymer Materials Science & Engineering, 2009, 25(06): 92-95.[29] ZHANG Z N, LIN B, ZHOU N, et al. Flame‐retardant olefin block copolymer composites with novel halogen‐free intumescent flame retardants based on the composition of melamine phosphate and pentaerythritol[J]. Journal of Applied Polymer Science, 2014, 131(7): 40066.[30] CHEN X L, WEI Z B, WANG W D, et al. Properties of flame‐retardant TPU based on para‐aramid fiber modified with iron diethyl phosphinate[J]. Polymers for Advanced Technologies, 2019, 30(1): 170-178.[31] WANG S H, JIANG Y C, MENG Y J, et al. The encapsulation of intumescent flame retardants by poly-siloxane for thermoplastic polyolefin: Fire safety and water resistance[J]. Polymer Degradation and Stability, 2021, 188: 109561.[32] WU K, WANG X Y, XU Y H, et al. Flame retardant efficiency of modified para-aramid fiber synergizing with ammonium polyphosphate on PP/EPDM[J]. Polymer Degradation and Stability, 2020, 172: 109065.[33] WU Q, GUO J, FEI B, et al. Synthesis of a novel polyhydroxy triazine-based charring agent and its effects on improving the flame retardancy of polypropylene with ammonium polyphosphate and zinc borate[J]. Polymer Degradation and Stability, 2020, 175: 109123.[34] WANG W, LEI L, BAO Q R, et al. Synthesis of a triazine charring agent containing hydroxyl and triazine ring and its flame retardant application in thermoplastic polyolefin[J]. Journal of Applied Polymer Science, 2022, 139(38): e52920.[35] 樊明帅, 冯 钠, 曲敏杰, 等. 三嗪成炭剂和聚磷酸铵协同阻燃动态硫化热塑性弹性体阻燃性能及成炭机制[J]. 高分子材料科学与工程, 2019, 35(10): 77-83.FAN M S, FENG N, QU M J, et al. Flame retardant properties and char-forming mechanism of synergistic flame retardant thermoplastic vulcanizates between the triazine charring agent and ammonium polyphosphate[J]. Polymer Materials Science & Engineering, 2019, 35(10): 77-83.[36] HE W D, ZHOU Y, CHEN X L, et al. Novel intumescent flame retardant masterbatch prepared through different processes and its application in EPDM/PP thermoplastic elastomer: Thermal stability, flame retardancy, and mechanical properties[J]. Polymers, 2018, 11(1): 50.[37] CHEN C, ZHOU Y, HE W D, et al. Flammability, thermal stability, and mechanical properties of ethylene‐propylene‐diene monomer/polypropylene composites filled with intumescent flame retardant and inorganic synergists[J]. Journal of Applied Polymer Science, 2021, 138(13): 50116.[38] 魏思淼, 邵路山, 许 准, 等. 次磷酸盐-环四硅氧烷双基化合物复配二乙基次磷酸铝对PA6的阻燃性能研究[J]. 中国塑料, 2022, 36(07): 129-135.WEI S M, SHAO L S, XU Z, et al. Flame-retardant performance of PA6 modified with hypophosphitelsiloxane bi-functional compound and diethyl aluminum hypophosphite compound[J]. China Plastics, 2022, 36(07): 129-135.[39] FAN M S, FENG N, ZHANG Y J, et al. Synergistic effects of aluminium hypophosphite on the flame retardancy and thermal degradation behaviours of a novel intumescent flame retardant thermoplastic vulcanisate composite[J]. Plastics, Rubber and Composites, 2019, 48(6): 270-280.[40] 王靖宇, 郝建薇. 无卤阻燃硬质聚氨酯泡沫塑料的研究进展[J]. 中国塑料, 2020, 34(05): 107-114.WANG J Y, HAO J W. Research progress in halogen-free flame-retardant RPUF[J]. China Plastics, 2020, 34(05): 107-114.[41] 陈 涛, 肖 雄, 汪继奎, 等. 新型阻燃剂PAPP的合成及其在热塑性弹性体中的应用[J]. 塑料科技, 2018, 46(08): 116-121.CHEN T, XIAO X, WANG J K, et al. Synthesis of a novel flame retardant PAPP and its application in thermoplastic elastomer[J]. Plastics Science and Technology, 2018, 46(08): 116-121.[42] HU Z, ZHONG Z Q, GONG X D, et al. Flame retardancy, thermal properties, and combustion behaviors of intumescent flame-retardant polypropylene containing (poly)piperazine pyrophosphate and melamine polyphosphate[J]. Polymer for Advanced Technologies, 2020, 31: 2701-2710.[43] CHEN T, XIAO X, WANG J K, et al. Fire, thermal and mechanical properties of TPE composites with systems containing piperazine pyrophosphate (PAPP), melamine phosphate (MPP) and titanium dioxide (TiO2)[J]. Plastics, Rubber and Composites, 2019, 48(4): 149-159.[44] ZHU P, XU M, LI S, et al. Preparation and investigation of efficient flame retardant TPE composites with piperazine pyrophosphate/aluminum diethylphosphinate system[J]. Journal of Applied Polymer Science, 2020, 137: 47711.[45] TAO L L, XU Y, LIU L B, et al. A novel and efficient P/N/B-containing mono-component IFR for improving the flame retardancy of polyolefin elastomer[J]. Journal of Thermal Analysis and Calorimetry, 2022, 147(15): 8145-8155.[46] 何京秀, 陈雅君. 生物基阻燃剂阻燃聚乳酸的研究进展[J]. 中国塑料, 2021, 35(02): 119-131.HE J X, CHEN Y J. Research progress in flame-retardant PLA containing bio-based flame retardants[J]. China Plastics, 2021, 35(02): 119-131.[47] 王栖桐, 冯 钠, 刘 俐, 等. 酶解木质素阻燃剂的制备及其对TPO阻燃性能的影响[J]. 合成树脂及塑料, 2017, 34(01): 6-10.WANG X T, FENG N, LIU L, et al. Preparation of Lig-based intumescent flame retardant and its effect on flame resistance of TPO[J]. China Synthetic Resin and Plastics, 2017, 34(01): 6-10. |
[1] | 吴加俊 曾佳 刘缓缓 朱民 倪忠斌 施冬健 陈明清. 釜式发泡制备氢化苯乙烯-异戊二烯-苯乙烯/聚丙烯发泡珠粒及其性能研究[J]. , 2023, 37(6): 43-49. |
[2] | 郑兴博 李佳汶 李子辉 韩文娟 蒋晶 王小峰 李倩. 氮化硼改性超高分子量聚乙烯的摩擦学性能研究[J]. , 2023, 37(5): 28-33. |
[3] | 于盛睿 刘钦迪 徐磊 骆杰 吴辉庭 韩文 邹佳勇 周华民. 双面覆膜与纤维含量对MIM/IMD工艺翘曲变形及力学性能的影响[J]. , 2023, 37(5): 55-61. |
[4] | 顾建国 孙建凯 侯培培 何浩 焦文亮. 双轴取向聚氯乙烯管材解取向研究[J]. , 2023, 37(4): 35-38. |
[5] | 韩阳阳 杨晓炯 张贵恩 董春雨 张小刚. 导电橡胶力学性能和耐高温性能研究[J]. , 2023, 37(3): 24-29. |
[6] | 董竞辉, 桑晓明, 陈祯, 尹伟浩, 姜骞, 陈兴刚. 短切碳纤维对聚苯腈/碳纤维复合材料性能的影响[J]. 中国塑料, 2023, 37(2): 31-37. |
[7] | 段凯歌, 朱辉, 倪佳, 泮豪, 周朝锡, 陈小蝶, 梅振威, 于东明. 热塑性交联聚乙烯(TPEXa)管材的制备及性能研究[J]. 中国塑料, 2023, 37(1): 8-12. |
[8] | 李毅, 樊桂琪, 吴天宇, 叶海木. 石墨微片对聚三氟氯乙烯结晶及性能的影响[J]. 中国塑料, 2023, 37(1): 18-25. |
[9] | 沈一蕊, 周文斌, 张菁菁, 赵承仲, 高华坤, 沈曙光, 刘德开, 蒋平平. 中长碳链氯化石蜡在聚氯乙烯制品中的应用及性能研究[J]. 中国塑料, 2023, 37(1): 31-37. |
[10] | 张伟程, 胡祥, 罗鸿兴, 金卉, 游峰, 江学良, 姚楚. 中空玻璃微珠填充聚氨酯发泡材料的吸声性能与动态力学性能研究[J]. 中国塑料, 2023, 37(1): 38-45. |
[11] | 赵一权, 董婧晗, 张铜柱, 王焰孟, 刁帅, 李明贺, 徐昌竹. 汽车外饰用再生聚丙烯材料性能研究[J]. 中国塑料, 2023, 37(1): 112-118. |
[12] | 刘昊育, 辛菲, 杜家盈, 樊晓玲. 无卤阻燃聚酯复合材料研究进展[J]. 中国塑料, 2023, 37(1): 133-143. |
[13] | 焦志伟, 王克琛, 张杨, 杨卫民. 基于碳纳米涂层沉积滑石粉与炭黑协同填充PVC/ABS复合材料的性能研究[J]. 中国塑料, 2022, 36(8): 10-15. |
[14] | 张陶忠, 陈晓龙, 郝晓宇, 于福家. 滑石、CaCO3、BaSO4填充PP复合材料力学性能及界面相互作用对比[J]. 中国塑料, 2022, 36(8): 36-41. |
[15] | 杜青, 何祎, 余坦竟, 蓝艳姣, 赵彦芝, 周菊英. 取向PAN/MWCNTs与热塑性聚烯烃复合材料的制备及表征[J]. 中国塑料, 2022, 36(8): 49-55. |
阅读次数 | ||||||
全文 |
|
|||||
摘要 |
|
|||||